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A New 2D Europium(III) Coordination Polymer Based on 4-Bromoisophthalate Ligand: Synthesis, X-ray Structure, Luminescent and Magnetic Properties

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Abstract

A new 2D europium coordination polymer, {[Eu2(Bript)3(H2O)2]·2(H2O)}n (1) [H2Bript = 4-bromoisophthalic acid], was prepared by hydrothermal synthesis and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The carboxylate oxygen atoms of Bript ligands link the neighboring Eu(III) ions to form a Eu(III)–carboxylate chain with the Eu⋯Eu separations of 3.982 and 5.585 Å, which the chains are further extend into a two-dimensional network. The 3D fluorescence spectra of 1 were detected at room temperature under the excitation and emission wavelengths range of 250–450 and 420–750 nm with the same interval of 5 nm, respectively. The lifetime of 1 in solid-state at room temperature is up to 0.935 ms. The magnetic result shows an antiferromagnetic coupling between the paramagnetic metal cations. Moreover, in vitro MTT assays at different concentrations of 1 have also been investigated and the results reveal that complex 1 was low cytotoxic.

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References

  1. A.K. Jami, V. Baskar, E.C. Sanudo, Inorg. Chem. 52, 2432 (2013)

    Article  CAS  Google Scholar 

  2. M.N. Akhtar, Y.C. Chen, M.A. AIDamen, M.L. Tong, Dalton Trans. 46, 116 (2017)

    Article  CAS  Google Scholar 

  3. D. Ma, W. Wang, Y. Li, J. Li, C. Daiguebonne, G. Calvez, O. Guillou, CrystEngComm 12, 4372 (2010)

    Article  CAS  Google Scholar 

  4. Y.P. Wu, G.W. Xu, W.W. Dong, J. Zhao, D.S. Li, J. Zhang, X. Bu, Inorg. Chem. 56, 1402 (2017)

    Article  CAS  Google Scholar 

  5. M. Chen, W.M. Xu, J.Y. Tian, H. Cui, J.X. Zhang, C.S. Liu, M. Du, J. Mater. Chem. C 5, 2015 (2017)

    Article  CAS  Google Scholar 

  6. C. He, K. Lu, D. Liu, W. Lin, J. Am. Chem. Soc. 136, 5181 (2014)

    Article  CAS  Google Scholar 

  7. D.M. Chen, N.N. Zhang, C.S. Liu, M. Du, J. Mater. Chem. C 5, 2311 (2017)

    Article  CAS  Google Scholar 

  8. A. Angelova, B. Angelov, R. Mutafchieva, S. Lesieur, J. Inorg. Organomet. Polym. Mater. 25, 214 (2015)

    Article  CAS  Google Scholar 

  9. Y.C. Liang, R. Cao, W.P. Su, M.C. Hong, W.J. Zhang, Angew. Chem. Int. Ed. 39, 3304 (2000)

    Article  CAS  Google Scholar 

  10. D.L. Long, A.J. Blake, N.R. Champness, M. Schoder, Chem. Commun. 2000, 1369 (2000)

  11. J. Liu, E.A. Meyers, J.A. Cowan, S.G. Shore, Chem. Commun. 2043 (1998)

  12. K.P. Mortl, J.P. Sutter, S. Golhen, L. Ouahab, O. Kahn, Inorg. Chem. 39, 1626 (2000)

    Article  CAS  Google Scholar 

  13. T. Xia, Y. Cui, Y. Yang, G. Qian, ChemNanoMat 3, 51 (2016)

    Article  Google Scholar 

  14. K.M. Wang, L. Du, Y.LU. Ma, J.S. Zhao, Q. Wang, T. Yan, Q.H. Zhao, CrystEngComm 18, 2690 (2016)

    Article  CAS  Google Scholar 

  15. G. Jin, Z. Liu, H. Sun, Z. Tian, Luminescence 31, 190 (2016)

    Article  CAS  Google Scholar 

  16. X. Lian, B. Yan, RSC Adv. 6, 11570 (2016)

    Article  CAS  Google Scholar 

  17. D. Zhao, Y. Cui, Y. Yang, G. Qian, CrystEngComm 18, 3746 (2016)

    Article  CAS  Google Scholar 

  18. Y. Zhou, B. Yan, Chem. Commun. 52, 2265 (2016)

    Article  CAS  Google Scholar 

  19. M.L. Han, S.H. Li, L.F. Ma, Inorg. Chem. Commun. 20, 340 (2012)

    Article  CAS  Google Scholar 

  20. L.F. Ma, X.Q. Li, Q.L. Meng, L.Y. Wang, M. Du, H.W. Hou, Cryst. Gworth Des. 11, 175 (2011)

    Article  CAS  Google Scholar 

  21. Y. Huang, B. Yan, M. Shao, J. Mol. Struct. 919, 185 (2009)

    Article  CAS  Google Scholar 

  22. Bruker, APEXII Software, Version 6.3.1. (Bruker AXS Inc, Madison, 2004)

    Google Scholar 

  23. O.V. Dolomanov, L.J. Bourhis, R.J. Gildea, J.A.K. Howard, H. Puschmann, J. Appl. Crystallogr. 42, 339 (2009)

    Article  CAS  Google Scholar 

  24. G.M. Sheldrick, Acta Crystallogr. Sect. C A64, 112 (2008)

    Article  Google Scholar 

  25. A.L. Spek, PLATON, A Multipurpose Crystallographic Tool. (Utrecht University, Utrecht, 2005)

    Google Scholar 

  26. T. Chalati, P. Horcajada, P. Couvreur, C. Serre, M.B. Yahia, G. Maurin, R. Gref, Nanomedicine 6, 1683 (2011)

    Article  CAS  Google Scholar 

  27. D. Sykes, I.S. Tidmarsh, A. Barbieri, I.V. Sazanovich, J.A. Weinstein, M.D. Ward, Inorg. Chem. 50, 11323 (2011)

    Article  CAS  Google Scholar 

  28. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th edn. (Wiley, New York, 1986)

    Google Scholar 

  29. A. de Bettencourt Dias, S. Viswanathan, Chem. Commun. 2004, 1024 (2004)

    Article  Google Scholar 

  30. J.C.G. Bunzli, in Lanthanide Probes in Life, Chemical and Earth Sciences, Theory and Practice, ed. by J.C.G. Bunzli, G.R. Choppin (Elsevier, Amsterdam, 1989), pp. 219–293

    Google Scholar 

  31. W.G. Lu, L. Jiang, T.B. Lu, Cryst. Growth Des. 10, 4310 (2010)

    Article  CAS  Google Scholar 

  32. S. Sivakumar, M.L.P. Reddy, A.H. Cowley, R.R. Butorac, Inorg. Chem. 50, 4882 (2011)

    Article  CAS  Google Scholar 

  33. O. Kahn, Molecular Magnetism. (VCH, New York, 1993)

    Google Scholar 

  34. J.S. Miller, M. Drillon, Magnetism: Molecules to Materials V. (VCH, New York, 2006)

    Google Scholar 

  35. J.H. Van Vleck, A. Frank, Phys. Rev. 34, 1494 (1929)

    Article  Google Scholar 

  36. B.N. Figgis, M.A. Hitchman, Ligand Field Theory and Its Application. (Wiley-VCH, New York, 2000

    Google Scholar 

Download references

Acknowledgements

This work was supported by the Special Funds of Guangdong College Students’ Scientific and Technological Innovation Cultivation (pdjh2017b0551), the Natural Science Foundation of Guangdong Province (2015A030310407), the characteristics of innovative projects in Colleges and Universities in Guangdong Province (2015KTSCX156), the Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions (YQ2015168) and the Natural Science Foundation of Zhaoqing University (201532).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Deyun Ma, Liang Qin, Haifu Guo, Shujun Li, Manfei Huang, Huimin Liu, Yifei Wang & Rui Xie

  2. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata, 990-8560, Japan

    Hiroshi Sakiyama

  3. College of Medicine, Jinan University, Guangzhou, 510632, People’s Republic of China

    Jun Wang & Jun Xu

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  1. Deyun Ma
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  2. Jun Wang
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  3. Liang Qin
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  10. Hiroshi Sakiyama
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  11. Jun Xu
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Correspondence to Deyun Ma or Jun Xu.

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Ma, D., Wang, J., Qin, L. et al. A New 2D Europium(III) Coordination Polymer Based on 4-Bromoisophthalate Ligand: Synthesis, X-ray Structure, Luminescent and Magnetic Properties. J Inorg Organomet Polym 27, 1514–1520 (2017). https://doi.org/10.1007/s10904-017-0611-z

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  • DOI: https://doi.org/10.1007/s10904-017-0611-z

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