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Removal of hexavalent chromium from contaminated ground water using zero-valent iron nanoparticles

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Abstract

Batch experiments were conducted on ground water samples collected from a site contaminated with Cr(VI) to evaluate the redox potential of zero-valent iron (Fe0) nanoparticles for remediation of Cr(VI)-contaminated ground water. For this, various samples of contaminated ground water were allowed to react with various loadings of Fe0 nanoparticles for a reaction period of 60 min. Data showed 100% reduction of Cr(VI) in all the contaminated ground water samples after treatment with 0.20 gL−1 of Fe0 nanoparticles. An increase in the reduction of Cr(VI) from 45% to 100% was noticed with the increase in the loading of Fe0 nanoparticles from 0.05 to 0.20 gL−1. Reaction kinetics of Cr(VI) reduction showed pseudo first-order kinetics with rate constant in the range of 1.1 × 10−3 to 3.9 × 10−3 min−1. This work demonstrates the potential utility of Fe0 nanoparticles in treatment and remediation of Cr(VI)-contaminated water source.

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Acknowledgments

The authors are thankful to the Director, Indian Institute of Toxicology Research, Lucknow, for providing all necessary facilities for this work. Financial support from University Grant Commission (UGC), New Delhi, India, and Uttar Pradesh Council of Science and Technology is duly acknowledged. This is IITR publication no. 2952.

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Authors and Affiliations

  1. Ecotoxicology Division, Indian Institute of Toxicology Research (Council of Scientific and Industrial Research), Post Box 80, Mahatma Gandhi Marg, Lucknow, 226 001, UP, India

    Ritu Singh & Virendra Misra

  2. Department of Environmental Science, Babasaheb Bhimrao Ambedkar University, Rae Bareilly Road, Lucknow, 226 025, UP, India

    Ritu Singh & Rana Pratap Singh

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  1. Ritu Singh
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  2. Virendra Misra
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  3. Rana Pratap Singh
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Correspondence to Virendra Misra.

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Singh, R., Misra, V. & Singh, R.P. Removal of hexavalent chromium from contaminated ground water using zero-valent iron nanoparticles. Environ Monit Assess 184, 3643–3651 (2012). https://doi.org/10.1007/s10661-011-2213-5

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  • DOI: https://doi.org/10.1007/s10661-011-2213-5

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