Abstract
Boron carbide is a low-density ceramic with high hardness and stiffness values that make it a valuable candidate for light armor applications. Fully dense boron carbide is fabricated by hot pressing of fine (<2 µm) powder at a relatively high temperature (2150–2200°C). Fully dense boron carbide can be processed from an initial mixture of 5.5 vol.% Fe and low-cost B4C powder by spark plasma sintering (SPS) at 2000°C. At this temperature, Fe-free boron carbide can be consolidated only to 96% of the theoretical density. The effect of the Fe addition on the densities is even more pronounced at lower processing temperatures and is related to the presence of a liquid phase in the Fe-containing material. The resulting microstructure and mechanical properties of the Fe-containing boron carbide are presented and discussed.
Similar content being viewed by others
References
F. Thévenot, “Boron carbide—A comprehensive review,” J. Eur. Cer. Soc., No. 6, 205 (1990).
R. W. Cahn, P. Haasen, and E. J. Kramer (ed.), “Material science and technology, structure and properties of ceramics,” VCH, No. 11, 177–212 (1994).
J. Kreigesmann, Patent DE3711871 C2, German (1989).
L. Levin, N. Frage, and M. P. Dariel, “The effect of Ti and TiO2 additions on the pressureless sintering of B4C,” Metal. Mater. Trans., 30 (1999).
R. G. Lange and Z. A. Munir, in: G. C. Kuczynski (ed.), Proc. 5th Int. Conf. on Sintering and Related Phenomena (June 1979, Indiana), Plenum, New York (1979), p. 311.
D. C. Halverson, A. J. Pyzik, I. A. Aksay, and W. E. Snowden, “Processing of boron carbide-aluminum composites,” J. Am. Ceram. Soc., 72 (1989).
R. Telle and G. Petzov, “Mechanism in the liquid phase sintering of boron carbide with silicon based melts,” in: High Tech Ceramics, Elsevier Publishers, Amsterdam (1987), pp. 961–973.
I. Mizrahi, A. Raviv, H. Dilman, M. Aizenshtein, M. P. Dariel, and N. Frage, “The effect of Fe addition on processing and mechanical properties of reaction infiltrated boron carbide-based composites,” J. Mater. Sci., 42(16) (2007).
Z. A. Munir, U. Anselmi-Tamburini, and M. Ohyanagi, “The effect of electric field and pressure on the synthesis and consolidation of materials: A review of the spark plasma sintering method,” J. Mater. Sci., 41, 763–777 (2006).
M. Aizenshtein, I. Mizrahi, N. Froumin, et al., “Interface interaction in the B4C/(Fe-B-C) system,” in: Proc. 5th Int. Conf. on High Temperature Capillarity (HTC5) (March 23–26, 2007), Alicante, Spain (2007).
S. Hayun, N. Frage, H. Dilman, et al., “Synthesis of dense B4C-SiC-TiB2 composites,” Ceramic Trans., 178, 37–44 (2006).
N. Frage, M. Bizbi, and M. P. Dariel, “The effect of Cr2O3 and CrB2 additions on the pressureless sintering of B4C preforms,” Science of Sintering, 33, No. 3, 149–158 (2001).
J. D. Eshelby, “The determination of the elastic field of an ellipsoidal inclusion, and related problems,” Proc. Royal Society of London, Ser. A, Mathematical and Physical Sciences, 241 (1226), 376–396 (1957).
Author information
Authors and Affiliations
Additional information
Published in Poroshkovaya Metallurgiya, Vol. 46, No. 11–12 (458), pp. 23–29, 2007.
Rights and permissions
About this article
Cite this article
Frage, N., Hayun, S., Kalabukhov, S. et al. The effect of Fe addition on the densification of B4C powder by spark plasma sintering. Powder Metall Met Ceram 46, 533–538 (2007). https://doi.org/10.1007/s11106-007-0082-9
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11106-007-0082-9