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Synthesis and characterization of modified resorcinol formaldehyde aerogel as a novel absorbent to remove oxytetracycline and chlortetracycline antibiotics from wastewater

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Abstract

Organic resorcinol formaldehyde (RF) aerogel was synthesized via the sol–gel process. The synthesized RF aerogel was modified by the incorporation of 1 and 3 wt.% of amine-functionalized graphene oxide (GO) during the synthesis process to prepare RF-GOA. The FTIR results showed that the functionalization of aerogels with amine was successfully conducted. The FESEM images showed that the interconnected 3D porous structure was created in the modified samples GO plates without affecting the porosity of the structure. The UV–Vis results showed that the RF-GOA1 and RF-GOA3 have improved the elimination amounts of antibiotics from 51 to 77% for oxytetracycline and from 65 to 94% for chlortetracycline. The absorption capacity for the neat RF aerogel, RF-GOA1, and RF-GOA3 was determined to be 258, 387, and 278 mg/g for oxytetracycline antibiotics and 326, 472, and 467 mg/g for the chlortetracycline antibiotics, respectively. Optimal pH for RF aerogel, RF-GOA1, and RF-GOA3 was obtained to be 6, 4, and 2 for oxytetracycline and 4, 2, and 6 for chlortetracycline, respectively. In addition, the adsorption data for modified aerogels were suited by the pseudo-second-order model, and the results showed that chemical adsorption was involved in the rapid absorption of antibiotics on modified aerogels.

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Authors and Affiliations

  1. Polymer Engineering Group, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran

    Alireza Behzadi & Ghodratollah Hashemi Motlagh

  2. Department of Mechanical Engineering, Faculty of Engineering, National University of Singapore, Singapore, 117581, Singapore

    Erfan Rezvani Ghomi, Amutha Chinnappan, Fatemeh Khosravi & Seeram Ramakrishna

  3. Department of Materials and Polymer Engineering, Faculty of Engineering, Hakim Sabzevari University, 9617976487, Sabzevar, Iran

    Rasoul Esmaeely Neisiany

  4. Department of Civil & Environmental Engineering, National University of Singapore, 1 Engineering Drive 2, Singapore, 117576, Singapore

    Iman Jafari

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Behzadi, A., Hashemi Motlagh, G., Rezvani Ghomi, E. et al. Synthesis and characterization of modified resorcinol formaldehyde aerogel as a novel absorbent to remove oxytetracycline and chlortetracycline antibiotics from wastewater. Polym. Bull. 79, 6309–6341 (2022). https://doi.org/10.1007/s00289-021-03812-9

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