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Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications

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Abstract

Ring-opening metathesis polymerization of vinylnorbornene with molybdenum (VI) complex or with Hoveyda-Grubbs type Ru alkylidene complex provided soluble polymers, poly (VNBE)s of M n about 10 000, having vinyl pendant groups on cyclopentenylenevinylene main chains. Post-polymerization modification via cross-metathesis of pendant vinyl groups with cis-1,4-diacetoxybut-2-ene, 5-hexenyl acetate, allyl acetoacetate, and allyltrimethylsilane was accomplished. Functionalization of poly (VNBE) was also performed via ene-yne cross-metathesis of vinyl pendants with (4-fluorophenyl) acetylene and (2,4-difluorophenyl) acetylene.

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Acknowledgements

The authors thank Prof. Ari Lehtonen (University Turku, Finland) for the sample of Mo catalyst. Financial support from Grant Agency of the Czech Republic (project 108-11-1661) is gratefully acknowledged.

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Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i, Dolejškova 3, 182 23, Prague 8, Czech Republic

    Hynek Balcar, Tushar Shinde & Martin Lamač

  2. Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 8/2030, 128 40, Prague 2, Albertov, Czech Republic

    Jan Sedláček & Jiří Zedník

Authors
  1. Hynek Balcar
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  2. Tushar Shinde
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  3. Martin Lamač
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  4. Jan Sedláček
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  5. Jiří Zedník
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Corresponding author

Correspondence to Hynek Balcar.

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Balcar, H., Shinde, T., Lamač, M. et al. Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications. J Polym Res 21, 557 (2014). https://doi.org/10.1007/s10965-014-0557-6

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  • DOI: https://doi.org/10.1007/s10965-014-0557-6

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