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Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME

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Abstract

Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich–Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg–Nissan, Eyring–UNIQUAC, three-body McAlister, and Eyring–NRTL models.

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References

  1. J. Liang, Lv. Jing, J. Fan, Z. Shang, Synth. Commun. 39, 2822 (2009)

  2. I.-W. Kim, M.D. Jang, Y.K. Ryu, E.H. Cho, Y.K. Lee, J.H. Park, Anal. Sci. 18, 1357 (2002)

    Article  Google Scholar 

  3. Z.P. Višak, L.M. Ilharco, A.R. Garcia, V. Najdanović-Višak, J.M.N.A. Farleira, F.J.P. Caetano, M.L. Kijevčanin, S.P. Šerbanović, J. Phys. Chem. B 115, 8481 (2011)

    Article  Google Scholar 

  4. O.E. Philippova, S.I. Kuchanov, I.N. Topchieva, V.A. Kabanov, Macromolecules 18, 1628 (1985)

    Article  ADS  Google Scholar 

  5. Toxicological Evaluation of Certain Food Additives, Food Additives Series 14 (World Health Organization, Geneva, 1979)

  6. Code of Federal Regulations, Title 21, vol. 3 (FDA, Washington, DC, 2001)

  7. J.M. Harris, Poly(Ethylene Glycol) Chemistry: Bio-technical and Bio-medical Applications (Plenum Press Inc., New York, 1992), pp. 7–12

    Book  Google Scholar 

  8. M.E. Ferreyra de Ruiz Holgado, C.R. de Schaefer, E.L. Arancibia, J. Chem. Eng. Data 47, 144 (2002)

    Article  Google Scholar 

  9. M.A. Monsalvo, A. Baylaucq, P. Reghem, S.E. Quiñones-Cisneros, C. Boned, Fluid Phase Equilib. 233, 1 (2005)

    Article  Google Scholar 

  10. F. Han, J. Zhang, G. Chen, X. Wei, J. Chem. Eng. Data 53, 2598 (2008)

    Article  Google Scholar 

  11. C.N. Schubert, W.I. Echter, The Method of Polymer Ethylene Glycol for Removal Pollution from Gases, CN. Patent 1364096A (2002)

  12. M. Heisel, A. Belloni, Gas. Sep. Purif. 5, 111 (1991)

    Article  Google Scholar 

  13. O. Redlich, A. Kister, Ind. Eng. Chem. 40, 345 (1948)

    Article  Google Scholar 

  14. L. Grunberg, A.H. Nissan, Nature 164, 799 (1949)

    Article  ADS  Google Scholar 

  15. R.J. Martins, M.J.E.D. Cardoso, O.E. Barcia, Ind. Eng. Chem. Res. 39, 849 (2000)

    Article  Google Scholar 

  16. R.A. McAllister, AIChE J. 6, 427 (1960)

    Article  Google Scholar 

  17. L.T. Novak, Ind. Eng. Chem. Res. 43, 2602 (2004)

    Article  Google Scholar 

  18. A.Ž. Tasić, D.K. Grozdanić, B.D. Djordjević, S.P. Šerbanović, N. Radojković, J. Chem. Eng. Data 40, 586 (1995)

    Article  Google Scholar 

  19. A.R. Riddick, W.B. Bunger, T.K. Sakano, Organic Solvents, Physical Properties and Methods of Purification, 4th edn. (Wiley, New York, 1986)

    Google Scholar 

  20. Z. Shan, A.F.A. Asfour, J. Chem. Eng. Data 44, 118 (1999)

    Article  Google Scholar 

  21. TRC Thermodynamic Tables, Hydrocarbons, Thermodynamic Research Center (The Texas A &M University System, College Station, TX, 1998)

  22. S. Ottani, D. Vitalini, F. Comelli, C. Castellari, J. Chem. Eng. Data 47, 1197 (2002)

    Article  Google Scholar 

  23. E.A. Mueller, P. Rasmussen, J. Chem. Eng. Data 36, 214 (1991)

    Article  Google Scholar 

  24. C. Aucouturier, G. Roux-Desgrenges, A.H. Roux, J. Chem. Thermodyn. 31, 289 (1999)

    Article  Google Scholar 

  25. A. Pal, G. Dass, A. Kumar, J. Chem. Eng. Data 44, 2 (1999)

    Article  Google Scholar 

  26. J.N. Real, T.P. Iglesias, S.M. Pereira, M.A. Rivas, J. Chem. Thermodyn. 34, 1029 (2002)

    Article  Google Scholar 

  27. F.J. Carmona, F.J. Arroyo, I.D. de la Fuente, J.A. Gonzales, J.C. Cobos, Can. J. Chem. 77, 1608 (1999)

    Article  Google Scholar 

  28. D. Bajić, G. Ivaniš, Z. Višak, E. Živković, S. Šerbanović, M. Kijevčanin, J. Chem. Thermodyn. 57, 510 (2013)

    Article  Google Scholar 

  29. D.W. Marquardt, J. Soc. Ind. Appl. Math. 2, 431 (1963)

    MathSciNet  Google Scholar 

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Acknowledgments

The authors gratefully acknowledge the financial support received from the Research Fund of Ministry of Science and Environmental Protection, Serbia and the Faculty of Technology and Metallurgy, University of Belgrade (Project No. 172063).

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Authors and Affiliations

  1. Vinča Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, 11001 , Belgrade, Serbia

    N. Živković

  2. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 , Belgrade, Serbia

    S. Šerbanović, M. Kijevčanin & E. Živković

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  1. N. Živković
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  2. S. Šerbanović
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  3. M. Kijevčanin
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  4. E. Živković
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Correspondence to E. Živković.

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Živković, N., Šerbanović, S., Kijevčanin, M. et al. Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. Int J Thermophys 34, 1002–1020 (2013). https://doi.org/10.1007/s10765-013-1469-0

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  • DOI: https://doi.org/10.1007/s10765-013-1469-0

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