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The influence of organic modified montmorillonite on the solution properties of copolymer containing β-cyclodextrin

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Abstract

In this paper, organic modified montmorillonite (O-MMT) was successfully encapsulated in acrylamide (AM)/cetyl dimethyl allyl ammonium bromide (SD-16)/modified β-cyclodextrin (M-β-CD) copolymer (denoted as ASM) by in situ polymerization. The ASM/O-MMT nanocomposite was characterized by FT-IR and TGA. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) clearly proved the exfoliation/intercalation phenomena of O-MMT in the ASM matrix. The results indicated that the introduction of the O-MMT endowed the ASM with excellent thickening efficiency, temperature resistance, salt tolerance, shear resistance. The viscosity retention rate of ASM/3 wt% O-MMT at 90 °C was 55.3%, which was higher than that of pure ASM (30.9%). The ability of salt tolerance for ASM/3 wt% O-MMT nanocomposite (Na+: 40%, Ca2+: 41.3% and Mg2+: 42%) were superior to that of ASM (Na+: 18.9%, Ca2+: 21.3% and Mg2+: 20.7%). Besides, measurement of the viscoelasticity revealed that the addition of the O-MMT significantly improved the storage modulus (G’) and loss modulus (G”) of ASM, which could be attributed to the O-MMT sheets in the ASM act as physical crosslinkers between macromolecules. These results indicated that ASM/O-MMT nanocomposite was more suitable for enhancing oil recovery.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant No.51974339; 51674270), National Major Project (Grant No.2017ZX05009-003), Major project of the National Natural Science Foundation of China (No.51490650), and the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (Grant: No.51821092; 51521063).

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  1. CNPC Nanochemistry Key Laboratory, College of Science, China University of Petroleum, Beijing, 102249, China

    Xu Hu & Yangchuan Ke

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Correspondence to Yangchuan Ke.

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Hu, X., Ke, Y. The influence of organic modified montmorillonite on the solution properties of copolymer containing β-cyclodextrin. J Polym Res 27, 19 (2020). https://doi.org/10.1007/s10965-019-1990-3

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