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Aerosol-assisted synthesis of hierarchical porous titanosilicate molecular sieve as catalysts for cyclohexene epoxidation

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Abstract

Hierarchical titanosilicate composites (HTS) have been synthesized by an aerosol spray method, by which TS-1 nanoparticles were assembled with cetyl trimethyl ammonium bromide and tetraethylorthosilicate/tetra-n-butyl titanate to form a hierarchical porous composites with a core–shell structure. The structure, porosity, morphology and composition of the materials were characterized by X-ray diffraction, nitrogen adsorption isotherm, Raman spectroscopy, electron microscopy and X-ray fluorescence spectroscopy. The hierarchical porous molecular sieve combines the advantages of TS-1 and Ti-KIT-1, and shows high activity and selectivity to epoxide in cyclohexene epoxidation with H2O2. The yield of cyclohexene oxide on HTS is much higher than those on TS-1 and Ti-KIT-1. The selectivities to cyclohexene oxide and 1,2-cyclohexanediol can be adjusted by varying the titanium contents of the HTS samples.

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Acknowledgments

This work was financially supported by the National Science Foundation of China (NSFC, Grant 21473016, 21206017, 20773019, 20603004).

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Authors and Affiliations

  1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, People’s Republic of China

    Zhendong Guo, Guang Xiong, Liping Liu, Peng Li, Liang Hao, Yuanyuan Cao & Fuping Tian

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  1. Zhendong Guo
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  2. Guang Xiong
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  3. Liping Liu
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  4. Peng Li
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  5. Liang Hao
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  6. Yuanyuan Cao
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  7. Fuping Tian
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Correspondence to Guang Xiong.

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Guo, Z., Xiong, G., Liu, L. et al. Aerosol-assisted synthesis of hierarchical porous titanosilicate molecular sieve as catalysts for cyclohexene epoxidation. J Porous Mater 23, 407–413 (2016). https://doi.org/10.1007/s10934-015-0094-7

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  • DOI: https://doi.org/10.1007/s10934-015-0094-7

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