Skip to main content
SpringerLink
Log in

Kinetics of dispersion polymerization of dimethyl diallyl ammonium chloride and acrylamide

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Dispersion copolymerization of dimethyl diallyl ammonium chloride with acrylamide has been investigated by the dilatometer technique using the mixture of poly(vinylpyrrolidone) and poly(dimethyl diallyl ammonium chloride) as the composite stabilizer and 2,2′-azobis(2-methylpropionconidine)dihydro chloride as the initiator. Monomer reactivity ratios of AM and DMDAAC were determined by the application of Fineman-Ross methods. The analysis of reactivity ratios revealed that DMDAAC is less reactive than AM, and copolymers formed are statistically in nature. The influences of the molar ratio of AM to DMDAAC, concentrations of monomers, stabilizer and initiator, etc. on polymerization rate and intrinsic viscosity of polymer have been examined. The rate of polymerization (Rp) can be represented by \( {R_{\rm{p}}} \propto {[M]^{1.44}},{R_{\rm{p}}} \propto {[S]^{0.39}},{R_{\rm{p}}} \propto {[I]^{0.60}} \). The overall activation energy for the rate of polymerization is 37.38 kJ/mol over the temperature range 35–55°C.Based on the experimental results, the polymerization mechanisms were discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Hoover MF, Carr HE (1968) Tappi 51:522

    Google Scholar 

  2. Ma X, Wang A, Hu X, Chen Y (1997) Polym Mater Sci Eng 13(5):26

    CAS  Google Scholar 

  3. Butler GB, Ingley F (1951) J Am Chem Soc 73:895

    Article  CAS  Google Scholar 

  4. Ma Q (1988) Aggregation chemistry and flocculants. Chinese Environmental Science, Beijing

    Google Scholar 

  5. Yue Q, Li Y, Gao B, Yang Z, Zou X (2004) J Shandong Univ (Natural Sci) 39(6):86

    CAS  Google Scholar 

  6. Sairam M, Babu VR, Naidu BVK, Aminabhavi TM (2006) Int J Pharm 320:131

    Article  CAS  Google Scholar 

  7. Wang W, Liu L, Huang Z, Yang W (2005) RadTech Asia 2005Organization Committee; RadTech Asia Organization; RadTech China (CSIST)

  8. Shim SE, Jung H, Lee K, Lee JM, Choe S (2004) J Colloid Interface Sci 279:464

    Article  CAS  Google Scholar 

  9. Cho MS, Yoon KJ, Song BK (2002) J Appl Polym Sci 83:1397

    Article  CAS  Google Scholar 

  10. Tseng CM, Lu YY, El-Aasser MS, Vanderhoff JW (1986) J Polym Sci, Part A Polym Chem 24:2995

    Article  CAS  Google Scholar 

  11. Paine AJ (1990) Macromolecules 23:3109

    Article  CAS  Google Scholar 

  12. Paine AJ (1990) J Colloid Interface Sci 138:157

    Article  CAS  Google Scholar 

  13. Paine AJ, Luymes W, McNulty J (1990) Macromolecules 23:3104

    Article  CAS  Google Scholar 

  14. Guha S, Mandal BM (2004) J Colloid Interface Sci 271:55

    Article  CAS  Google Scholar 

  15. Chen D, Liu X, Yue Y, Zhang W, Wang P (2006) Eur Polym J 42:1284

    Article  CAS  Google Scholar 

  16. Sparnacci K, Laus M, Tondelli L, Magnani L, Bernardi C (2002) Macromol Chem Phys 203:1364

    Article  CAS  Google Scholar 

  17. Ober CK, Lok KP (1987) Macromolecules 20:268

    Article  CAS  Google Scholar 

  18. Takahashi K, Miyamori S, Uyama H, Kobayashi S (1996) J Polym Sci Part A Polym Chem 34:175

    Article  CAS  Google Scholar 

  19. Corner T (1981) Colloids Surf 3:119

    Article  CAS  Google Scholar 

  20. Ray B, Mandal BM (1997) Langmuir 13:2191

    Article  CAS  Google Scholar 

  21. Ray B, Mandal BM (1999) J Polym Sci Part A Polym Chem 37:493

    Article  CAS  Google Scholar 

  22. Lu J, Liang H (2005) Polymer chemistry. Chemical Industry, Beijing

    Google Scholar 

  23. Gowariker VR, Viswanathan NV, Sreedhar J (1986) Polymer science. Wiley, New York

    Google Scholar 

  24. Kuo SW, Kao HC, Chang FC (2003) Polymer 44:6873

    Article  CAS  Google Scholar 

  25. Aguilar MR, Gallardo A, Fernandez MM, SanRoman J (2002) Macromolecules 35(6):2036

    Article  CAS  Google Scholar 

  26. Ye Q, Zhang Z, Jia H, He W, Ge X (2002) J Colloid Interface Sci 253(2):279

    Article  CAS  Google Scholar 

  27. Gupta V, Nath S, Chand S (2002) Polymer 43(11):3387

    Article  CAS  Google Scholar 

  28. Behari K, Taunk K, Das R (1998) Polym Int 46(2):126

    Article  CAS  Google Scholar 

  29. Cowie JMG (1989) In: Allen G, Bevington JC, Booth C, Price C (eds) Comprehensive polymer science, vol. 3. Pergamon Press, England, Oxford

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Jinan, 250100, Shandong, People’s Republic of China

    Xiaona Wang, Qinyan Yue, Baoyu Gao, Xiaohui Si, Xun Sun & Shengxiao Zhang

Authors
  1. Xiaona Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qinyan Yue
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Baoyu Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaohui Si
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xun Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shengxiao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Qinyan Yue.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, X., Yue, Q., Gao, B. et al. Kinetics of dispersion polymerization of dimethyl diallyl ammonium chloride and acrylamide. J Polym Res 18, 1067–1072 (2011). https://doi.org/10.1007/s10965-010-9508-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10965-010-9508-z

Keywords

Search

Navigation