Abstract
A series of calcium containing silicate mixed oxide materials has been developed for biodiesel production. It has been shown that these materials can catalyze transesterification reactions from feedstocks with various fatty acid contents. However, their reaction kinetics for biodiesel synthesis was very slow compared to that of homogeneous-catalyst-catalyzed reactions. Herein, we report fast-reacting solid catalysts for biodiesel production. Two types of materials have been developed: a non-porous and an anionic-surfactant-templated catalysts. Compared to previously reported transesterification reaction by mesoporous calcium containing silicate catalysts, the reaction rates from both families were much faster. In addition, both the preparation time of catalysts and the cost of preparation were significantly reduced. Details in material synthesis and its effect on catalysis are discussed.
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References
Ma F, Hanna M (1999) Biodiesel production: a review. Bioresour Technol 70:1–15
Lin VSY, Nieweg JA, Verkade JG, Reddy Chinta RV, Kern C (2008) US Patent, Patent Publication Number US20080021232 A1
Pale-Grosdemange C, Simon ES, Prime KL, Whitesides GM (1991) J Am Chem Soc 113:12–20
Huo Q, Margolese DI, Ciesla U, Feng P, Gier TE, Sieger P, Leon R, Petroff PM, Schuth F, Stucky GD (1994) Nature 368:317–321
Che S, Garcia-Bennett AE, Yokoi T, Sakamoto K, Kunieda H, Terasaki O, Tatsumi T (2003) Nat Mater 2:801–805
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710–712
Zhao D, Feng J, Huo Q, Melosh N, Frederickson GH, Chmelka BF, Stucky GD (1998) Science 279:548–552
Venkat Reddy CR, Oshel R, Verkade JG (2006) Energ Fuel 20:1310–1314
Kouzu M, Yamanaka SY, Hidaka JS, Tsunomori M (2009) Appl Catal A 355:94–99
Garcia-Bennett AE, Kupferschmidt N, Sakamoto Y, Che S, Terasaki O (2005) Angew Chem Int Ed 44:5317–5322
Garcia-Bennett AE, Miyasaka K, Terasaki O, Che S (2004) Chem Mater 16:3597–3605
Gao C, Sakamoto Y, Sakamoto K, Terasaki O, Che S (2006) Angew Chem Int Ed 45:4295–4298
Gao C, Qiu H, Zeng W, Sakamoto Y, Terasaki O, Sakamoto K, Chen Q, Che S (2006) Chem Mater 18:3904–3914
Gao C, Sakamoto Y, Terasaki O, Che S (2008) Chem Eur J 14:11423–11428
Chen JJ, Thomas JJ, Taylor HFW, Jennings HM (2004) Cem Concr Res 34:1499–1519
Kruk M, Jaroniec M (2001) Chem Mater 13:3169–3183
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Hsin, TM., Chen, S., Guo, E. et al. Calcium Containing Silicate Mixed Oxide-Based Heterogeneous Catalysts for Biodiesel Production. Top Catal 53, 746–754 (2010). https://doi.org/10.1007/s11244-010-9462-3
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DOI: https://doi.org/10.1007/s11244-010-9462-3