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Thermodynamics of Mixed Ligand Complex Formation of Copper(II) and Nickel Ions with Glycine and Histidine in Solution

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Abstract

Mixed ligand complexes of copper(II) and nickel(II) with glycine (Gly) and histidine (His) have been studied in aqueous solution using calorimetric, potentiometric and spectrophotometric data at 298.15 K and the ionic strength of I = 0.5 mol·L–1 (KNO3). The thermodynamic parameters of formation of various mixed complexes have been determined. The probable coordination modes of amino acid residues in mixed ligand complexes is discussed.

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Acknowledgements

This research was specified by the Ministry of Education and Science of the Russian Federation in accordance with a state assignment (basic part), project 4.7104.2017/8.9.

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Authors and Affiliations

  1. Department of Inorganic and Analytic Chemistry, Ivanovo State University, Ermak str. 39, Ivanovo, Russia, 153025

    Dmitrii Pyréu

  2. Ivanovo State University of Chemistry and Technology, 7, Sheremetevsky Ave., Ivanovo, Russia, 153000

    Sergei Gridchin

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  1. Dmitrii Pyréu
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  2. Sergei Gridchin
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Correspondence to Dmitrii Pyréu.

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Pyréu, D., Gridchin, S. Thermodynamics of Mixed Ligand Complex Formation of Copper(II) and Nickel Ions with Glycine and Histidine in Solution. J Solution Chem 49, 239–253 (2020). https://doi.org/10.1007/s10953-020-00957-5

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  • DOI: https://doi.org/10.1007/s10953-020-00957-5

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