Abstract
A facile and eco-friendly synthetic approach was employed to synthesize superparamagnetic magnetite (Fe3O4) nanoparticles with cubic lattice structure. Zucchini and pomegranate peel-extracts were used as natural stabilizer and surfactant. The X-ray diffraction patterns revealed that the green synthetic technique was successful in formation of highly distributed Fe3O4 nanoparticles using both of the above extracts. The infrared (IR) analysis further confirmed the phase formation and the binding of extracts with Fe3O4 nanoparticles. Based on UV–Vis analysis, the samples showed the characteristic of surface plasmon resonance in the presence of Fe3O4 nanoparticles. The as-synthesized samples were heated at 550 °C for 2 h. It was found that the particles however grew, their sizes remained in nanoscale regime, indicating their thermal stability. The VSM analysis indicated that the as-synthesized samples have a saturation magnetization of 21.4 emu/g (using zucchini peel extract) and 13.3 emu/g (using pomegranate peel extract), which increased respectively to 45.8 emu/g and 38.1 emu/g after the heating process. A negligible coercivity in the samples with the particle sizes of less than 10 nm suggests superparamagnetic behavior of the samples.
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A. Ali, H. Zafar, M. Zia, I. ul Haq, A. Phull, J. Sarfarz ali, A. Hussain, Synthesis, characterization, applications, and challenges of iron oxide nanoparticles. Nanotechnol. Sci. Appl. 9, 49–67 (2016)
J. Qu, Y. Dong, Y. Wang, H. Xing, A novel sensor based on Fe3O4 nanoparticles–multiwalled carbon nanotubes composite film for determination of nitrite. Sens. Bio-Sens. Res. 3(Supplement C), 74–78 (2015)
A. Von Held Soares, H. Atia, U. Armbruster, F. Passos, A. Martin, Platinum, palladium and nickel supported on Fe3O4 as catalysts for glycerol aqueous-phase hydrogenolysis and reforming. Appl. Catal. Gen. 548, 179–190 (2017)
G. Prabha, V. Raj, Sodium alginate-polyvinyl alcohol-bovin serum albumin coated Fe3O4 nanoparticles as anticancer drug delivery vehicle: doxorubicin loading and in vitro release study and cytotoxicity to HepG2 and L02 cells. Mater. Sci. Eng. C Mater. Biol. Appl. 79, 410–422 (2017)
K.K. Kefeni, T.A.M. Msagati, B.B. Mamba, Ferrite nanoparticles: synthesis, characterisation and applications in electronic device. Mater. Sci. Eng. B 215(Supplement C), 37–55 (2017)
A. Mahdieh, A.R. Mahdavian, H. Salehi-Mobarakeh, Chemical modification of magnetite nanoparticles and preparation of acrylic-base magnetic nanocomposite particles via miniemulsion polymerization. J. Magn. Magn. Mater. 426(Supplement C), 230–238 (2017)
A. Hajalilou, S.A. Mazlan, S.T. Shilan, E. Abouzari-Lotf, Enhanced magnetorheology of soft magnetic carbonyl iron suspension with binary mixture of Ni-Zn ferrite and Fe3O4 nanoparticle additive. Colloid Polym. Sci. 295(9), 1499–1510 (2017)
R.M. Cornell, U. Schwertmann, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses (Wiley, Weinheim, 2006)
O.M. Lemine, K. Omri, B. Zhang, L. El Mir, M. Sajieddine, A. Alyamani, M. Bououdina, Sol–gel synthesis of 8 nm magnetite (Fe3O4) nanoparticles and their magnetic properties. Superlattices Microstruct. 52(4), 793–799 (2012)
L. Zhu, X. Zeng, X. Li, B. Yang, R. Yu, Hydrothermal synthesis of magnetic Fe3O4/graphene composites with good electromagnetic microwave absorbing performances. J. Magn. Magn. Mater. 426, 114–120 (2017)
T. Lu, J. Wang, J. Yin, A. Wang, X. Wang, T. Zhang, Surfactant effects on the microstructures of Fe3O4 nanoparticles synthesized by microemulsion method. Colloids Surf. Physicochem. Eng. Asp. 436, 675–683 (2013)
A. Radoń, A. Drygała, L. Hawelek, D. Lukowiec, Structure and optical properties of Fe3O4 nanoparticles synthesized by co-precipitation method with different organic modifiers. Mater. Charact. 131, 148–156 (2017)
D. Chen, S. Ni, Z. Chen, Synthesis of Fe3O4 nanoparticles by wet milling iron powder in a planetary ball mill. China Particuol. 5(5), 357–358 (2007)
S. Santra, R. Tapec, N. Theodoropoulou, J. Dobson, A. Hebard, W. Tan, Synthesis and characterization of silica-coated iron oxide nanoparticles in micro emulsion: the effect of nonionic surfactants. Langmuir 17, 2900–2906 (2001)
S. Dhar, E.M. Reddy, A. Shiras, V. Pokharkar, B.E.E. Prasad, Natural gum reduced/stabilized gold nanoparticles for drug delivery formulations. Chem. Eur. J. 14(33), 10244–10250 (2008)
A. Hajalilou, A. Kianvash, K. Shameli, H. Lavvafi, Carbonyl iron based magnetorheological effects with silver nanoparticles via green-assisted coating. Appl. Phys. Lett. 110(26), 261902 (2017)
Z. Khodsiani, H. Mansuri, T. Mirian, The effect of cryomilling on the morphology and particle size distribution of the NiCoCrAlYSi powders with and without nano-sized alumina. Powder Technol. 245, 7–12 (2013)
Y. Cai, Y. Shen, A. Xie, S. Li, X. Wang, Green synthesis of soya bean sprouts-mediated superparamagnetic Fe3O4 nanoparticles. J. Magn. Magn. Mater. 322(19), 2938–2943 (2010)
W. Lu, Y. Shen, A. Xie, W. Zhang, Green synthesis and characterization of superparamagnetic Fe3O4 nanoparticles. J. Magn. Magn. Mater. 322(13), 1828–1833 (2010)
A. Demir Korkmaz, R. Topkaya, A. Baykal, Green synthesis of superparamagnetic Fe3O4 nanoparticles with maltose: Its magnetic investigation. Polyhedron 65, 282–287 (2013)
B. Kumar, K. Smita, L. Cumbal, A. Debut, Biogenic synthesis of iron oxide nanoparticles for 2-arylbenzimidazole fabrication. J. Saudi Chem. Soc. 18(4), 364–369 (2014)
M.Y. Khan, A.S. Mangrich, J. Schultz, F.S. Grasel, N. Mattoso, D.H. Mosca, Green chemistry preparation of superparamagnetic nanoparticles containing Fe3O4 cores in biochar. J. Anal. Appl. Pyrolysis 116, 42–48 (2015)
F. Dumur, A. Guerlin, E. Dumas, D. Bertin, D. Gigmes, C.R. Mayer, Controlled spontaneous generation of gold nanoparticles assisted by dual reducing and capping agents. Gold Bull. 44(2), 119–137 (2011)
A. Hajalilou, M. Hashim, R. Ebrahimi-Kahrizsangi, H. Mohamed, Kamari, N. Sarami, Synthesis and structural characterization of nano-sized nickel ferrite obtained by mechanochemical process. Ceram. Int. 40, 5881–5887 (2014)
A. Hajalilou, M. Hashim, R. Ebrahimi-Kahizsangi, I. Ismail, N. Sarami, Synthesis of titanium carbide and TiC–SiO2 nanocomposite powder using rutile and Si by mechanically activated sintering. Adv. Powder Technol. 25, 1094–1102 (2014)
D. Zhang, Processing of advanced materials using high-energy mechanical milling. Prog. Mater. Sci. 49, 537–560 (2004)
S. Akhtar, T. Ismail, D. Fraternale, P. Sestili, Pomegranate peel and peel extracts: chemistry and food features. Food Chem. 174, 417–425 (2015)
A.B. Ogholbeyg, A. Kianvash, A. Hajalilou, E. Abouzari-Lotf, A. Zarebkohan, Cytotoxicity characteristics of green assisted-synthesized superparamagnetic maghemite (γ-Fe2O3) nanoparticles. J. Mater. Sci. Mater. Electron, 29(14), 12135–12143. https://doi.org/10.1007/s10854-018-9321-8
A. Hajalilou, S.A. Mazlan, A review on preparation techniques for synthesis of nanocrystalline soft magnetic ferrites and investigation on the effects of microstructure features on magnetic properties, Appl. Phys. A 122, 680 (2016). https://doi.org/10.1007/s00339-016-0217-2
E.M.A. Khalil, M. Aouf, Effect of heat treatment on the infrared absorption spectra of strontium-sodium-borosilicate glass. IJEMS 4(4), 155–162 (1997)
N. Basavegowda, K.B.S. Magar, K. Mishra, Y.R. Lee, Green fabrication of ferromagnetic Fe3O4 nanoparticles and their novel catalytic applications for the synthesis of biologically interesting benzoxazinone and benzthioxazinone derivatives. N. J. Chem. 38(11), 5415–5420 (2014)
A. Hajalilou, M. Hashim, H. Mohamed Kamari, Structure and magnetic properties of Ni0.64Zn0.36Fe2O4 nanoparticles synthesized by high-energy milling and subsequent heat treatment. J. Mater. Sci. Mater. Electron. 26(3), 1709–1718 (2015)
A. Hajalilou, M. Hashim, M. Abbasi, H.Mohamed Kamari, H. Azimi, A comparative study on the effects of different milling atmospheres and sintering temperatures on the synthesis and magnetic behavior of spinel single phase Ni0.64Zn0.36Fe2O4 nanocrystals. J. Mater. Sci. Mater. Electron. 26(10), 7468–7483 (2015)
A. Hajalilou, M. Hashim, R. Ebrahimi-Kahrizsangi, H. Mohamed Kamari, Influence of evolving microstructure on electrical and magnetic characteristics in mechanically synthesized polycrystalline Ni-ferrite nanoparticles. J. Alloys Compd. 633, 306–316 (2015)
A. Hajalilou, A. Kianvash, H. Lavvafi, S. Kamyar, Nanostructured soft magnetic materials synthesized via mechanical alloying: a review. J. Mater. Sci. Mater. Electron. 29(2), 1690–1717 (2018)
D. Jiles, Introduction to Magnetism and Magnetic Materials. SERBIULA Sist. Libr. 20, (2017)
A. Hajalilou, M. Hashim, H. Kamari, Influence of CaO and SiO2 co-doping on the magnetic, electrical properties and microstructure of a Ni–Zn ferrite. J. Phys. Appl. Phys. 48, 145001 (2015)
H. Abdollah, M. Hashim, R. Ebrahimi-Kahrizsangi, M.T. Masoudi, Effect of milling atmosphere on structural and magnetic properties of Ni–Zn ferrite nanocrystalline. Chin. Phys. B 24(4), 048102 (2015)
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Etemadifar, R., Kianvash, A., Arsalani, N. et al. Green synthesis of superparamagnetic magnetite nanoparticles: effect of natural surfactant and heat treatment on the magnetic properties. J Mater Sci: Mater Electron 29, 17144–17153 (2018). https://doi.org/10.1007/s10854-018-9805-6
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DOI: https://doi.org/10.1007/s10854-018-9805-6