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Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst

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Abstract

Nickel modified Titanium silicalite 1 (TS-1) catalysts provided an environmentally benign and effective method for butadiene epoxidation. Certain loading of modified Ni in our system significantly promoted TS-1 catalytic activity. The product vinyloxirane (VO) was obtained with high yield of 0.49 mol/L (theoretic equilibrium value 0.52 mol/L). The turnover number (TON, determined as the molar VO obtained per molar Ti atom) reached 1,140. Besides, the catalyst kept high activity during five runs of reusability test. XRD, N2 adsorption and desorption, TPR, XPS, FT-IR and DR UV–Vis were employed to characterize the specific Ni role to Ti-site in Ni/TS-1 catalysts.

Graphical Abstract

Titanium silicalite 1 (TS-1) modified with different nickel contents as catalysts for the epoxidation of butadiene (BD) with hydrogen peroxide (H2O2). Vinyloxirane (VO) was obtained with high yield TON

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Acknowledgments

The authors sincerely acknowledge the financial support of the State Key Laboratory for Oxo Synthesis and Selective Oxidation of China.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, People’s Republic of China

    Mei Wu, Lingjun Chou & Huanling Song

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Mei Wu

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  1. Mei Wu
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  2. Lingjun Chou
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  3. Huanling Song
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Correspondence to Huanling Song.

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Wu, M., Chou, L. & Song, H. Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst. Catal Lett 142, 627–636 (2012). https://doi.org/10.1007/s10562-012-0792-6

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  • DOI: https://doi.org/10.1007/s10562-012-0792-6

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