Abstract
In terms of the ability for electrochemical transformations in acidic medium, the reactivity decreases in the order o-aminoacetophenone > p-aminoacetophenone > m-aminoacetophenone > aniline. The products of electrochemical polycondensation of the ortho and para isomers are conductors. Oxidative polycondensation of o-aminoacetophenone forms emeraldin hydrosulfate, and with p- and m-aminoacetophenones, emeraldin and leucoemeraldin are formed. In terms of thermal stability, polyacetoaminophenones can be ranked in the order poly-o-aminoacetophenone > poly-m-aminoacetophenone > poly-p-aminoacetophenone.
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REFERENCES
Stejskal, Ja., Spirkova, M., Riede, A., Helmstedt, M., Mokreva, P., and Prokes, J., Polymer, 1999, vol. 40, no.10, p. 2487.
Stejskal, Ja., Sapurina, I., Prokes, J., and Zemek, J., Synth. Metals, 1999, vol. 105, no.1, p. 195.
Koval’chuk, E.P., Stratan, N.V., Reshetnyak, O.V., Blazejowski, J., and Whittingham, M.S., Solid State Ionics, 2001, vols. 141–142, no.1, p. 217.
Guo, R., Bariebi, J.N., Innis, P.C., Too, C.O., Wallace, G.G., and Zhou, D., Synth. Metals, 2000, vol. 114, no.2, p. 267.
Yang, C.-H., J. Electroanal. Chem., 1998, vol. 459, no.1, p. 71.
Zhou D., Innis, P.C., Wallace, G.G., Shimizu, Sh., and Maeda, Sh., Synth. Metals, 2000, vol. 114, no.2, p. 287.
Glarum, S.H. and Marshall, J.-H., J. Electrochem. Soc., 1987, vol. 134, no.9, p. 2160.
Kuramoto, N. and Tomita, A., Synth. Metals, 1997, vol. 88, no.1, p. 147.
Aksiment’eva, O.I., Elektrohimichni metodi sintezu ta providnisti spryazhenih pol’mer’v (Electrochemical Methods of Synthesis and Conductivity of Conjugated Polymers), Lvov: Svit, 1998.
Faez, R. and De Paoli, M.-A., Eur. Polymer J., 2001, vol. 37, no.7, p. 1139.
Trchova, M., Stejskal, J., and Prokes, J., Synth. Metals, 1999, vol. 101, no.4, p. 840.
Novak, P., Muller, K., Santhanom, K.S.V., and Haas, O., Chem. Rev., 1997, vol. 97, no.2, p. 207.
Gurunathan, K., Murugan, A.V., Marimuthu, R., Mulik, U.P., and Amalnerkar, D.P., Mater. Chem. Phys., 1999, vol. 61, no.1, p. 173.
Batich, C.D., Laitinen, H.A., and Zhou, H.C., J. Electrochem. Soc., 1990, vol. 137, no.4, p. 883.
Koul, S., Dhavan, S.K., Chandra, S., and Chandra, R., Indian J. Chem., Sect. A, 1987, vol. 37, no.4, p. 901.
Koul, S., Chandra, R., and Dhavan, S.K., Sensors Actuators B, 2001, vol. 75, no.1, p. 151.
Meijerink, M.G.H., Strike, D.J., De Rooij, N.F., and Kondelna-Hep, M., Sensors Actuators B, 2000, vol. 68, no.2, p. 331.
Bertrand, C., Coulet, P., and Gaubehran, P.C., Anal. Chem. Acta, 1981, vol. 126, no.1, p. 23.
Antonovskii, V.L., Organicheskie perekisnie initsiatory (Organic Peroxide Initiators), Moscow: Khimiya, 1972, p. 447.
Elektrohimiya polimerov (Electrochemistry of Polymers), Tarasevich, M.R., Orlova, S.B., and Shkol’nikova, E.I., Eds., Moscow: Nauka, 1990, p. 236.
Vinokurov, I.A., Bertsev, V.V., and Karshina, E.A., Elektrokhimiya, 1990, vol. 26, no.3, p. 311.
Kwon, O. and McKee, M.L., J. Phys. Chem., 2000, vol. 104, no.11, p. 1686.
Bühler, K.-U., Spezialplaste, Berlin: Akademie, 1984. Translated under the title Teplo-i termostoikie polimery, Moscow: Khimiya, 1984, p. 1056.
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 12, 2004, pp. 2012–2018.
Original Russian Text Copyright © 2004 by Stratan, Koval’chuk, Blazejowski.
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Stratan, N.V., Koval’chuk, E.P. & Blazejowski, J. Synthesis, structure, and properties of isomeric polyaminoacetophenones. Russ J Gen Chem 74, 1900–1906 (2004). https://doi.org/10.1007/s11176-005-0115-3
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DOI: https://doi.org/10.1007/s11176-005-0115-3