Skip to main content
Log in

Polystyrene/thermoplastic starch blends with different plasticizers

Preparation and thermal characterization

  • regular
  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Conventional plastics has a large impact in increasing the environment’s pollution. That’s why the interest has turned towards novel partially and completely biodegradable polymers. In this work, blends of polystyrene and thermoplastic starch with glycerol and Buriti (Mauritia flexuosa L.) oil as plasticizers were prepared. Samples were analyzed using TG/DTG and DSC techniques. The TG results indicated that the blends with Buriti oil are thermally more stable than those with glycerol. The DSC analysis that Buriti oil provides a higher degree of plasticization of PS, compared to the blends plasticized using glycerol under the studied conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D Raghavan (1995) Polym. Plast. Technol. Eng. 34 41 Occurrence Handle1:CAS:528:DyaK2MXkt1Cgs7o%3D

    CAS  Google Scholar 

  2. FJ Rodriguez-Gonzalez BA Ramsay BD Favis (2003) Polymer 44 1517 Occurrence Handle10.1016/S0032-3861(02)00907-2 Occurrence Handle1:CAS:528:DC%2BD3sXhtFCmurc%3D

    Article  CAS  Google Scholar 

  3. I Arvanitoyannis CG Biliaderis (1999) Carbohydr. Polym. 38 47 Occurrence Handle10.1016/S0144-8617(98)00087-3 Occurrence Handle1:CAS:528:DyaK1MXmslSktQ%3D%3D

    Article  CAS  Google Scholar 

  4. S Kiatkamjornwong M Sonsuk S Wittayapichet P Prasassarakich P-C Vejjanukroh (1999) Polym. Degrad. Stab. 66 323 Occurrence Handle10.1016/S0141-3910(99)00082-8 Occurrence Handle1:CAS:528:DyaK1MXntF2nsb0%3D

    Article  CAS  Google Scholar 

  5. P Aggarwal (1999) Thermochim. Acta 340–341 195 Occurrence Handle10.1016/S0040-6031(99)00264-6

    Article  Google Scholar 

  6. P Aggarwal D Dollimore K Heon (1997) J. Thermal Anal. 50 7 Occurrence Handle10.1007/BF01979545 Occurrence Handle1:CAS:528:DyaK2sXmsVKitrY%3D

    Article  CAS  Google Scholar 

  7. C Bastioli et al. (1995) Degradable Polymers Chapman and Hall Cambridge 112

    Google Scholar 

  8. LF França G Reber MAM Meireles NT Machado SGC Moreira (1999) J. Supercrit. Fluids 14 247 Occurrence Handle10.1016/S0896-8446(98)00122-3

    Article  Google Scholar 

  9. MLS Albuquerque I Guedes P Alcântara SGC Moreira NMB Neto DS Correa SC Zílio (2005) J. Braz. Chem. Soc. 16 1113 Occurrence Handle10.1590/S0103-50532005000700004 Occurrence Handle1:CAS:528:DC%2BD2MXhtleksLbJ

    Article  CAS  Google Scholar 

  10. J. A. Durães, A. L. Drummond, T. A. P. F. Pimentel, M. M. Murta, S. G. C. Moreira, F. S. Bicalho and M. J. A. Sales, Eur. Polym. J., (2006), in press.

  11. JA Duraes MJA Sales RF Souto A Romariz JC da Costa AM Ceschin SGC Moreira (2006) Appl. Phys. Lett. 89 133502 Occurrence Handle10.1063/1.2356097 Occurrence Handle1:CAS:528:DC%2BD28XhtVyltLjK

    Article  CAS  Google Scholar 

  12. J Chrastil (1987) Carbohydr. Res. 159 154 Occurrence Handle10.1016/S0008-6215(00)90013-2 Occurrence Handle1:CAS:528:DyaL2sXhtlOjuro%3D

    Article  CAS  Google Scholar 

  13. BA Ramsay V Langlade PJ Carreau JA Ramsay (1993) Appl. Environ. Microbiol. 59 1244

    Google Scholar 

  14. J Lorcks (1998) Polym. Degrad. Stab. 59 245 Occurrence Handle10.1016/S0141-3910(97)00168-7 Occurrence Handle1:CAS:528:DyaK1cXjs1OqtbY%3D

    Article  CAS  Google Scholar 

  15. B Wunderlich et al. (1990) Thermal Analysis Academic Press, Inc. Boston

    Google Scholar 

  16. AJF Carvalho AAS Curvelo JAM Agnelli (2001) Carbohydr. Polym. 45 189 Occurrence Handle10.1016/S0144-8617(00)00315-5

    Article  Google Scholar 

  17. D Lourdin H Bizot P Colonna (1996) J. Appl. Polym. Sci. 63 1047 Occurrence Handle10.1002/(SICI)1097-4628(19970222)63:8<1047::AID-APP11>3.0.CO;2-3

    Article  Google Scholar 

  18. Z Zhong XS Sun (2005) J. Food Eng. 69 453 Occurrence Handle10.1016/j.jfoodeng.2004.07.023

    Article  Google Scholar 

  19. A Garcia-Quiroz SGC Moreira AV de Morais AS Silva GN Rocha P Alcântara (2003) Instrum. Sci. Technol. 31 93 Occurrence Handle10.1081/CI-120018411 Occurrence Handle1:CAS:528:DC%2BD3sXisFKisL4%3D

    Article  CAS  Google Scholar 

  20. P Tandon G Förster R Neubert S Wartewig (2000) J. Mol. Struct. 524 201 Occurrence Handle10.1016/S0022-2860(00)00378-1 Occurrence Handle1:CAS:528:DC%2BD3cXjtVGjsbY%3D

    Article  CAS  Google Scholar 

  21. FO Cedeno MM Prieto A Espina JR Garcia (2001) Thermochim. Acta 369 39 Occurrence Handle10.1016/S0040-6031(00)00752-8 Occurrence Handle1:CAS:528:DC%2BD3MXhvFKitbw%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. J. Araújo Sales.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schlemmer, D., de Oliveira, E.R. & Araújo Sales, M.J. Polystyrene/thermoplastic starch blends with different plasticizers. J Therm Anal Calorim 87, 635–638 (2007). https://doi.org/10.1007/s10973-006-7776-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7776-y

Keywords

Navigation