Abstract
Luminescent and hydrophobic textile coatings with recyclability and self-healing capability against both chemical and physical damage were prepared, which present multi-functions and long service life cycles. The applications in self-cleaning, oil-water separation, and anti-counterfeit technology were successfully demonstrated. The coatings can be easily created onto different fabrics including cotton cloth, filter paper, and chemical fabric. A rare earth organic complex of SmTTAPhen(NO3)3 (STPN), silane modified epoxy oligomer, and bis(4-maleimidophenyl)methane (BMI) provide luminescence, hydrophobicity, as well as recyclability and self-healing capability, respectively, to the coatings. More specifically, high transparency but high luminescence were achieved due to the good dispersion of STPN in coating matrix, resulting from the hydron bonding between nitrate groups from STPN and hydroxyl groups from epoxy oligomer. Silane modification facilitated the accumulation of Si–O bonds on the free-surface of the coating, which offers hydrophobic features. The introduction of reversible Diels-Alder reactions provided the self-healing capability and recyclability. Upon heating using an electronic iron, the hydrophobicity can be recovered from physical or chemical damage to the coatings. Besides, the coatings on abandoned fabrics can be recycled and reused to a new bare fabric. We believe that the concept and coating materials are useful to further expand the areas of smart and multi-functional coatings with long service life.
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Blaiszik BJ, Sottos NR, White SR (2008) Nanocapsules for self-healing materials. Compos Sci Technol 68(3):978–986. https://doi.org/10.1016/j.compscitech.2007.07.021
Chen S, Li X, Li Y, Sun J (2015) Intumescent flame-retardant and self-healing superhydrophobic coatings on cotton fabric. ACS Nano 9(4):4070–4076. https://doi.org/10.1021/acsnano.5b00121
Chen D, Chen F, Zhang H, Yin X, Zhou Y (2016a) Preparation and characterization of novel hydro-phobic cellulose fabrics with polyvinylsilsesquioxane functional coatings. Cellulose 23(1):941–953. https://doi.org/10.1007/s10570-015-0820-y
Chen J, Fang L, Xu Z, Lu C (2016b) Self-healing epoxy coatings curing with varied ratios of diamine and monoamine triggered via near-infrared light. Prog Org Coat 101:543–552. https://doi.org/10.1016/j.porgcoat.2016.09.020
Chen K, Gou W, Xu L, Zhao Y (2018) Low cost and facile preparation of robust multifunctional coatings with self-healing superhydrophobicity and high conductivity. Compos Sci Technol 56:177–185. https://doi.org/10.1016/j.compscitech.2017.12.036
Cho EC, Chang-Jian CW, Chen HC, Chuang KS, Zheng JH, Hsiao YS, Lee KC, Huang JH (2017) Robust multifunctional superhydrophobic coatings with enhanced water/oil separation, self-cleaning, anti-corrosion, and anti-biological adhesion. Chem Eng J 314:347–357. https://doi.org/10.1016/j.cej.2016.11.145
Deng B, Cai R, Yu Y, Jiang H, Wang C, Li J, Li L, Yu M, Li J, Xie L (2010) Laundering durability of superhydrophobic cotton fabric. Adv Mater 22(48):5473–5477. https://doi.org/10.1002/adma.201002614
Erdman A, Kulpinski P, Grzyb T, Lis S (2016) Preparation of multicolor luminescent cellulose fibers containing lanthanide doped inorganic nanomaterials. J Lumin 169:520–527. https://doi.org/10.1016/j.jlumin.2015.02.049
Faghihnejad A, Feldman KE, Yu J, Tirrell MV, Israelachvili JN, Hawker CJ, Kramer EJ, Zeng H (2014) Adhesion and surface interactions of a self-healing polymer with multiple hydrogen-bonding groups. Adv Funct Mater 24(16):2322–2333. https://doi.org/10.1002/adfm.201303013
Fang L, Chen J, Zou Y, Xu Z, Lu C (2017) Thermally-induced self-healing behaviors and properties of four epoxy coatings with different network architectures. Polymers 9(8):333. https://doi.org/10.3390/polym9080333
Gu S, Yang L, Huang W, Bu Y, Chen D, Huang J, Zhou Y, Xu W (2017) Fabrication of hydropho-bic cotton fabrics inspired by polyphenol chemistry. Cellulose 24(6):2635–2646. https://doi.org/10.1007/s10570-017-1274-1
Guo X, Zhang K, Zhang H, Ge M (2018) Working conditions on the afterglow characteristics of rare-earth luminous fibers. Fiber Polym 19(3):531–537. https://doi.org/10.1007/s12221-018-7376-z
Hansen CJ, Wu W, Toohey KS, Sottos NR, White SR, Lewis JA (2009) Self-healing materials with interpenetrating microvascular networks. Adv Mater 21(41):4143–4147. https://doi.org/10.1002/adma.200900588
Hsieh HC, Chen JY, Lee WY, Bera D, Chen WC (2018) Stretchable fluorescent polyfluorene/acrylonitrile butadiene rubber blend electrospun fibers through physical interaction and geometrical confinement. Macromol Rapid Commun 39(5):1700616. https://doi.org/10.1002/marc.201700616
Ishida K, Yoshie N (2008) Synthesis of readily recyclable biobased plastics by Diels–Alder reaction. Macromol Biosci 8(10):916–922. https://doi.org/10.1002/mabi.200800078
Khattab TA, Rehan M, Hamdy Y, Shaheen TI (2018) Facile development of photoluminescent textile fabric via spray coating of Eu(II)-doped strontium aluminate. Ind Eng Chem Res 57(34):11483–11492. https://doi.org/10.1021/acs.iecr.8b01594
Ki HY, Kim JH, Kwon SC, Jeong SH (2007) A study on multifunctional wool textiles treated with nano-sized silver. J Mater Sci 42(19):8020–8024. https://doi.org/10.1007/s10853-007-1572-3
Kulpinski P, Erdman A, Grzyb T, Lis S (2016) Luminescent cellulose fibers modified with cerium fluoride doped with terbium particles. Polym Composite 37(1):153–160. https://doi.org/10.1002/pc.23166
Lai WJ, Cheng KC (2018) Crystallization and luminescence properties of polypropylene fiber containing rare earth aluminates and a sorbital derivative nucleating agent. Fiber Polym 19(1):22–30. https://doi.org/10.1007/s12221-018-1089-6
Li Y, Li L, Sun J (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Edit 122(35):6265–6269. https://doi.org/10.1002/anie.201001258
Li Y, Chen S, Wu M, Sun J (2014) All spraying processes for the fabrication of robust, self-healing, superhydrophobic coatings. Adv Mater 26(20):3344–3348. https://doi.org/10.1002/adma.201306136
Li Y, Ge B, Men X, Zhang Z, Xue Q (2016) A facile and fast approach to mechanically stable and rapid self-healing waterproof fabrics. Compos Sci Technol 125:55–61. https://doi.org/10.1016/j.compscitech.2016.01.021
Liu YL, Chuo TW (2013) Self-healing polymers based on thermally reversible Diels–Alder chemistry. Polym Chem 4(7):2194–2205. https://doi.org/10.1039/C2PY20957H
Liu Y, Xin JH, Choi CH (2012) Cotton fabrics with single-faced superhydrophobicity. Langmuir 28(50):17426–17434. https://doi.org/10.1021/la303714h
Ma M, Mao Y, Gupta M, Gleason KK, Rutledge GC (2005) Superhydrophobic fabrics produced by electrospinning and chemical vapor deposition. Macromolecules 38(23):9742–9748. https://doi.org/10.1021/ma0511189
Oehlenschlaeger KK, Mueller JO, Brandt J, Hilf S, Lederer A, Wilhelm M, Graf R, Coote ML, Schmidt FG, Barner-Kowollik C (2014) Adaptable hetero Diels–Alder networks for fast self-healing under mild conditions. Adv Mater 26(21):3561–3566. https://doi.org/10.1002/adma.201306258
Park HJ, Kim S, Lee JH, Kim HT, Seung W, Son Y, Kim TY, Khan U, Park NM, Kim SW (2019) Self-powered motion-driven triboelectric electroluminescence textile system. ACS Appl Mater Inter 11(5):5200–5207. https://doi.org/10.1021/acsami.8b16023
Pereira C, Alves C, Monteiro A, Magén C, Pereira AM, Ibarra A, Ibarra MR, Tavares PB, Araújo JP, Blanco G, Pintado JM, Carvalho AP, Pires J, Pereira MFR, Freire C (2011) Designing novel hybrid materials by one-pot co-condensation: from hydrophobic mesoporous silica nanoparticles to superamphiphobic cotton textiles. ACS Appl Mater Inter 3(7):2289–2299. https://doi.org/10.1021/am200220x
Pratama PA, Peterson AM, Palmese GR (2012) Diffusion and reaction phenomena in solution-based healing of polymer coatings using the Diels–Alder reaction. Macromol Chem Phys 213(2):173–181. https://doi.org/10.1002/macp.201100407
Pratama PA, Sharifi M, Peterson AM, Palmese GR (2013) Room temperature self-healing thermoset based on the Diels–Alder reaction. ACS Appl Mater Int 5(23):12425–12431. https://doi.org/10.1021/am403459e
Przybylak M, Maciejewski H, Dutkiewicz A (2016) Preparation of highly hydrophobic cotton fabrics by modification with bifunctional silsesquioxanes in the sol-gel process. Appl Surf Sci 387:163–174. https://doi.org/10.1016/j.apsusc.2016.06.094
Qian L, Sun G (2004) Durable and regenerable antimicrobial textiles: improving efficacy and du- rability of biocidal functions. J Appl Polym Sci 91(4):2588–2593. https://doi.org/10.1002/app.13428
Qiang S, Chen K, Yin Y, Wang C (2017) Robust UV-cured superhydrophobic cotton fabric surfaces with self-healing ability. Mater Design 116:395–402. https://doi.org/10.1016/j.matdes.2016.11.099
Roy N, Bruchmann B, Lehn JM (2015) DYNAMERS: dynamic polymers as self-healing material -s. Chem Soc Rev 44(11):3786–3807. https://doi.org/10.1002/chin.201530328
Samadzadeh M, Boura SH, Peikari M, Kasiriha SM, Ashrafi A (2010) A review on self-healing coatings based on micro/nanocapsules. Prog Org Coat 68(3):159–164. https://doi.org/10.1016/j.porgcoat.2010.01.006
Scheltjens G, Diaz MM, Brancart J, Van Assche G, Van Mele B (2013) A self-healing polymer network based on reversible covalent bonding. React Funct Polym 73(2):413–420. https://doi.org/10.1016/j.reactfunctpolym.2012.06.017
Shi Z, Wyman I, Liu G, Hu H, Zou H, Hu J (2013) Preparation of water-repellent cotton fabrics from fluorinated diblock copolymers and evaluation of their durability. Polymer 54(23):6406–6414. https://doi.org/10.1016/j.polymer.2013.09.043
Skwierczyńska M, Runowski M, Kulpiński P, Lis S (2019) Modification of cellulose fibers with inorganic luminescent nanoparticles based on lanthanide(III) ions. Carbohyd Polym 206(742–74):8. https://doi.org/10.1016/j.carbpol.2018.11.058
Suryaprabha T, Sethuraman MG (2017) Fabrication of copper-based superhydrophobic self-cleaning antibacterial coating over cotton fabric. Cellulose 24(1):395–407. https://doi.org/10.1007/s10570-016-1110-z
Varley RJ, van der Zwaag S (2008) Towards an understanding of thermally activated self-healing of an ionomer system during ballistic penetration. Acta Mater 56(19):5737–5750. https://doi.org/10.1016/j.actamat.2008.08.008
Wang X, Gao W, Xu S, Xu W (2012) Luminescent fibers: in situ synthesis of silver nanoclusters on silk via ultraviolet light-induced reduction and their antibacterial activity. Chem Eng J 210:585–589. https://doi.org/10.1016/j.cej.2012.09.034
Wang H, Chen L, Fang L, Li L, Fang J, Lu C, Xu Z (2018) Supramolecular hydrogel hybrids having high mechanical property, photoluminescence and light-induced shape deformation capability: design, preparation and characterization. Mater Des 160:194–202. https://doi.org/10.1016/j.matdes.2018.09.018
Wang H, Fang L, Zhang Z, Epaarachchi J, Li L, Hu X, Lu C, Xu Z (2019) Light-induced rare earth organic complex/shape-memory polymer composites with high strength and luminescence based on hydrogen bonding. Compos Part A-Appl S 125:105525. https://doi.org/10.1016/j.compositesa.2019.105525
Xi P, Zhao T, Xia L, Shu D, Ma M, Cheng B (2017) Fabrication and characterization of dual-functional ultrafine composite fibers with phase-change energy storage and luminescence properties. Sci Rep 7:40390. https://doi.org/10.1038/srep40390
Xiong Z, Lin H, Zhong Y, Qin Y, Li T, Liu F (2017) Robust superhydrophilic polylactide (PLA) membranes with a TiO2 nano-particle inlaid surface for oil/water separation. J Mater Chem A 5(14):6538–6545. https://doi.org/10.1039/C6TA11156D
Xue CH, Ji PT, Zhang P, Li YR, Jia ST (2013) Fabrication of superhydrophobic and superoleophilic textiles for oil–water separation. Appl Surf Sci 284:464–471. https://doi.org/10.1016/j.apsusc.2013.07.120
Xue CH, Zhang ZD, Zhang J, Jia ST (2014) Lasting and self-healing superhydrophobic surfaces by coating of polystyrene/SiO2 nanoparticles and polydimethylsiloxane. J Mater Chem A 2(36):15001–15007. https://doi.org/10.1039/c4ta02396j
Ye J, Wang B, Xiong J, Sun R (2016) Enhanced fluorescence and structural characteristics of car-boxymethyl cellulose/Eu(III) nano-complex: influence of reaction time. Carbohyd Polym 135(5):7–63. https://doi.org/10.1016/j.carbpol.2015.08.063
Ye H, Zhu L, Li W, Liu H, Chen H (2017) Simple spray deposition of a water-based superhydrophobic coating with high stability for flexible applications. J Mater Chem A 5(20):9882–9890. https://doi.org/10.1039/c7ta02118f
Yetisen AK, Qu H, Manbachi A, Butt H, Dokmeci MR, Hinestroza JP, Skorobogatiy M, Khadem- hosseini A A, Yun SH (2016) Nanotechnology in Textiles. ACS Nano 10(3):3042–3068. https://doi.org/10.1021/acsnano.5b08176
Yoo Y, You JB, Choi W, Im SG (2013) A stacked polymer film for robust superhydrophobic fabrics. Polym Chem 4(5):1664–1671. https://doi.org/10.1039/C2PY20963B
Yu H, Song H, Pan G, Li S, Liu Z, Bai X, Wang T, Lu S, Zhao H (2007) Preparation and luminescent properties of europium-doped yttria fibers by electrospinning. J Lumin 124(1):39–44. https://doi.org/10.1016/j.jlumin.2006.01.360
Zang X, Shen L, Pun E, Guo J, Lin H (2017) Photon quantification of electrospun europium-complexes/PMMA submicron fibers. J Alloy Compd 709:620–626. https://doi.org/10.1016/j.jallcom.2017.03.178
Zhang M, Li J, Zang D, Lu Y, Gao Z, Shi J, Wang C (2016) Preparation and characterization of cotton fabric with potential use in UV resistance and oil reclaim. Carbohyd Polym 137:264–270. https://doi.org/10.1016/j.carbpol.2015.10.087
Zhang Z, Chang H, Xue B, Han Q, Lü X, Zhang S, Li X, Zhu X, Wong W-K, Li K (2017) New transparent flexible nanopaper as ultraviolet filter based on red emissive Eu(III) nanofibrillated cellulose. Opt Mater 73:747–753. https://doi.org/10.1016/j.optmat.2017.09.039
Zhang H, Hou C, Song L, Ma Y, Ali Z, Gu J, Zhang B, Zhang H, Zhang Q (2018a) A stable 3D sol-gel network with dangling fluoroalkyl chains and rapid self-healing ability as a long-lived superhydrophobic fabric coating. Chem Eng J 334:598–610. https://doi.org/10.1016/j.cej.2017.10.036
Zhang Zh, Hj Wang, Liang Yh, Xj Li, Lq Ren, Zq Cui, Luo C (2018b) One-step fabrication of robust superhydrophobic and superoleophilic surfaces with self-cleaning and oil/water separation function. Sci Rep 8(1):3869. https://doi.org/10.1038/s41598-018-22241-9
Zhou X, Zhang Z, Xu X, Guo F, Zhu X, Men X, Ge B (2013a) Robust and durable superhydrophobic cotton fabrics for oil/water separation. ACS Appl Mater Int 5(15):7208–7214. https://doi.org/10.1021/am4015346
Zhou H, Wang H, Niu H, Gestos A, Lin T (2013b) Robust, self-healing superamphiphobic fabrics prepared by two-step coating of fluoro-containing polymer, fluoroalkyl silane, and modified silica nanoparticles. Adv Funct Mater 23(13):1664–1670. https://doi.org/10.1002/adfm.201202030
Zhou C, Chen Z, Yang H, Hou K, Zeng X, Zheng Y, Cheng J (2017) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl mater inter 9(10):9184–9194. https://doi.org/10.1021/acsami.7b00412
Zimmermann J, Artus GRJ, Seeger S (2007) Long term studies on the chemical stability of a sup-erhydrophobic silicone nanofilament coating. Appl Surf Sci 253(14):5972–5979. https://doi.org/10.1016/j.apsusc.2006.12.118
Zimmermann J, Reifler FA, Fortunato G, Gerhardt LC, Seeger S (2008a) A simple, one-step approach to durable and robust superhydrophobic textiles. Adv Funct Mater 18(22):3662–3669. https://doi.org/10.1002/adfm.200800755
Zimmermann J, Artus GRJ, Seeger S (2008b) Superhydrophobic silicone nanofilament coatings. J Adhes Sci Technol 22(3–4):251–263. https://doi.org/10.1163/156856108X305165
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This work was sponsored by Natural Science Foundation of Jiangsu Province (No. BK20191364) and National Natural Science Foundation of China (51503098). Financial support from Priority Academic Program Development of the Jiangsu Higher Education Institutions (PAPD) is gratefully acknowledged.
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Ma, Y., Zou, Y., Zhang, Z. et al. Luminescent and hydrophobic textile coatings with recyclability and self-healing capability against both chemical and physical damage. Cellulose 27, 561–573 (2020). https://doi.org/10.1007/s10570-019-02819-w
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DOI: https://doi.org/10.1007/s10570-019-02819-w