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Performance of the La–Mn–Zn–Cu–O Based Perovskite Precursors for Methanol Synthesis from CO2 Hydrogenation

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Abstract

A series of La–Mn–Zn–Cu–O based perovskite ceramic precursors were prepared and characterized by XRD, N2-adsorption, SEM, H2-TPR, N2O-adsorption, XPS and TPD techniques. Both La2CuO4 and LaMnO3 perovskite structures were observed for the materials and more defects and the “metal-on oxide” can be realized via reduction. It was found that the samples with both La2CuO4 and LaMnO3 structures showed better catalytic performance for methanol synthesis from CO2/H2. Higher methanol selectivity might due to the appearance of Cuα+ that derived from the abundant defects of perovskite structure. The ratio of both Cuα+ and Cu0 species to the total copper species was the significant factor for the CO2 conversion.

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Acknowledgments

This work was financially supported by the Natural Science Foundation of China (21343012), the National Key Technology Research and Development Program of the Ministry of Science and Technology (2013BAC11B00) as well as the Key Science and Technology Program of Shanxi Province, China (MD2014-10).

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Authors and Affiliations

  1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, South Taoyuan Road 27#, Taiyuan, 030001, People’s Republic of China

    Haijuan Zhan, Feng Li, Chunling Xin, Ning Zhao, Fukui Xiao, Wei Wei & Yuhan Sun

  2. University of the Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Haijuan Zhan & Chunling Xin

  3. National Engineering Research Center for Coal-based Synthesis, Institute of Coal Chemistry, Chinese Academy of Sciences, South Taoyuan Road 27#, Taiyuan, 030001, People’s Republic of China

    Ning Zhao & Fukui Xiao

  4. Center for Greenhouse Gas and Environmental Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201203, People’s Republic of China

    Wei Wei

  5. CAS Key Laboratory of Low-carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201203, People’s Republic of China

    Yuhan Sun

Authors
  1. Haijuan Zhan
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  2. Feng Li
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  3. Chunling Xin
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  4. Ning Zhao
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  5. Fukui Xiao
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  6. Wei Wei
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  7. Yuhan Sun
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Correspondence to Ning Zhao.

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Zhan, H., Li, F., Xin, C. et al. Performance of the La–Mn–Zn–Cu–O Based Perovskite Precursors for Methanol Synthesis from CO2 Hydrogenation. Catal Lett 145, 1177–1185 (2015). https://doi.org/10.1007/s10562-015-1513-8

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  • DOI: https://doi.org/10.1007/s10562-015-1513-8

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