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A ascorbic acid-imprinted poly(o-phenylenediamine)/zeolite imidazole frameworks-67/carbon cloth for electrochemical sensing ascorbic acid

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Abstract

A flexible ascorbic acid (AA)-imprinted poly(o-phenylenediamine) (ploy(o-PD))/zeolite imidazole frameworks-67 (ZIF-67)/carbon cloth (CC) electrode was prepared for electrochemical sensing AA. The flexible AA-imprinted poly(o-PD)/ZIF-67/CC electrode was prepared by growing ZIF-67 on flexible CC, electropolymerization of o-PD with AA on ZIF-67/CC and eluting template molecules AA. The results showed that the spherical ZIF-67 crystals were arranged evenly and firmly on the fibers of CC surface. The diameter of spherical ZIF-67 crystals was approximately 500–600 nm, and the spherical ZIF-67 crystals catalyzed the oxidation of AA well. A layer of poly(o-PD) with AA-imprinted pores was covered on the ZIF-67/CC electrode, so the AA-imprinted poly(o-PD)/ZIF-67/CC electrode exhibited better selectivity toward AA detection and good stability. The molecularly imprinted sensor exhibits high sensitivity, and the sensitivity could reach 959.9 μA/mM−1 cm−2, the detection limit was 0.019 μM, and the concentration range of AA was 0.057 μM–11.4 0 mM. The AA-imprinted poly(o-PD)/ZIF-67/CC electrode also showed higher stability and repeatability. The results proved that the spherical ZIF-67 crystals were good electrode materials for electrochemical AA biosensors.

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Acknowledgements

This work was financially supported by National Natural Science Foundation of China (21465014, 21964010 and 21765009) and the Ground Plan of Science and Technology Projects of Jiangxi Educational Committee (KJLD14023).

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Authors and Affiliations

  1. Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, 99 Ziyang Road, Nanchang, 330022, People’s Republic of China

    Yufei Guo, Li Wang, Lijuan Xu, Canwei Peng & Yonghai Song

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  1. Yufei Guo
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  2. Li Wang
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Correspondence to Li Wang or Yonghai Song.

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Guo, Y., Wang, L., Xu, L. et al. A ascorbic acid-imprinted poly(o-phenylenediamine)/zeolite imidazole frameworks-67/carbon cloth for electrochemical sensing ascorbic acid. J Mater Sci 55, 9425–9435 (2020). https://doi.org/10.1007/s10853-020-04687-3

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