Abstract
Four wells downgradient from a landfill near Elkhart, Indiana were sampled during 2000–2002 to evaluate the presence of waste-indicator and pharmaceutical compounds in landfill-leachate-affected ground water. Compounds detected in leachate-affected ground water included detergent metabolites (p-nonylphenol, nonylphenol monoethoxylate, nonylphenol diethoxylate, and octylphenol monoethoxylate), plasticizers (ethanol-2-butoxy-phosphate and diethylphthalate), a plastic monomer (bisphenol A), disinfectants (1,4-dichlorobenzene and triclosan), an antioxidant (5-methyl-1H-benzotriazole), three fire-retardant compounds (tributylphosphate and tri(2-chloroethyl)phosphate, and tri(dichlorisopropyl)phosphate), and several pharmaceuticals and metabolites (acetaminophen, caffeine, cotinine, 1,7-dimethylxanthine, fluoxetine, and ibuprofen). Acetaminophen, caffeine, and cotinine detections confirm prior indications of pharmaceutical and nicotinate disposal in the landfill.
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Barnes KK, Christenson SC, Kolpin DW, Focazio MJ, Furlong ET, Zaugg SD, Meyer MT, Barber LB (2004) Pharmaceuticals and other organic waste water contaminants within a leachate plume downgradient of a municipal landfill. Ground Water Monit R 24:119–126. doi:10.1111/j.1745-6592.2004.tb00720.x
Cahill JD, Furlong ET, Burkhardt MR, Kolpin DW, Anderson LG (2004) Determination of pharmaceutical compounds in surface- and ground-water samples by solid-phase extraction and high-performance liquid chromatography—electrospray ionization mass spectrometry. J Chromatogr A 1041:171–180. doi:10.1016/j.chroma.2004.04.005
Cordy G, Duran N, Bouwer H, Rice R, Kolpin DW, Furlong ET, Zaugg SD, Meyer MT, Barber LB (2004) Do pharmaceuticals, pathogens, and other organic waste water compounds persist when waste water is used for recharge? Ground Water Monit R 24:58–69. doi:10.1111/j.1745-6592.2004.tb00713.x
Duwelius RF, Silcox CA (1991) Ground-water levels, flow, and quality in northwestern Elkhart County, Indiana, 1980–89. US Geological Survey Water-Resources Investigations Report 91–4053:66 p. U.S. Geological Survey, Reston, VA, USA
Eganhouse RP, Cozzarelli IM, Scholl MA, Matthews LL (2001) Natural attenuation of volatile organic compounds in the leachate plume of a municipal landfill using alkylbenzenes as process probes. Ground Water 39:192–202. doi:10.1111/j.1745-6584.2001.tb02300.x
Focazio MJ, Kolpin DW, Barnes KK, Furlong ET, Meyer MT, Zaugg SD, Barber LB, Thurman ME (2008) A national reconnaissance for pharmaceuticals and other organic wastewater contaminants in the United States—II—Untreated drinking water sources. Sci Total Environ 402:201–206. doi:10.1016/jscitoenv.2008.02.021
Glassmeyer ST, Furlong ET, Kolpin DW, Cahill JD, Zaugg SD, Warner SL, Meyer MT, Kryak DD (2005) Transport of chemical and microbial compounds from known wastewater discharges: potential for use as indicators of human fecal contamination. Environ Sci Technol 39:5157–5169. doi:10.1021/es048120k
Holm JV, Ruegge K, Bjerg PJ, Christensen TH (1995) Occurrence and distribution of pharmaceutical organic compounds in the groundwater downgradient of a landfill (Grindsted, Denmark). Environ Sci Technol 29:1415–1420. doi:10.1021/es00005a039
Imbrigiotta TE, Martin A (1981) Hydrologic and chemical evaluation of the ground-water resources of northwest Elkhart County Indiana. US Geological Survey Water-Resources Investigations Report 81–53:140 p. U.S. Geological Survey, Reston, VA, USA
Kolpin DW, Furlong ET, Meyer MT, Thurman EM, Zaugg SD, Barber LB, Buxton HT (2002) Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999–2000. A national reconnaissance: Environ Sci Technol 36:1202–1211. doi:10.1021/es011055j
Meyer MT, Lee EA, Ferrell GF, Bumgarner JE, Varnes J (2007) Evaluation of tandem off-line and on-line solid-phase extraction with liquid chromatography/electrospray ionization-mass spectrometry for the analysis of antibiotics in ambient water and comparision to an independent method. US Geological Survey Scientific Investigations Report 2007–5021:28 p
Murray HE, Beck JN (1990) Concentrations of synthetic organic chemicals in leachate from a municipal landfill. Environ Pollut 67:195–203. doi:10.1016/0269-7491(90)90186-G
Oman C, Hynning PA (1993) Identification of organic compounds in municipal landfill leachates. Environ Pollut 80:265–271. doi:10.1016/0269-7491(93)90047-R
US Environmental Protection Agency (2002) Supplemental site investigations/site characterization report, Himco Dump Superfund site, Elkhart, Indiana, Dec 2002 vol 1
Zaugg SD, Smith SG, Schroeder MP, Barber LB, and Burkhardt MR (2002) Methods of analysis by the US geological survey national water quality laboratory—Determination of wastewater compounds by polystyrene-divinylbenzene solid-phase extraction and capillary-column gas chromatography/mass spectrometry. U.S. Geological Survey Water-Resources Investigations Report 01-4186:37 p
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Buszka, P.M., Yeskis, D.J., Kolpin, D.W. et al. Waste-Indicator and Pharmaceutical Compounds in Landfill-Leachate-Affected Ground Water near Elkhart, Indiana, 2000–2002. Bull Environ Contam Toxicol 82, 653–659 (2009). https://doi.org/10.1007/s00128-009-9702-z
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DOI: https://doi.org/10.1007/s00128-009-9702-z