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Preparation, Characterization and Reactivity of Keggin Type Phosphomolybdates, H3−2x Ni x PMo12O40 and (NH4)3−2x Ni x PMo12O40, for Adipic Acid Synthesis

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Abstract

Two H3−2x Ni x PMo12O40 and (NH4)3−2x Ni x PMo12O40 Keggin type heteroploysalts series (x: 0.25–1.5) were synthesized and characterized by IR spectroscopy, XR diffraction and thermal analysis (TG). Their catalytic properties were studied in the oxidation reaction of cylohexanone and cyclohexanone/cyclohexanol mixture to adipic acid in presence of hydrogen peroxide and in absence of solvent. The effects of catalyst/substrate molar ratios and heteropolysalt composition on AA yields were examined. TG analysis allowed to confirm the x value. Obtained catalytic results showed that both salts series are efficient for oxidation of cylohexanone and cyclohexanone/cyclohexanol mixture. Adipic acid yield achieved 45 % in the cyclohexanone oxidation in presence of (NH4)0.5Ni1.25PMo12O40 with a catalyst/substrate molar ratio of 10−3.

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Authors and Affiliations

  1. Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediène (USTHB), BP 32, El-Alia, Bab-Ezzouar, 16111, Alger, Algeria

    A. Tahar, S. Benadji, T. Mazari, L. Dermeche & C. Rabia

  2. Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri (UMMTO), 15000, Tizi-Ouzou, Algeria

    T. Mazari & L. Dermeche

  3. ILV-UMR 8180 CNRS, Bâtiment Lavoisier, Université de Versailles-St Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035, Versailles Cedex, France

    C. Marchal-Roch

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  1. A. Tahar
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  2. S. Benadji
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  3. T. Mazari
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  4. L. Dermeche
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  5. C. Marchal-Roch
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  6. C. Rabia
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Correspondence to C. Rabia.

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Tahar, A., Benadji, S., Mazari, T. et al. Preparation, Characterization and Reactivity of Keggin Type Phosphomolybdates, H3−2x Ni x PMo12O40 and (NH4)3−2x Ni x PMo12O40, for Adipic Acid Synthesis. Catal Lett 145, 569–575 (2015). https://doi.org/10.1007/s10562-014-1373-7

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  • DOI: https://doi.org/10.1007/s10562-014-1373-7

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