Abstract:
The dynamical behavior of a polystyrene(Mw1)/polystyrene(Mw2)/toluene ternary mixture has been investigated by Dynamic Light Scattering (DLS) and Fluorescence Recovery After Photobleaching (FRAP). The experiments were made at several total polymer concentrations CT from dilute to semi-dilute range of concentration. In FRAP experiments, the dynamic of such a system is characterized by the existence of one relaxation mode identified to the self-diffusion coefficient Ds of the labelled polymer. This mode has been compared to the corresponding extracted Ds value from the two relaxation modes observed in DLS. The comparison between the results shows that in the semi-dilute range of concentration the agreement is good between both Ds values. As the concentration decreases, the agreement becomes less and less satisfactory, showing the limitation of the theory used to extract Ds from DLS measurements to the semi-dilute regime.
Similar content being viewed by others
References
Akcasu, A.Z.; Nägele, G.; Klein, R. Macromolecules 1991, 24, 4408.
Akcasu, A. Z. Dynamic Light Scattering: The method and Some Applications; Brown, W., Ed.; Oxford University Press: Oxford, U. K., 1993.
Benmouna, M.; Benoit, H.; Duval, M.; Akcasu, A.Z. Macromolecules 1987, 20, 1107.
Benmouna, M.; Benoit, H.; Borsali, R.; Duval, M. Macromolecules 1987, 20, 2620.
Foley, G.; Cohen, C. Macromolecules 1987, 20, 1891.
Akcasu, A.Z.; Tombakoglu, M. Macromolecules 1990, 23, 607.
Akcasu, A.Z.; Hammouda, B.; Lodge, T.P.; Han, C.C. Macromolecules 1984, 17, 759.
Daivis, P.; Snook, I.; van Megen, W.; Preston, B.N.; Comper, W.D. Macromolecules 1984, 17, 2376.
Borsali, R.; Duval, M.; Benoit, H.; Benmouna, M. Macromolecules 1987, 20, 1112.
Borsali, R.; Duval, M.; Benmouna, M. Macromolecules 1989, 22, 816.
Giebel, L.; Borsali, R.; Fischer, E.W.; Meier, G. Macromolecules 1990, 23, 4054.
Brown, W.; Konak, C.; Johnsen, R.M.; Zhou, P. Macromolecules 1990, 23, 901.
Giebel, L.; Benmouna, M.; Borsali, R.; Fischer, E. W. Macromolecules 1993, 26, 2433
Benmouna, M.; Benmansour, Z.; Fischer, E.W.; Benoit, H.; Vilgis, T.A. Journal of Polymer Science: Part B Polymer Physics 1992, 30, 733.
Brown, W.; Zhou, P. Macromolecules 1989, 22, 4031
Tinland, B.; Borsali, R. Macromolecules 1994, 27, 2141.
Lapp, A.; Beinert, G.; Picot, C. Makromol. Chem. 1984, 185, 453.
Feinberg, R.S.; Merrifield, R.B. Tetrahedron 1974, 30, 3209.
Duval, M.; Coles, H. J. Rev. Phys. Appl. 1980, 15, 1399.
Siegert, A.J. MIT, Rad. Lab. Rep. 1943, No. 465.
Provencher, S.W. Makromol. Chem. 1979, 180, 201.
Davoust, J.; Devaux, P.F.; Leger, L. EMBO Journal 1982, 1, 1233.
de Gennes P.G. “Scaling Concepts in Polymer Physics” Cornell University Press: Ithaca, New York, 1979.
Leger, L.; Hervet, H.; Rondelez, F. Macromolecules 1981, 14, 1334.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Meistermann, L., Duval, M. & Tinland, B. Self-diffusion coefficient studies in polystyrene/polystyrene/ toluene solutions: Dynamic light scattering and fluorescence recovery after photobleaching experiments. Polymer Bulletin 39, 101–108 (1997). https://doi.org/10.1007/s002890050126
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s002890050126