Abstract
Multilayer composite membranes with high removal capability for metal ion were prepared using electrostatic self-assembly (ESA) technique. Especially, self-assembled multilayer of chitosan microspheres and PAA were formed onto charged surface of polyacrylonitrile (PAN) membranes. It was confirmed that the alternate multilayer of chitosan and PAA were deposited on the base membrane surface. The formation of the ESA layer-by-layer of chitosan/PAA or chitosan microspheres/PAA onto the base membrane surface functionally equipped the membrane with removal capability for Cu2+. Especially, membranes with chitosan microspheres/PAA ESA layers on the surface showed relatively higher adsorption capability as compared with membranes with chitosan/PAA ESA layers. Besides, the influence of the pH of metal ion solution on the metal ion adsorption property of ESA modified membrane was investigated. It was proposed that the layer-by-layer self-assembled deposition of chitosan microspheres would be a new approach to functionalize membrane with high adsorption capability for metal ions.
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Ko DCK, Porter JF, Mckay G (2000) Chem Eng Sci 55(23):5819
Cassano A, Molinari R, Romano M, Drioli E (2001) J Membr Sci 181(1):111
Van der Bruggen B, Vandecasteele C (2003) Environ Pollut 122(3):435
Atia A, Donia AM, Abou-El-Enein SA, Yousif AM (2003) Sep Purif Technol 33(3):295
Coskun R, Soykan C, Sacak M (2006) React Funct Polym 66(6):599
Pearce CI, Lloyd JR, Guthrie JT (2003) Dyes Pigments 58(3):179
Oboh I, Aluyor E, Audu T (2009) Leonardo J Sci 8(14):58
Kumar MNVR (2000) React Funct Polym 46(1):1
Juang RS, Shao HJ (2002) Water Res 36(12):2999
Shimizu Y, Nakamura S, Saito Y, Nakamura T (2007) J Appl Polym Sci 107(3):1578
Guibal E, Touraud E, Roussy J (2005) World J Microbiol Biotechnol 21:913
Muzzarelli RAA (1973) Natural chelating polymers. Pergamon Press, Oxford, UK, p 1
Du WL, Niu SS, Xu ZR, Xu YL (2009) J Appl Polym Sci 111(6):2881
Harris R, Paños I, Acosta N, Heras A (2008) J Controlled Release 132(3):e76
Ding Y, Zhao Y, Tao X, Zheng YZ, Chen JF (2009) Polymer 50(13):2841
Decher G, Hong JD, Schmitt J (1992) Thin Solid Films 210–211:831
Ariga K, Hill JP, Lee MV, Vinu A, Charvet R, Acharya S (2008) Sci Technol Adv Mater 9:1
Lu OY, Ramamoorthy M, Bruening LM (2008) J Membr Sci 310(1–2):76
Hong SU, Malaisamy R, Bruening ML (2006) J Membr Sci 283(1–2):366
Garudadhwaj H, Rajesh KB, Ng WJ, Ramakrishna S (2008) J Mater Sci 43:212. doi:10.1007/s10853-007-2142-4
Ngah WSW, Endud CS, Mayanar R (2002) React Funct Polym 50(2):181
Steenkamp GC, Keizer K, Neomagus HWJP, Krieg H (2002) J Membr Sci 197:147
Kobayashi T, Fu HT, Cui Q, Wang HY (2008) J Appl Polym Sci 110:3234
Berthold A, Cremer K, Kreuter J (1996) J Controlled Release 39:17
Juang RS, Shao HJ (2002) Adsorption 8:71
Sailaja GS, Velayudhan S, Sunny MC, Sreenivasan K, Varma HK, Ramesh P (2003) J Mater Res 38:3653
Chang YC, Chang SW, Chen DH (2006) React Funct Polym 66(3):335
Sorlier P, Denuziere A, Viton C, Domard A (2001) Biomacromolecules 2(3):765
Dambies L, Guimon C, Yiacoumi S, Guibal E (2000) Colloids Surf A 177(2–3):203
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Fu, H., Kobayashi, T. Self-assembly functionalized membranes with chitosan microsphere/polyacrylic acid layers and its application for metal ion removal. J Mater Sci 45, 6694–6700 (2010). https://doi.org/10.1007/s10853-010-4762-3
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DOI: https://doi.org/10.1007/s10853-010-4762-3