Abstract
Conventional plastics has a large impact in increasing the environment’s pollution. That’s why the interest has turned towards novel partially and completely biodegradable polymers. In this work, blends of polystyrene and thermoplastic starch with glycerol and Buriti (Mauritia flexuosa L.) oil as plasticizers were prepared. Samples were analyzed using TG/DTG and DSC techniques. The TG results indicated that the blends with Buriti oil are thermally more stable than those with glycerol. The DSC analysis that Buriti oil provides a higher degree of plasticization of PS, compared to the blends plasticized using glycerol under the studied conditions.
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References
D Raghavan (1995) Polym. Plast. Technol. Eng. 34 41 Occurrence Handle1:CAS:528:DyaK2MXkt1Cgs7o%3D
FJ Rodriguez-Gonzalez BA Ramsay BD Favis (2003) Polymer 44 1517 Occurrence Handle10.1016/S0032-3861(02)00907-2 Occurrence Handle1:CAS:528:DC%2BD3sXhtFCmurc%3D
I Arvanitoyannis CG Biliaderis (1999) Carbohydr. Polym. 38 47 Occurrence Handle10.1016/S0144-8617(98)00087-3 Occurrence Handle1:CAS:528:DyaK1MXmslSktQ%3D%3D
S Kiatkamjornwong M Sonsuk S Wittayapichet P Prasassarakich P-C Vejjanukroh (1999) Polym. Degrad. Stab. 66 323 Occurrence Handle10.1016/S0141-3910(99)00082-8 Occurrence Handle1:CAS:528:DyaK1MXntF2nsb0%3D
P Aggarwal (1999) Thermochim. Acta 340–341 195 Occurrence Handle10.1016/S0040-6031(99)00264-6
P Aggarwal D Dollimore K Heon (1997) J. Thermal Anal. 50 7 Occurrence Handle10.1007/BF01979545 Occurrence Handle1:CAS:528:DyaK2sXmsVKitrY%3D
C Bastioli et al. (1995) Degradable Polymers Chapman and Hall Cambridge 112
LF França G Reber MAM Meireles NT Machado SGC Moreira (1999) J. Supercrit. Fluids 14 247 Occurrence Handle10.1016/S0896-8446(98)00122-3
MLS Albuquerque I Guedes P Alcântara SGC Moreira NMB Neto DS Correa SC Zílio (2005) J. Braz. Chem. Soc. 16 1113 Occurrence Handle10.1590/S0103-50532005000700004 Occurrence Handle1:CAS:528:DC%2BD2MXhtleksLbJ
J. A. Durães, A. L. Drummond, T. A. P. F. Pimentel, M. M. Murta, S. G. C. Moreira, F. S. Bicalho and M. J. A. Sales, Eur. Polym. J., (2006), in press.
JA Duraes MJA Sales RF Souto A Romariz JC da Costa AM Ceschin SGC Moreira (2006) Appl. Phys. Lett. 89 133502 Occurrence Handle10.1063/1.2356097 Occurrence Handle1:CAS:528:DC%2BD28XhtVyltLjK
J Chrastil (1987) Carbohydr. Res. 159 154 Occurrence Handle10.1016/S0008-6215(00)90013-2 Occurrence Handle1:CAS:528:DyaL2sXhtlOjuro%3D
BA Ramsay V Langlade PJ Carreau JA Ramsay (1993) Appl. Environ. Microbiol. 59 1244
J Lorcks (1998) Polym. Degrad. Stab. 59 245 Occurrence Handle10.1016/S0141-3910(97)00168-7 Occurrence Handle1:CAS:528:DyaK1cXjs1OqtbY%3D
B Wunderlich et al. (1990) Thermal Analysis Academic Press, Inc. Boston
AJF Carvalho AAS Curvelo JAM Agnelli (2001) Carbohydr. Polym. 45 189 Occurrence Handle10.1016/S0144-8617(00)00315-5
D Lourdin H Bizot P Colonna (1996) J. Appl. Polym. Sci. 63 1047 Occurrence Handle10.1002/(SICI)1097-4628(19970222)63:8<1047::AID-APP11>3.0.CO;2-3
Z Zhong XS Sun (2005) J. Food Eng. 69 453 Occurrence Handle10.1016/j.jfoodeng.2004.07.023
A Garcia-Quiroz SGC Moreira AV de Morais AS Silva GN Rocha P Alcântara (2003) Instrum. Sci. Technol. 31 93 Occurrence Handle10.1081/CI-120018411 Occurrence Handle1:CAS:528:DC%2BD3sXisFKisL4%3D
P Tandon G Förster R Neubert S Wartewig (2000) J. Mol. Struct. 524 201 Occurrence Handle10.1016/S0022-2860(00)00378-1 Occurrence Handle1:CAS:528:DC%2BD3cXjtVGjsbY%3D
FO Cedeno MM Prieto A Espina JR Garcia (2001) Thermochim. Acta 369 39 Occurrence Handle10.1016/S0040-6031(00)00752-8 Occurrence Handle1:CAS:528:DC%2BD3MXhvFKitbw%3D
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Schlemmer, D., de Oliveira, E.R. & Araújo Sales, M.J. Polystyrene/thermoplastic starch blends with different plasticizers. J Therm Anal Calorim 87, 635–638 (2007). https://doi.org/10.1007/s10973-006-7776-y
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DOI: https://doi.org/10.1007/s10973-006-7776-y