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Comparison of the Promoted CuZnMxOy (M: Ga, Fe) Catalysts for CO2 Hydrogenation to Methanol

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Abstract

Up to date, selective hydrogenation of undesirable CO2 to value-added chemicals is of great interest. To address this issue, the doped CuZnM (M: Ga, Fe) catalysts were synthesized by a facile microwave-assisted technique and its activity towards to CO2 hydrogenation were evaluated. Indeed, the characterization results revealed the positive impact of the promoters on Cu dispersion and the total basicity etc., which were critical for CO2 adsorption/conversion. Interestingly, the Fe dopants accelerated the formation of desirable C2+ oxygenates (ethanol and n-propanol).

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Acknowledgements

The financial support was provided by Natural Science Foundation of Liaoning Province (20170540073), General project from Department of education of Liaoning Province (2017J026) and Jiangsu Province Natural Science Foundation (BK 20170526).

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Authors and Affiliations

  1. Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, 116023, China

    Weijie Cai, Qing Chen, Shaoyin Zhang & Li Cui

  2. Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Zhongcheng Li

  3. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Hao Yu

  4. State Key Laboratory Breeding Base of Coal Science and Technology Co-founded by Shanxi Province and the Ministry of Science and Technology, Taiyuan University of Technology, Taiyuan, 030024, China

    Congming Li

  5. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China

    Fagen Wang

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  1. Weijie Cai
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Correspondence to Weijie Cai or Congming Li.

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Cai, W., Chen, Q., Wang, F. et al. Comparison of the Promoted CuZnMxOy (M: Ga, Fe) Catalysts for CO2 Hydrogenation to Methanol. Catal Lett 149, 2508–2518 (2019). https://doi.org/10.1007/s10562-019-02825-4

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  • DOI: https://doi.org/10.1007/s10562-019-02825-4

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