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Improvement of Anticorrosion Properties of Epoxy Primer Coating on Aluminum Alloy 2024-T3 by Thiosemicarbazone Derivatives

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Abstract

The effect of adding thiosemicarbazone derivatives on the anticorrosion properties of epoxy primer coatings on aluminum alloy 2024-T3 was investigated. (E)-2-(2,4-dihydroxybenzylidene)hydrazinecarbothioamide (2,4-DHC), (E)-2-(3,4-dihydroxybenzylidene)hydrazinecarbothioamide (3,4-DHC), and (E)-2-(2,3,4-dihydroxybenzylidene)hydrazinecarbothioamide (2,3,4-THC) were supplemented to epoxy primer that is generally used in aircraft paint systems; and its anticorrosion property was examined by electrochemical impedance spectroscopy and salt spray test. Field emission scanning electron microscopy and energy dispersive x-ray analysis were used to study the surface topology of the coating system. 2,4-DHC and 3,4-DHC doped primer coating exhibits good barrier properties, while 2,3,4-THC doped primer coating exhibits good barrier properties along with active corrosion protection.

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Acknowledgements

The first author places on record his thankfulness to Director, NAL and NIITK, Suratkal for giving him an opportunity and facilities to pursue his doctoral degree. The help rendered by Mr. Siju, SED, NAL in obtaining the FE-SEM images is greatly acknowledged.

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Authors and Affiliations

  1. Surface Engineering Division, CSIR- National Aerospace Laboratories, Bangalore, Karnataka, 560 017, India

    B. G. Prakashiah & B. E. Amitha Rani

  2. Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Srinivasnagar, Mangalore, Karnataka, 575 025, India

    B. G. Prakashiah & A. Nityananda Shetty

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  1. B. G. Prakashiah
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Prakashiah, B.G., Nityananda Shetty, A. & Amitha Rani, B.E. Improvement of Anticorrosion Properties of Epoxy Primer Coating on Aluminum Alloy 2024-T3 by Thiosemicarbazone Derivatives. JOM 71, 4880–4890 (2019). https://doi.org/10.1007/s11837-019-03615-4

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