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Synthesis and properties of water-soluble CdSe/ZnS nanocrystals with the type-I core/shell structure

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Abstract

The synthesis of CdSe/ZnS core/shell nanocrystals though aqueous phase using the coprecipitation method was reported. The influences of factors such as injection methods and dosages of precursors, reaction duration of water-bathing and the initial CdSe:ZnS molar ratio were discussed. In comparison to the CdSe plain core nanocrystals, the CdSe/ZnS core/shell nanocrystals show much brighter photoluminescence demonstrated by the photoluminescence spectra. The epitaxial growth of the core/shell structures was verified by TEM and XRD.

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References

  1. Bailey R E, Smith A M, Nie Shuming. Quantum Dots in Biology and Medicine[J]. Phys. E., 2004, 25(1):1–12

    Article  CAS  Google Scholar 

  2. Qu L, Peng X. Control of Photoluminescence Properties of CdSe Nanocrystals in Growth[J]. J. Am. Chem. Soc., 2002, 124(9):2 049–2 055

    Article  CAS  Google Scholar 

  3. De Mello Donega C, Hickey S G, Wuister S F, et al. Single-step Synthesis to Control the Photoluminescence Quantum Yield and Size Dispersion of CdSe Nanocrystals[J]. J. Phys. Chem. B, 2003, 107(2):489–496

    Article  Google Scholar 

  4. Guo W, Li J J, Wang Y A, et al. Luminescent CdSe/CdS Core/Shell Nanocrystals in Dendron Boxes: Superior Chemical, Photochemical and Thermal Stability[J]. J. Am. Chem. Soc., 2003, 125(13):3 901–3 909

    Article  CAS  Google Scholar 

  5. Micic O I, Smith B B, Nozik A J. Core-shell Quantum Dots of Lattice-matched ZnCdSe2 Shells on InP Cores: Experiment and Theory[J]. J. Phys. Chem. B, 2000, 104(51):12 149–12 156

    Article  CAS  Google Scholar 

  6. Manna L, Scher E C, Li L-S, et al. Epitaxial Growth and Photochemical Annealing of Graded CdS/ZnS Shells on Colloidal CdSe Nanorods[J]. J. Am. Chem. Soc., 2002, 124(24): 7 136–7 145

    Article  CAS  Google Scholar 

  7. Tesster N, Medvedev V, Kazes M, et al. Efficient Near-infrared Polymer Nanocrystal Light-emitting Diodes[J]. Science, 2002 (295):1 506–1 508

  8. Peng X, Schlamp M C, Kadavanich A V, et al. Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility[J]. J. Am.Chem. Soc., 1997, 119(30):7 019–7 029

    Article  CAS  Google Scholar 

  9. WANG Deping, WANG Lu, Huang Wenhai. Selective Synthesis and Advaced Characteristic of CdSe Semiconductor Quantum Dots by Aqueous Phase[J]. Journal of Wuhan University of Technology-Mater.Sci. Ed., 2006, 21(1):32–37

    Article  Google Scholar 

  10. XIE Ying, XU Jingjuan, YU Junsheng, et al. Synthesis and Characterization of Water-soluble CdSe/ZnS Core-shell Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(6):663–667

    CAS  Google Scholar 

  11. Rogach A L, Kornowski A, Gao M Y. Synthesis and Characterization of a Size Series of Extremely Small Thiol-Stabilized CdSe Nanocrystals[J]. J. Phys. Chem. B, (Letter), 1999, 103(16):3 065–3 069

    CAS  Google Scholar 

  12. Joël Bleuse, Sophie Carayon, Peter Reiss. Optical Properties of Core/multishell CdSe/Zn(S, Se) Nanocrystals[J]. Phys. E., 2004, 21(2–4):331–335

    Article  CAS  Google Scholar 

  13. Chin I Lin, Abraham K Joseph, Chao Kang Chang, et al. Synthesis and Photoluminescence Study of Molecularly Imprinted Polymers Appended onto CdSe/ZnS Core-shells[J]. Biosensors and Bioelectronics, 2004, 20(1):127–131

    Article  PubMed  CAS  Google Scholar 

  14. LI J J, WANG Y A, GUO W, et al. Large-scale Synthesis of Nearly Monodisperse CdSe/CdS Core/Shell Nanocrystals Using Air-stable Reagents via Successive Ion Layer Adsorption and Reaction[J]. J. Am. Chem. Soc., 2003, 125(41): 12 567–12 575

    CAS  Google Scholar 

  15. Puls J, Rossin V V, Kreller F, et al. Bound and Bi-excitons in ZnCdSe/ZnSe Multiple Quantum Wells[J]. Journal of Crystal Growth, 1996, 159(1–4):784–787

    Article  ADS  CAS  Google Scholar 

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Correspondence to Deping Wang  (王德平).

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Funded by the National Natural Science Foundation of China (No. 5057 2072) and Nano Special Fouds from Science and Technology Commission of Shanghai Municipality (No. 0852nm05200)

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Wang, D., Yu, M., Huang, W. et al. Synthesis and properties of water-soluble CdSe/ZnS nanocrystals with the type-I core/shell structure. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 23, 600–605 (2008). https://doi.org/10.1007/s11595-007-5600-6

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  • DOI: https://doi.org/10.1007/s11595-007-5600-6

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