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Hybrid organic–inorganic sol–gel coatings with interpenetrating network for corrosion protection of tinplate

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Abstract

Novel hybrid organic–inorganic coatings with interpenetrating network were synthesized by the acid-catalyzed hydrolytic co-polycondensation of tetraethoxysilane and 3-metacryloxypropyltrimethoxysilane, followed by radical polymerization with methyl methacrylate and triallyl isocyanurate (TAIC). The hybrid coatings were characterized by Fourier transformed infrared spectroscopy, thermogravimetric analysis and scanning electron microscope, and their anti-corrosion behaviors were evaluated by potentiodynamic polarization, electrochemical impedance spectroscopy and salt spray test. The results indicated that the hybrid coatings exhibited excellent anti-corrosion ability by forming a physical barrier between metal and its external environment. Thermal stability of the hybrid coatings was increased after the addition of TAIC. Furthermore, hydrophobic properties of the hybrid coatings were examined by measuring the contact angles, and the change in wetting characteristics of the hybrid coatings was not obvious.

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Acknowledgments

The authors thank Yong Kong and Sheng-Chun Chen for their useful comments about the linguistic content of the article.

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Authors and Affiliations

  1. Institute of Design and Research, ChangZhou University, Changzhou, 213164, China

    Jian-Guo Liu & Yong-Qin Fang

  2. Changzhou Institute of Advanced Materials, BUCT, Changzhou, 213164, China

    Liang Xu

Authors
  1. Jian-Guo Liu
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  2. Liang Xu
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  3. Yong-Qin Fang
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Correspondence to Yong-Qin Fang.

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Liu, JG., Xu, L. & Fang, YQ. Hybrid organic–inorganic sol–gel coatings with interpenetrating network for corrosion protection of tinplate. J Sol-Gel Sci Technol 71, 246–253 (2014). https://doi.org/10.1007/s10971-014-3361-1

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  • DOI: https://doi.org/10.1007/s10971-014-3361-1

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