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Characterization of conductive poly(acrylonitrile-co-vinyl acetate) composites: Matrix polymerization of pyrrole derivatives

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Abstract

In this study, poly(acrylonitrile-co-vinyl acetate) (P(AN-co-VAc)) composite films were prepared by chemical polymerization of pyrrole(Py), N-methyl pyrrole (NMPy) and N-phenyl pyrrole (NPhPy) with cerium(IV) [Ce(IV)] on P(AN-co-VAc) matrix. An increase was observed in the absorbances of CN ring stretching vibration (1451 cm−1) by introducing pyrrole (Py) derivatives on P(AN-co-VAc) matrix. The nitrile (CN) and carbonyl (C=O) groups played a significant role on the interactions with cationic sites of Py derivatives. Conductivity was increased in the presence of carbonyl (C=O) groups due to their additional negative charges on P(AN-co-VAc) matrix compared to PAN. Poly(N-Phenyl Pyrrole) (PNPhPy) exhibited higher dielectric constant and AC conductivity in the frequency range between the 10−2–107 Hz. The TGA results exhibited shifts of peak to higher temperatures by the presence of Py derivatives by increasing the weight loss %.

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References

  1. L. X. Wang, X. G. Li, and Y. L. Yang, React. Funct. Polym., 47, 125 (2001).

    Article  CAS  Google Scholar 

  2. J. O. Iroh and K. Levine, J. Power Sources, 117, 267 (2003).

    Article  CAS  Google Scholar 

  3. N. G. Sahoo, Y. C. Jung, H. H. So, and J. W. Cho, Synthetic Met., 157, 374 (2007).

    Article  CAS  Google Scholar 

  4. N. Li, D. Shan, and H. Xue, Eur. Polym. J., 43, 2532 (2007).

    Article  CAS  Google Scholar 

  5. L. M. Yee, A. Kassim, E. Mahmud, A. M. Sharif, and M. J. Haron, Malay. J. Anal. Sci., 11, 133 (2007).

    Google Scholar 

  6. Z. Zhang, R. Roy, F. J. Dugre, D. Tessier, and L. H. Dao, J. Biomed. Mater. Res., 57, 63 (2001).

    Article  CAS  Google Scholar 

  7. A. Kaynak and R. Beltran, Polym. Int., 52, 1021 (2003).

    Article  CAS  Google Scholar 

  8. J. Honey, M. T. Rinku, J. Joe, J. Rani, and K. T. Mathew, Micro. Opt. Techn. Let., 48, 1324 (2006).

    Article  Google Scholar 

  9. E. Hakansson, A. Amiet, and A. Kaynak, Synthetic Met., 156, 917 (2006).

    Article  CAS  Google Scholar 

  10. I. Cucchi, A Boschi, C. Arosio, F. Bertini, G. Freddi, and M. Catellani, Synthetic Met., 159, 246 (2009).

    Article  CAS  Google Scholar 

  11. S. H. Hossein, M. Dabiri, and M. Ashrafi, Polym. Int., 55, 1081 (2006).

    Article  Google Scholar 

  12. V. Panwar, B. Kang, J. O. Park, S. Park, and R. M. Mehra, Eur. Polym. J., 45, 1777 (2009).

    Article  CAS  Google Scholar 

  13. A. J. Epstein in “Conductive Polymers and Plastics” (L. Rupprecht Eds.), p.7, RTP Company Press, USA, 1999.

    Google Scholar 

  14. X. Li, X. Hao, H. Yu, and H. Na, Mater. Lett., 62, 1155 (2008).

    Article  CAS  Google Scholar 

  15. Y. Lee, D. Shin, J. Cho, Y. H. Park, Y. Son, and D. Y. Baik, J. Appl. Polym. Sci., 69, 2641 (1998).

    Article  CAS  Google Scholar 

  16. Y. Lee, D. Shin, J. Cho, Y. H. Park, Y. Son, and D. Y. Baik, Mol. Cryst. Liq. Cryst., 316, 313 (1998).

    Article  CAS  Google Scholar 

  17. Y. Xia and Y. Lu, Polym. Compos., 31, 340 (2010).

    CAS  Google Scholar 

  18. S. Cetiner, H. Karakas, R. Ciobanu, M. Olariu, N. U. Kaya, C. Unsal, F. Kalaoglu, and A. S. Sarac, Synthetic Met., 160, 1189 (2010).

    Article  CAS  Google Scholar 

  19. S. Cetiner, M. Olariu, R. Ciobanu, H. Karakas, F. Kalaoglu, and A. S. Sarac, Fiber. Polym., 11, 843 (2010).

    Article  CAS  Google Scholar 

  20. S. Cetiner, F. Kalaoglu, H. Karakas, and A. S. Sarac, Text. Res. J., 80, 1784 (2010).

    Article  CAS  Google Scholar 

  21. Q. Cheng, V. Pavlinek, C. Li, A. Lengalova, Y. He, and P. Saha, Appl. Surf. Sci., 253, 1736 (2006).

    Article  CAS  Google Scholar 

  22. N. V. Bhat, A. P. Gadre, and V. A. Bambole, J. Appl. Polym. Sci., 88, 22 (2003).

    Article  CAS  Google Scholar 

  23. M. Micusik, M. Omastova, K. Boukerma, A. Albouy, M. M. Chehimi, M. Trchova, and P. Fedorko, Polym. Eng. Sci., 47, 1198 (2007).

    Article  CAS  Google Scholar 

  24. L. Al-Mashat, H. D. Tran, W. Wlodarski, R. B. Kaner, and K. Kalantar-Zadeh, IEEE Sens. J., 8, 365 (2008).

    Article  CAS  Google Scholar 

  25. D. Sahin, B. Sar, and H. I. Unal, Turk. J. Chem., 26, 113, (2002).

    CAS  Google Scholar 

  26. M. I. Redondo, E. Sanchez de la Blanca, M. V. Garcia, M. A. Raso, J. Tortajada, and M. J. Gonzalez-Tejera, Synthetic Met., 122, 431 (2001).

    Article  CAS  Google Scholar 

  27. A. K. D. Diaw, A. Yassar, D. Gninngue-Sall, and J. J. Aaron, Arkivoc, 17, 122 (2008).

    Google Scholar 

  28. A. S. Sarac, S. Sezgin, M. Ates, and C. M. Turhan, Surf. Coat. Tech., 202, 3997 (2008).

    Article  CAS  Google Scholar 

  29. L. Ji, Y. Yao, O. Toprakci, Z. Lin, Y. Liang, Q. Shi, A. J. Medford, C. R. Millns, and X. Zhang, J. Power Sour., 195, 2050 (2010).

    Article  CAS  Google Scholar 

  30. S. V. Kasisomayajula, X. Qi, C. Vetter, K. Croes, and D. Pavlacky, J. Coat. Technol. Res., 7, 145 (2010).

    Article  CAS  Google Scholar 

  31. W. Chen, X. Li, G. Xue, Z. Wang, and W. Zou, Appl. Surf. Sci., 218, 215 (2003).

    Article  CAS  Google Scholar 

  32. D. K. Kim, K. W. Oh, H. J. Ahn, and S. H. Kim, J. Appl. Polym. Sci., 107, 3925 (2008).

    Article  CAS  Google Scholar 

  33. T. M. Wu, H. L. Chang, and Y. W. Lin, Polym. Int., 58, 1065 (2009).

    Article  CAS  Google Scholar 

  34. N. U. Kaya, M.Sc. Dissertation, ITU, Istanbul, 2010.

  35. M. S. Silverstein, Y. Najary, Y. Lumelsky, I. Lampe, G. S. Grader, and G. E. Shter, Polymer, 45, 937 (2004).

    Article  CAS  Google Scholar 

  36. Q. Cheng, Y. He, V. Pavlinek, C. Li, and P. Saha, Synthetic Met., 158, 9532 (2008).

    Article  Google Scholar 

  37. D. L. Sidebottom, B. Roling, and K. Funke, Phys. Rev. B., 63, 24301 (2000).

    Article  Google Scholar 

  38. H. Deligoz, T. Yalcinyuva, S. Ozgumus, and S. Yildirim, J. Appl. Polym. Sci., 100, 810 (2006).

    Article  CAS  Google Scholar 

  39. C. Hamciuc, E. Hamciuc, A. M. Ipate, and L. Okrasa, Polymer, 49, 681 (2008).

    Article  CAS  Google Scholar 

  40. S. A. Saafan, M. K. El-Nimr, and E. H. El-Ghazzawy, J. Appl. Polym. Sci., 99, 3370 (2006).

    Article  CAS  Google Scholar 

  41. M. M. Rao, J. S. Liub, W. S. Li, Y. Lianga, Y. H. Liao, and L. Z. Zhao, J. Power Sour., 189, 711 (2009).

    Article  CAS  Google Scholar 

  42. Z. Tian, X. M. He, W. H. Pu, C. R. Wan, and C. Y. Jiang, Electrochim. Acta., 52, 688 (2006).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Textile Engineering, Istanbul Technical University, Gumussuyu, 34437, Istanbul, Turkey

    Suat Cetiner, Fatma Kalaoglu, Hale Karakas & A. Sezai Sarac

  2. Department of Chemistry, Polymer Science and Technology, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey

    A. Sezai Sarac

Authors
  1. Suat Cetiner
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  2. Fatma Kalaoglu
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  3. Hale Karakas
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  4. A. Sezai Sarac
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Correspondence to A. Sezai Sarac.

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Cetiner, S., Kalaoglu, F., Karakas, H. et al. Characterization of conductive poly(acrylonitrile-co-vinyl acetate) composites: Matrix polymerization of pyrrole derivatives. Fibers Polym 12, 151–158 (2011). https://doi.org/10.1007/s12221-011-0151-z

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  • DOI: https://doi.org/10.1007/s12221-011-0151-z

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