Abstract
Prussian blue (PB) nanoparticles were successfully synthesized via a γ radiation route in aqueous solutions using sugar as stabilizer at room temperature and ambient pressure. The particle size and shape can be affected by stabilizer and radiation conditions. When the stabilizer was sucrose and the radiation dose was 30 kGy, well-dispersed and uniform PB nanoparticles were obtained, which are 100–200 nm in diameter. They exhibit good ions exchange properties and have maximal Cs+ adsorption capacity of 125.8 mg g−1, which may be applied in radioactive wastewater treatments, ion battery etc.
Similar content being viewed by others
References
Aguila D, Prado Y, Koumousi ES, Mathoniere C, Clerac R (2016) Switchable Fe/Co Prussian blue networks and molecular analogues. Chem Soc Rev 45(1):203–224
Grandjean F, Samain L, Long GJ (2016) Characterization and utilization of Prussian blue and its pigments. Dalton Trans 45(45):18018–18044
Kong B, Selomulya C, Zheng GF, Zhao DY (2015) New faces of porous Prussian blue: interfacial assembly of integrated hetero-structures for sensing applications. Chem Soc Rev 44(22):7997–8018
Torad NL, Hu M, Imura M, Naito M, Yamauchi Y (2012) Large Cs adsorption capability of nanostructured Prussian Blue particles with high accessible surface areas. J Mater Chem 22(35):18261–18267
Takahashi A, Minami N, Tanaka H, Sue K, Minami K, Parajuli D, Lee KM, Ohkoshi SI, Kurihara M, Kawamoto T (2015) Efficient synthesis of size-controlled open-framework nanoparticles fabricated with a micro-mixer: route to the improvement of Cs adsorption performance. Green Chem 17(8):4228–4233
You Y, Wu XL, Yin YX, Guo YG (2014) High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ Sci 7(5):1643–1647
Cai XJ, Gao W, Zhang LL, Ma M, Liu TZ, Du WX, Zheng YY, Chen HR, Shi JL (2016) Enabling Prussian blue with tunable localized surface plasmon resonances: simultaneously enhanced dual-mode imaging and tumor photothermal therapy. ACS Nano 10(12):11115–11126
Fiorito PA, Goncales VR, Ponzio EA, de Torresi SIC (2005) Synthesis, characterization and immobilization of Prussian blue nanoparticles. A potential tool for biosensing devices. Chem Commun 3(3):366–368
Manivannan S, Kang I, Kim K (2016) In situ growth of Prussian blue nanostructures at reduced graphene oxide as a modified platinum electrode for synergistic methanol oxidation. Langmuir 32(7):1890–1898
Awual MR, Suzuki S, Taguchi T, Shiwaku H, Okamoto Y, Yaita T (2014) Radioactive cesium removal from nuclear wastewater by novel inorganic and conjugate adsorbents. Chem Eng J 242(15):127–135
Jang SC, Haldorai Y, Lee GW, Hwang SK, Han YK, Roh C, Yun SH (2015) Porous three-dimensional graphene foam/Prussian blue composite for efficient removal of radioactive 137Cs. Sci Rep 5:17510
Sangvanich T, Sukwarotwat V, Wiacek RJ, Grudzien RM, Fryxell GE, Addleman RS, Timchalk C, Yantasee W (2010) Selective capture of cesium and thallium from natural waters and simulated wastes with copper ferrocyanide functionalized mesoporous silica. J Hazard Mater 182(1–3):225–231
Sasaki T, Tanaka S (2012) Magnetic separation of cesium ion using Prussian blue modified magnetite. Chem Lett 41(1):32–34
Hu M, Jiang JS, Ji RP, Zeng Y (2009) Prussian Blue mesocrystals prepared by a facile hydrothermal method. CrystEngComm 11(11):2257–2259
Ming H, Torad NLK, Chiang YD, Wu KCW, Yamauchi Y (2012) Size- and shape-controlled synthesis of Prussian blue nanoparticles by a polyvinylpyrrolidone-assisted crystallization process. CrystEngComm 14(10):3387–3396
Hu M, Furukawa S, Ohtani R, Sukegawa H, Nemoto Y, Reboul J, Kitagawa S, Yamauchi Y (2012) Synthesis of Prussian blue nanoparticles with a hollow interior by controlled chemical etching. Angew Chem Int Ed 51(4):984–988
Uemura T, Ohba M, Kitagawa S (2004) Size and surface effects of Prussian blue nanoparticles protected by organic polymers. Inorg Chem 43(23):7339–7345
Uemura T, Kitagawa S (2003) Prussian blue nanoparticles protected by poly(vinylpyrrolidone). J Am Chem Soc 125(26):7814–7815
Bu FX, Hu M, Zhang W, Meng Q, Xu L, Jiang DM, Jiang JS (2015) Three-dimensional hierarchical Prussian blue composed of ultrathin nanosheets: enhanced hetero-catalytic and adsorption properties. Chem Commun 51(99):17568–17571
Zhang W, Zhao YY, Malgras V, Ji QM, Jiang DM, Qi RJ, Ariga K, Yamauchi Y, Liu J, Jiang JS, Hu M (2016) Synthesis of monocrystalline nanoframes of Prussian blue analogues by controlled preferential etching. Angew Chem Int Edit 55(29):8228–8234
Li XN, Yuan LZ, Wang JH, Jiang LH, Rykov AI, Nagy DL, Bogdan C, Ahmed MA, Zhu KY, Sun GQ, Yang WS (2016) A “copolymer-co-morphology” conception for shape-controlled synthesis of Prussian blue analogues and as-derived spinel oxides. Nanoscale 8(4):2333–2342
Cai XJ, Gao W, Ma M, Wu MY, Zhang LL, Zheng YY, Chen HR, Shi JL (2015) A Prussian blue-based core-shell hollow-structured mesoporous nanoparticle as a smart theranostic agent with ultrahigh pH-responsive longitudinal relaxivity. Adv Mater 27(41):6536
Sheng QL, Liu RX, Zheng JB (2012) Prussian blue nanospheres synthesized in deep eutectic solvents. Nanoscale 4(21):6880–6886
Ge XP, Wang MZ, Yuan Q, Wang H, Ge XW (2009) The morphological control of anisotropic polystyrene/silica hybrid particles prepared by radiation miniemulsion polymerization. Chem Commun 19(19):2765–2767
Yu CH, Zhao L, Wang SJ, Cui ZP, Peng J, Li JQ, Zhai ML, Huang JB (2013) One-step radiation-induced construction of multi-responsive self-assemblies using simple cyclic ethers. Soft Matter 9(25):5959–5965
Gao QH, Hu JT, Li R, Pang LJ, Xing Z, Xu L, Wang MH, Guo XJ, Wu GZ (2016) Preparation and characterization of superhydrophobic organic-inorganic hybrid cotton fabrics via gamma-radiation-induced graft polymerization. Carbohydr Polym 149:308–316
Wang L, Magliocca E, Cunningham EL, Mustain WE, Poynton SD, Escudero-Cid R, Nasef MM, Ponce-Gonzalez J, Bance-Souahli R, Slade RCT, Whelligan DK, Varcoe JR (2017) An optimised synthesis of high performance radiation-grafted anion-exchange membranes. Green Chem 19(3):831–843
Alrehaily LM, Joseph JM, Wren JC (2015) Radiation-induced formation of Co3O4 nanoparticles from Co2+(aq): probing the kinetics using radical scavengers. Phys Chem Chem Phys 17(37):24138–24150
Ghosh S, Datta A, Biswas N, Datta A, Saha A (2013) Radiation-induced synthesis of self-organized assemblies of functionalized inorganic-organic hybrid nanocomposites. RSC Adv 3(34):14406–14412
Iyengar GA, Ko KR, Lee SH, Shanmugasundaram K, Veres M, Lee KP (2012) Radiation induced preparation of new multifunctional nanobiowebs. Radiat Phys Chem 81(9):1407–1410
Jovanovic SP, Syrgiannis Z, Markovic ZM, Bonasera A, Kepic DP, Budimir MD, Milivojevic DD, Spasojevic VD, Dramicanin MD, Pavlovic VB, Markovie BMT (2015) Modification of structural and luminescence properties of graphene quantum dots by gamma irradiation and their application in a photodynamic therapy. ACS Appl Mater Interfaces 7(46):25865–25874
Liu HZ, Lv M, Deng B, Li JY, Yu M, Huang Q, Fan CH (2014) Laundering durable antibacterial cotton fabrics grafted with pomegranate-shaped polymer wrapped in silver nanoparticle aggregations. Sci Rep 4:5920
Chang L, Chang SQ, Han W, Chen W, Li Z, Zhang Z, Dai YD, Chen D (2016) gamma-Radiation fabrication of porous permutite/carbon nanobeads/alginic acid nanocomposites and their adsorption properties for Cs+. RSC Adv 6(90):86829–86835
Chang SQ, Dai YD, Kang B, Han W, Chen D (2009) Gamma-radiation synthesis of silk fibroin coated CdSe quantum dots and their biocompatibility and photostability in living cells. J Nanosci Nanotechnol 9(10):5693–5700
Chang SQ, Kang B, Dai YD, Zhang HX, Chen D (2011) One-step fabrication of biocompatible chitosan-coated ZnS and ZnS:Mn2+ quantum dots via a gamma-radiation route. Nanoscale Res Lett 6:1–7
Chang SQ, Kang B, Dai YD, Chen D (2009) Synthesis of antimicrobial silver nanoparticles on silk fibers via gamma-radiation. J Appl Polym Sci 112(4):2511–2515
Eaton WA, George P, Hanania GIH (1967) Thermodynamic aspects of the potassium hexacyano-ferrate(III)-(II) system. I. Ion association. J Phys Chem 71(7):2016–2021
Jang J, Lee DS (2016) Magnetic Prussian blue nanocomposites for effective cesium removal from aqueous solution. Ind Eng Chem Res 55(13):3852–3860
Yang HJ, Sun L, Zhai JL, Li HY, Zhao Y, Yu HW (2014) In situ controllable synthesis of magnetic Prussian blue/graphene oxide nanocomposites for removal of radioactive cesium in water. J Mater Chem A 2(2):326–332
Zhao G, Feng JJ, Zhang QL, Li SP, Chen HY (2005) Synthesis and characterization of Prussian Blue modified magnetite nanoparticles and its application to the electrocatalytic reduction of H2O2. Chem Mater 17(12):3154–3159
Zhou PH, Xue DS, Luo HQ, Chen XG (2002) Fabrication, structure, and magnetic properties of highly ordered Prussian blue nanowire arrays. Nano Lett 2(8):845–847
Yi R, Ye G, Wu F, Wen M, Feng X, Chen J (2014) ChemInform abstract: highly efficient removal of 137Cs in seawater by potassium titanium ferrocyanide functionalized magnetic microspheres with multilayer core-shell structure. RSC Adv 4(71):37600–37608
Yang H, Li H, Zhai J, Sun L, Zhao Y, Yu H (2014) Magnetic prussian blue/graphene oxide nanocomposites caged in calcium alginate microbeads for elimination of cesium ions from water and soil. Chem Eng J 246(16):10–19
Acknowledgements
This work was supported by Fundamental Research Funds for Central Universities (NJ20150022, NP2015207), National Natural Science Foundation of China (11105073, 11575086), Jiangsu Cooperative Innovation Fund (BY2013003-09) and project funded by Priority Academic Program Development of Jiangsu Higher Education Institutions.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chang, L., Chang, S., Han, W. et al. Radiation-assisted synthesis of Prussian blue nanoparticles using sugar as stabilizer. J Radioanal Nucl Chem 314, 289–295 (2017). https://doi.org/10.1007/s10967-017-5397-5
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-017-5397-5