Skip to main content
Log in

Preparation of antibacterial polyester–cotton absorbents; the effects of star-shaped functional oligomers

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

Antibacterial absorbent fabrics were prepared through by the immersion of polyester polyester–cotton fabrics in a soaking media, containing novel functional acrylic monomers and various antibacterial agents. 2-acrylamido 2-methyl propane sulfonic acid (AMPS) and a novel functional star-shaped oligomer (FSO) were used as monomers for inducing the absorbency and compatibility to the fabric. FSO in two steps and employing condensation reaction between glycerol and lactic acid via multi-step microwave irradiation was synthesized. Bio-based materials, such as gallic acid and tannic acid, were used as antibacterial agents to induce antibacterial activity to the cotton fabric. ATR-FTIR, H NMR, SEM, contact angle, as well as antibacterial activity, absorbency in distilled water and saline solution have been employed for further evaluation. The swelling capacity of the modified absorbent fabric H1 (AMPS/FSO: 50:/50 wt%) was up to 21.1 g/g−1 in distilled water, and 6.1 g/g−1 in saline solution. Antibacterial properties tests of these absorbent fabrics showed a good antibacterial behavior, against Staphylococcus aureus.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Scheme 2
Scheme 3
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Abbreviations

FSO:

Functional star-shaped oligomers

AMPS:

2-acrylamide-2-methyl propane sulfonic acid

APS:

Ammonium persulfate

PEGDA:

Polyethylene glycol diacrylate

TA:

Tannic acid

GA:

Gallic acid

LA:

Lactic acid

AA:

Acrylic acid

PTSA:

P-toluene sulfonic acid

Na OH:

Sodium hydroxide

PET:

Polyethylene terephthalate

References

  1. Zohuriaan-Mehr MJ, Kabiri K (2008) Superabsorbent polymer materials: a review. Iran Polym J 17(6):451

    CAS  Google Scholar 

  2. Moini N, Kabiri K, Zohuriaan-Mehr MJ, Esmaeili N (2016) Simple and efficient approach for recycling of fine acrylic-based superabsorbent waste. Polym Bull 73(4):1119–1133. https://doi.org/10.1007/s00289-015-1538-6

    Article  CAS  Google Scholar 

  3. Sabzevari A, Kabiri K, Siahkamari M (2016) Induced superabsorbency in polyester fiber. Iran Polym J 25(7):635–646. https://doi.org/10.1007/s13726-016-0454-4

    Article  CAS  Google Scholar 

  4. Amiri F, Kabiri K, Bouhendi H, Abdollahi H, Najafi V, Karami Z (2018) High gel-strength hybrid hydrogels based on modified starch through surface cross-linking technique. Polym Bull. https://doi.org/10.1007/s00289-018-2593-6

    Article  Google Scholar 

  5. Hans-Karl R (2000) Encyclopedia of textile finishing. Springer, Berlin, pp 235–242

    Google Scholar 

  6. Schindler WD, Hauser PJ (2004) Chemical finishing of textiles. Elsevier, New York

    Book  Google Scholar 

  7. Wu TH, Der Tai Y, Shen LH (2007) The novel methods for preparing antibacterial fabric composites containing nano-material. Solid State Phenom 124:1241–1244. https://doi.org/10.4028/www.scientific.net/SSP.124-126.1241

    Article  Google Scholar 

  8. Perelshtein I, Ruderman E, Francesko A, Fernandes MM, Tzanov T, Gedanken A (2014) Tannic acid NPs–synthesis and immobilization onto a solid surface in a one-step process and their antibacterial and anti-inflammatory properties. Ultrason Sonochem 21(6):1916–1920. https://doi.org/10.1016/j.ultsonch.2013.11.022

    Article  CAS  PubMed  Google Scholar 

  9. Hong KH (2014) Preparation and properties of multifunctional cotton fabrics treated by phenolic acids. Cellulose 21(3):2111–2117. https://doi.org/10.1007/s10570-014-0214-6

    Article  CAS  Google Scholar 

  10. Ninan N, Forget AA, Shastri VP, Voelcker NH, Blencowe A (2016) Antibacterial and anti-inflammatory pH-responsive tannic acid-carboxylated agarose composite hydrogels for wound healing. ACS Appl Mater Interfaces 8(42):28511–28521. https://doi.org/10.1021/acsami.6b10491

    Article  CAS  PubMed  Google Scholar 

  11. Jahandideh A, Esmaeili N, Muthukumarappan K (2018) Synthesis and characterization of novel star-shaped itaconic acid based thermosetting resins. J Polym Environ 26(5):2072–2085. https://doi.org/10.1007/s10924-017-1112-4

    Article  CAS  Google Scholar 

  12. Jahandideh A, Muthukumarappan K (2016) Synthesis, characterization and curing optimization of a biobased thermosetting resin from xylitol and lactic acid. Eur Polym J 83:344–358. https://doi.org/10.1016/j.eurpolymj.2016.08.033

    Article  CAS  Google Scholar 

  13. Zohuriaan-Mehr MJ et al (2019) Engineered green adhesives based on demands: star-shaped glycerol-lactic acid oligomers in anaerobic adhesives. ACS Sustain Chem Eng 7(19):16247–16256. https://doi.org/10.1021/acssuschemeng.9b03214

    Article  CAS  Google Scholar 

  14. Jahandideh A, Moini N, Kabiri K, Zohuriaan-Mehr MJ (2019) A green strategy to endow superabsorbents with stretchability and self-healability. Chem Eng J 370:274–286. https://doi.org/10.1016/j.cej.2019.03.149

    Article  CAS  Google Scholar 

  15. Jahandideh A, Esmaeili N, Muthukumarappan K (2017) Synthesis and characterization of novel star-shaped itaconic acid based thermosetting resins. J Polym Environ. https://doi.org/10.1007/s10924-017-1112-4

    Article  Google Scholar 

  16. Dabbaghi A, Jahandideh A, Kabiri K, Ramazani A, Zohuriaan-Mehr MJ (2019) The synthesis and incorporation of a star-shaped bio-based modifier in the acrylic acid based superabsorbent: a strategy to enhance the absorbency under load. Polym Technol Mater 58:1–13

    Google Scholar 

  17. Shahi S, Motasadizadeh HR, Zohuriaan-Mehr MJ (2017) Surface modification of superabsorbing hydrogels through a feasible esterification reaction: toward tunable superabsorbent for hygienic applications. Int J Polym Mater Polym Biomater 66(11):544–557. https://doi.org/10.1080/00914037.2016.1252348

    Article  CAS  Google Scholar 

  18. Sabzevari A, Kabiri K, Siahkamari M (2016) Induced superabsorbency in polyester fiber. Iran Polym J. https://doi.org/10.1007/s13726-016-0454-4

    Article  Google Scholar 

  19. Kabiri MAK et al (2018) Hybrid hydrogel based on pre-gelatinized starch modified with glycidyl-crosslinked microgel. Iran Polym J 27(3):183–192. https://doi.org/10.1007/s13726-018-0599-4

    Article  CAS  Google Scholar 

  20. Rosa F, Bordado J, Casquilho M (2010) Effect of the polymerization conditions on the swelling of a copolymer of AA/AMPS/BA via experimental design. J Appl Polym Sci 115(1):520–525. https://doi.org/10.1002/app

    Article  CAS  Google Scholar 

  21. Bollino F, Tranquillo E, Armenia E, Tranquillo E (2017) Zirconia/hydroxyapatite composites synthesized via sol-gel: influence of hydroxyapatite content and heating on their biological properties. Materials (Basel) 10(7):757. https://doi.org/10.3390/ma10070757

    Article  CAS  Google Scholar 

  22. Dabbaghi A, Jahandideh A, Kabiri K, Ramazani A, Zohuriaan-mehr MJ (2019) The synthesis and incorporation of a star-shaped bio-based modifier in the acrylic acid based superabsorbent: a strategy to enhance the absorbency under load. Polym Technol Mater 0881:1–13. https://doi.org/10.1080/25740881.2018.1563140

    Article  CAS  Google Scholar 

  23. Jahandideh A, Esmaeili N, Muthukumarappan K (2017) Effect of lactic acid chain length on thermomechanical properties of star-LA-xylitol resins and jute reinforced biocomposites. Polym Int 66(7):1021–1030

    Article  CAS  Google Scholar 

  24. Barrientos IJH et al (2017) Electrospun collagen-based nanofibres: a sustainable material for improved antibiotic utilisation in tissue engineering applications. Int J Pharm 531(1):67–79. https://doi.org/10.1016/j.ijpharm.2017.08.071

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. Kabiri.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Palizban, Z., Kabiri, K., Zohuriaan-Mehr, M.J. et al. Preparation of antibacterial polyester–cotton absorbents; the effects of star-shaped functional oligomers. Polym. Bull. 78, 4959–4975 (2021). https://doi.org/10.1007/s00289-020-03353-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-020-03353-7

Keywords

Navigation