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Synthesis and Structural Analysis of Trichloroacetamidoxime

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Abstract

The trichloroacetoamidoxime was synthesized following the principles of green chemistry in excellent yield (90 %). This compound crystallizes in the orthorhombic system with space group P212121 and the cell parameters are a = 5.7353 (3), b = 10.5167 (8) Å, c = 21.4787 (16) Å, α, β and γ = 90°, V = 1295.52 (15) Å3, Z = 4. The final residual factor is R 1 = 0.0429, wR 2 = 0.0884. The presence of the intermolecular hydrogen bonds generates pseudo rings of five members between two molecules that indicate the amido oxime conformation for trichloroacetoamidoxime.

Graphical Abstract

The present paper describes the synthesis and a brief study structural of tricloroacetoamidoxime.

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References

  1. Katritzky AR, Khashad NM, Kirichenko N, Singh A (2006) J Org Chem 71:9051

    Article  CAS  Google Scholar 

  2. Hynes JB, Hack LG (1972) J Med Chem 15:1194

    Article  CAS  Google Scholar 

  3. Bretanha LC, Venzke D, Campos PT, Duarte A, Martins MAP, Siqueira GM, Freitag RA (2009) Arkivoc xii:1

    Google Scholar 

  4. Bruker (2006) APEX2 (version 2.1), COSMO (version 1.56), BIS (version 2.0.1.9), SAINT (version 7.3A) and SADABS (version 2004/1) and XPREP (version 2005/4) Bruker AXS Inc., Madison

  5. Sheldrick GM (1997) SHELXS-97, program for crystal structure solution. University of Göttingen, Göttingen

    Google Scholar 

  6. Sheldrick GM (1997) SHELXL-97, program for crystal structure refinement. University of Göttingen, Göttingen

    Google Scholar 

  7. Coppens P, Leiserowitz L, Rabinovich D (1965) Acta Crystallogr 18:1035

    Article  CAS  Google Scholar 

  8. Farrugia LJ (1997) ORTEP-III for Windows. J Appl Crystallogr 30:565

    Article  CAS  Google Scholar 

  9. Allen FH, Kennard O, Watson DG, Brammer L, Orpen AG, Taylor RJ (1987) J Chem Soc Perkin Trans II:S1

    Google Scholar 

  10. Arulsamy N, Bohle DS (2000) J Org Chem 65:1139

    Article  CAS  Google Scholar 

  11. Pyykko P (1997) Chem Rev 97:597

    Article  Google Scholar 

  12. Sobczyk L, Grabowski SJ, Krygowski TM (2005) Chem Rev 105:3513

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to FAPERGS, CNPq (Project 476769/2004-3) and CAPES for financial support. Authors also thank to Professor Claudio M. P. Pereira (UFPel) and Professor Wilson Cunico (UFPel) for the valuable contributions on the preparation of this manuscript.

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Authors and Affiliations

  1. Departamento de Química Orgânica, Universidade Federal de Pelotas, Pelotas, RS, 96010-900, Brazil

    Lizandra C. Bretanha, Rogério A. Freitag, Geonir M. Siqueira & Marina Ritter

  2. Departamento de Química Orgânica, Universidade Federal de Santa Maria, Santa Maria, RS, 97105-900, Brazil

    Patrick T. Campos & Marcos A. P. Martins

Authors
  1. Lizandra C. Bretanha
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  2. Rogério A. Freitag
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  3. Geonir M. Siqueira
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  4. Marina Ritter
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  5. Patrick T. Campos
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  6. Marcos A. P. Martins
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Corresponding author

Correspondence to Rogério A. Freitag.

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Bretanha, L.C., Freitag, R.A., Siqueira, G.M. et al. Synthesis and Structural Analysis of Trichloroacetamidoxime. J Chem Crystallogr 42, 697–700 (2012). https://doi.org/10.1007/s10870-012-0302-0

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