Abstract
The present work reports low cost, rapid synthesis of ZnO nanostructures capped with Millettia pinnata leaf extract which produced rods, pyramids, cones and flower like morphology. Microwave irradiation method drastically reduced the reaction time. Three samples were prepared with different volumes of the extract and a control experiment was performed where no extract was used. The quantity of the extract significantly influences the size and morphology. Characterization done by X-ray diffraction established the purity and crystalline nature of the samples. The composition was further confirmed by EDS which shows the exclusive presence of elements zinc and oxygen. UV–visible spectroscopy shows absorption wavelength for the as synthesized ZnO semiconductor samples between 351 and 365 nm. FTIR spectra show a band in the region of 500–550 cm−1 corresponding to Zn–Ostr. FESEM images show rodlike morphology for uncapped ZnO which on annealing at 400 °C produced an assembled flower like morphology. The morphology varies from pyramid, to cone, to flower like as the volume of extract increases from 2.5 to 10 mL. Methylene blue was the target textile dye and its degradation was tested under UV light.
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M. H. Huang, S. Mao, H. Feick, H. Yan, Y. Wu, H. Kind, E. Weber, R. Russo, and P. Yang (2001). Science 292, 1897.
Z. Deng, M. Chen, A. Gu, and L. Wu (2008). J. Phys. Chem. B 112, 16.
B. Archana, K. Manjunath, G. Nagaraju, K. B. ChandraSekhar, and N. Kottam (2017). Int. J. Hydrogen Energy 42, 5125.
S. B. A. Hamid, S. J. Teh, and C. W. Lai (2017). Catalysts 7, 93.
J. Song, J. Zhou, and Z. L. Wang (2006). Nano Lett. 6, 1656.
Y. I. Alivov, E. V. Kalinina, A. E. Cherenkov, D. C. Look, B. M. Ataev, A. K. Omaev, M. V. Chukichev, and D. M. Bagnall (2003). Appl. Phys. Lett. 83, 4719.
S. M. H. Akhter, Z. Mahmood, S. Ahmad, and F. Mohammad (2018). BioNanoScience. 8, 811.
K. Kairyte, A. Kadys, and Z. Luksiene (2013). J. Photochem. Photobiol B: Biol 128, 78.
J. Guo and C. Peng (2015). Ceram. Int. 41, 2180.
X. Zhao and L. Qi (2012). Nanotechnology 23, 235604.
L. Upadhyaya, J. Singh, V. Agarwal, A. C. Pandey, S. P. Verma, P. Das, and R. P. Tewari (2014). J. Polym. Res 21, 550.
C. L. Kuo, C. L. Wang, H. H. Ko, W. S. Hwang, K. Chang, W. L. Li, H. H. Huang, Y. H. Chang, and M. C. Wang (2010). Ceram. Int. 36, 693.
P. J. Lu, S. C. Huang, Y. P. Chen, L. C. Chiueh, and D. Y. C. Shih (2015). J. Food Drug Anal 23, 587.
Z. Y. Zhang and H. M. Xiong (2015). Materials 8, 3101.
G. C. J. Swarnavalli, S. Dinakaran, S. Krishnaveni, and G. M. Bhalerao (2019). Mater. Sci. Eng. B. 247, 114376.
F. Davar, A. Majedi, and A. Mirzaei (2015). J. Am. Ceram. Soc. 98, 1739.
A. Kolodziejczak-Radzimska and T. Jesionowski (2014). Materials 7, 2833.
S. Ahmed, M. Ahmad, B. L. Swami, and S. Ikram (2016). J. Adv. Res. 7, 17.
N. Zikalala, K. Matshetshe, S. Parani, and O. S. Oluwafemi (2018). Nano-Struct. Nano-Objects. 16, 288.
L. Xu, Y. L. Hu, C. Pelligra, C. H. Chen, L. Jin, H. Huang, S. Sithambaram, M. Aindow, R. Joesten, and S. L. Suib (2009). Chem. Mater. 21, 2875.
C. Anupama, A. Kaphle, Udayabhanu, and G. Nagaraju (2018). J. Mater. Sci. Mater. Electr. 29, 4238.
M. M. Khan, N. H. Saadah, M. E. Khan, M. H. Harunsani, A. L. Tan, and M. H. Cho (2019). BioNanoScience 9, 334.
T. T. Liu, M. H. Wang, H. Su, X. Chen, C. Chen, and R. C. Zhang (2015). J. Electr. Mater. 44, 3430.
J. Duraimurugan, G. S. Kumar, P. Maadeswaran, S. Shanavas, P. M. Anbarasan, and V. Vasudevan (2019). J. Mater. Sci: Mater. Electr 30, 1927.
S. Narendhran and R. Sivaraj (2016). Bull. Mater. Sci. 39, 1.
G. Khara, H. Padalia, P. Moteriya, and S. Chanda (2018). Arab. J. Sci. Eng 43, 3393.
E. Shayegan, M. Mina, S. Ali, R. Saeid, and T. Fardood (2018). J. Mater. Sci: Mater. Electr 29, 1333.
A. Venkateasan, R. Prabakaran, and V. Sujatha (2017). Nanotechnol. Environ. Eng 2, 1.
S. Kumar and C. Lalit (2017). Appl. Nanosci. 7, 501.
T. Bhuyan, K. Mishra, M. Khanuja, R. Prasad, and A. Varma (2015). Mater. Sci. Semicond. Process. 32, 55.
P. Thatoi, R. G. Kerry, S. Gouda, G. Das, K. Pramanik, H. Thatoi, and J. K. Patra (2016). J. Photochem. Photobiol. B: Biol 163, 311.
D. Sharma, M. I. Sabela, S. Kanchi, P. S. Mdluli, G. Singh, T. A. Stenström, and K. Bisetty (2016). J. Photochem. Photobiol. B: Biol. 162, 199.
M. Sundrarajan, S. Ambika, and K. Bharathi (2015). Adv. Powder Technology 26, 1294.
M. S. A. Marzouk, M. T. Ibrahim, O. R. El-Gindi, and M. S. A. Bakr (2008). Zeitschrift Für Naturforschung C 63, 1.
R. Gandhidasan, S. Neelakantan, P. V. Raman, and S. Devaraj (1986). Phytochemistry 26, 281.
S. S. Momeni, M. Nasrollahzadeh, and A. Rustaiyan (2016). J. Coll. Interface Sci. 472, 173.
J. Fowsiya, G. Madhumitha, N. A. Al-Dhabi, and M. V. Arasu (2016). J. Photochem. Photobiol. B: Biol. 162, 395.
M. Ramesh, M. Anbuvannan, and G. Viruthagiri (2015). Spectrochimica Acta Part A: Mol. Biomol. Spectrosc. 136, 864.
R. B. Kale, Y. J. Hsu, Y. F. Lin, and S. Y. Lu (2014). Superlattices Microstruct 69, 239.
L. Vayssieres, K. Keis, A. Hagfeldt, and S. Lindquist (2001). Chem. Mater. 13, 4395.
H. R. Madan, S. C. Sharma, Udayabhanu, D. Suresh, Y. S. Vidya, H. Nagabhushana, H. Rajanaik, K. S. Anantharaju, S. C. Prashantha, and P. Sadananda Maiya (2016). Spectrochimica Acta Part A: Mol. Biomol. Spectrosc. 152, 404.
I. John Peter, E. Praveen, G. Vignesh, and P. Nithiananthi (2017). Mater. Res. Bull. 4, 124003.
X. Wang, Q. Zhang, Q. Wan, G. Dai, C. Zhou, and B. Zou (2011). J. Phys. Chem C. 115, 2769.
Acknowledgements
We gratefully acknowledge the facilities provided by Department of Nuclear Physics, University of Madras, Guindy Campus Chennai, Tamil Nadu, India.
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This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
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Cynthia Jemima Swarnavalli, G., Dinakaran, S. Morphology Controlled Synthesis of Zinc Oxide Nanostructures Through Millettia pinnata (MP) Leaf Extract as Capping Agent and its Photocatalytic Degradation Efficiency of a Textile Dye. J Clust Sci 32, 1585–1592 (2021). https://doi.org/10.1007/s10876-020-01911-7
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DOI: https://doi.org/10.1007/s10876-020-01911-7