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The use of carboranylphosphite ligands in Rh-catalyzed hydroformylation of alkenes in supercritical carbon dioxide

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Abstract

Novel carborane-containing phosphites were synthesized. The efficiency of the ligands was tested in the Rh-catalyzed hydroformylation of styrene, hept-1-ene, and oct-1-ene in super-critical carbon dioxide (scCO2) and toluene. The use of scCO2 as the reaction medium allows one to attain higher conversions and regioselectivities compared to toluene.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, P. V. Petrovskii, E. A. Rastorguev, T. A. Verbitskaya, V. N. Kalinin & V. A. Davankov

Authors
  1. S. E. Lyubimov
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  2. P. V. Petrovskii
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  3. E. A. Rastorguev
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  4. T. A. Verbitskaya
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  5. V. N. Kalinin
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  6. V. A. Davankov
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Corresponding author

Correspondence to S. E. Lyubimov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2037–2040, October, 2011.

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Lyubimov, S.E., Petrovskii, P.V., Rastorguev, E.A. et al. The use of carboranylphosphite ligands in Rh-catalyzed hydroformylation of alkenes in supercritical carbon dioxide. Russ Chem Bull 60, 2074–2077 (2011). https://doi.org/10.1007/s11172-011-0316-3

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  • DOI: https://doi.org/10.1007/s11172-011-0316-3

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