Abstract
The system water–benzene–ethanol was used to illustrate the complexity of spontaneous emulsification, when water-poor emulsions are brought in contact with water. In the first case, an O/W emulsion located close to the plait point in the system was used. The aqueous phase in the emulsion was incompatible with water, and a strong spontaneous emulsification to an O/W between the two liquids took place in the water layer close to the interface between layers. In the second case, a W/O emulsion, also close to the plait point, was brought in contact with water. Now, the spontaneous emulsification between the water and the oil phase of the original emulsion to an O/W emulsion also took place in the water layer forming a distinct emulsion layer beneath the interface.
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Acknowledgments
The authors thank Hamdi Mango Center for Scientific Research for providing a very suitable and well-equipped working environment, where all the experiments took place in its laboratories, and the CIES Fulbright Specialist Program, Washington, DC, for a grant to SEF. This work was financially supported by the National Nature Science Foundation of China (no. 21073156, no. 21203162).
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Bozeya, A.A., Al-Bawab, A.F., Friberg, S.E. et al. Some experiments on complex spontaneous emulsification in the system water–benzene–ethanol. Colloid Polym Sci 291, 1933–1938 (2013). https://doi.org/10.1007/s00396-013-2932-y
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DOI: https://doi.org/10.1007/s00396-013-2932-y