Abstract
Acidified hydrazine hydrate was used to remediate Cr(VI)-contaminated soil. The content of water-soluble Cr(VI) in contaminated soil was 4977.53 mg/kg. The optimal initial pH of hydrazine hydrate solution, soil to solution ratio and molar ratio of Cr(VI) to hydrazine hydrate for remediation of Cr(VI)-contaminated soil were 5.0, 3:1 and 1:3, respectively. Over 99.50 % of water-soluble Cr(VI) in the contaminated soil was reduced at the optimal condition within 30 min. The remediated soil can keep stable within 4 months. Meanwhile the total phosphorus increased from 0.47 to 4.29 g/kg, indicating that using of acidified hydrazine hydrate is an effective method to remediate Cr(VI)-contaminated soil.
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References
Bagayoko M, George E, Römheld V, Buerkert A (2000) Effects of mycorrhizae and phosphorus on growth and nutrient uptake of millet, cowpea and sorghum on a West African soil. J Arg Sci 135:399–407
Barrera-Díaz CE, Lugo-Lugo V, Bilyeu B (2012) A review of chemical, electrochemical and biological methods for aqueous Cr(VI) reduction. J Hazard Mater 223:1–12
Ganguli A, Tripathi A (2002) Bioremediation of toxic chromium from electroplating effluent by chromate-reducing Pseudomonas aeruginosa A2Chr in two bioreactors. Appl Microbiol Biotechnol 58:416–420
Graham MC, Farmer JG, Anderson P, Paterson E, Hillier S, Lumsdon DG, Bewley RJ (2006) Calcium polysulfide remediation of hexavalent chromium contamination from chromite ore processing residue. Sci Total Environ 364:32–44
He Z, Gao F, Sha T, Hu Y, He C (2009) Isolation and characterization of a Cr(VI)-reduction Ochrobactrum sp. strain CSCr-3 from chromium landfill. J Hazard Mater 163:869–873
James BR (2001) Remediation-by-reduction strategies for chromate-contaminated soils. Environ Geochem Health 23:175–179
Krishna KR, Philip L (2005) Bioremediation of Cr(VI) in contaminated soils. J Hazard Mater 121:109–117
Ludwig RD, Su C, Lee TR, Wilkin RT, Acree SD, Ross RR, Keeley A (2007) In situ chemical reduction of Cr(VI) in groundwater using a combination of ferrous sulfate and sodium dithionite: a field investigation. Environ Sci Technol 41:5299–5305
Morse JL, Luczak MW, Zhitkovich A (2013) Chromium (VI) causes interstrand DNA cross-linking in vitro but shows no hypersensitivity in cross-link repair-deficient human cells. Chem Res Toxicol 26:1591–1598
Sultana MY, Akratos CS, Pavlou S, Vayenas DV (2014) Chromium removal in constructed wetlands: a review. Int Biodeterior Biodegrad 96:181–190
Thornton EC, Amonette JE (1999) Hydrogen sulfide gas treatment of Cr(VI)-contaminated sediment samples from a plating-waste disposal site implications for in situ remediation. Environ Sci Technol 33:4096–4101
Wang T, Xu H (2005) Reduction of Cr(VI) by hydrazine in solution saturated with KHCO3. J Hazard Mater 123:176–180
Wittbrodt PR, Palmer CD (1995) Reduction of Cr(VI) in the presence of excess soil fulvic acid. Environ Sci Technol 29:255–263
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This work was supported by a grant from the National Natural Science Foundation of China (41430637); Program for Innovative Research Team (in Science and Technology) in University of Henan Province (16IRTSTHN012); Research Fund Project of Henan University.
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Ma, Y., Li, F., Jiang, Y. et al. Remediation of Cr(VI)-Contaminated Soil Using the Acidified Hydrazine Hydrate. Bull Environ Contam Toxicol 97, 392–394 (2016). https://doi.org/10.1007/s00128-016-1862-z
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DOI: https://doi.org/10.1007/s00128-016-1862-z