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Cu(II) and Zn(II)-Pyridine-2,3-Dicarboxylate Complexes with 2-Methylimidazole: Syntheses, Crystal Structures, Spectroscopic and Thermal Analyses

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Abstract

Two new Cu(II) and Zn(II)-pyridine-2,3-dicarboxylate (pydc) complexes with 2-methylimidazole (2-Meim), [Cu(pydc)(2-Meim)3]·H2O (1) and {[Zn(μ-pydc)(H2O)(2-Meim)]·H2O}n (2) have been synthesized and characterized by elemental, spectral (IR and UV–Vis.) and thermal analyses. The molecular structures of mononuclear (1) and polynuclear (2) complexes have been determined by the single crystal X-ray diffraction. Compound 1 crystallizes in the triclinic P − 1 space group, while compound 2 crystallizes in the monoclinic P21/c space group. The pyridine-2,3-dicarboxylate ligand acts in two different coordination modes; namely, bidentate-(N,O) for 1 and μ-tridentate-(N,O,O) for 2, the latter displaying a 1D polynuclear structure. The crystal packing of the complexes exhibit 3D supramolecular frameworks including channels by C–H···π, π···π, and N–H···O interactions. Water molecules occupy the channels by O–H···O hydrogen bonds.

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Acknowledgments

This work was supported by the Eskişehir Osmangazi University by project No 200819042.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Eskişehir Osmangazi University, 26480, Eskişehir, Turkey

    Fatih Semerci & Okan Zafer Yeşilel

  2. Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240, Erzurum, Turkey

    Ertan Şahin

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  1. Fatih Semerci
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  2. Okan Zafer Yeşilel
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  3. Ertan Şahin
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Correspondence to Okan Zafer Yeşilel.

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Semerci, F., Yeşilel, O.Z. & Şahin, E. Cu(II) and Zn(II)-Pyridine-2,3-Dicarboxylate Complexes with 2-Methylimidazole: Syntheses, Crystal Structures, Spectroscopic and Thermal Analyses. J Inorg Organomet Polym 20, 334–342 (2010). https://doi.org/10.1007/s10904-010-9353-x

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