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EDTA-grafted Cu2+-doped superparamagnetic nanoparticles: facile novel synthesis and their structural and magnetic characterizations

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Abstract

In this work, ethylenediaminetetraacetic acid (EDTA) surface grafting and copper(II) doping of superparamagnetic iron oxide nanoparticles (EDTA/Cu-SPIONs) were simultaneously performed during their formation by a simple electrochemical procedure. This method was achieved by applying a constant current of 10 mA/cm2 to the two-electrode electrochemical cell containing aqueous electrolyte of iron(II) chloride (0.75 g), iron(III) nitrate (2 g), copper(II)chloride (0.5 g) and 0.2 g EDTA. The prepared EDTA/Cu-SPION samples are specified by TEM, VSM, IR, EDS, FE-SEM, TGA and XRD analyses. The magnetite (i.e., Fe3O4) crystal structure (verified by the XRD results), 10 nm particle size (proved by TEM observations), 11 wt% doped copper (revealed though EDS data), and 10 wt% surface coat (calculated from the thermogravimetric data) were specified for the deposited SPION powder. IR data showed all the absorptions related to the chemical bonds (i.e., C–C, C–N, N–H, C–O) of EDTA and proved the EDTA-grafted configuration of the deposited SPIONs. VSM measurements exhibited the superparamagnetic behavior of the EDTA-grafted EDTA/Cu-SPION sample, where relative high saturation magnetization (Ms = 31.38 emu g−1), low remanence (Mr = 0.31 emu g−1) and negligible coercivity (Hci = 6.6 Oe) were observed. Based on the results, the developed route is introduced as a facile procedure for the preparation of EDTA-grafted metal ion-doped magnetite fine particles.

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Authors and Affiliations

  1. Materials and Nuclear Research School, Nuclear Science and Technology Research Institute (NSTRI), P.O. Box 14395-834, Tehran, Iran

    Mustafa Aghazadeh

  2. Department of Physics, Bonab Branch, Islamic Azad University, Bonab, Iran

    Isa Karimzadeh

  3. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran

    Mohammad Reza Ganjali & Davoud Gharailou

  4. Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

    Mohammad Reza Ganjali

  5. Scientific Research Center, Soran University, PO Box 624, Soran, Kurdistan Region, Iraq

    Samir M. Hamad

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  1. Mustafa Aghazadeh
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Aghazadeh, M., Karimzadeh, I., Ganjali, M.R. et al. EDTA-grafted Cu2+-doped superparamagnetic nanoparticles: facile novel synthesis and their structural and magnetic characterizations. Appl. Phys. A 125, 506 (2019). https://doi.org/10.1007/s00339-019-2803-6

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