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SBA-15 modified with Al, Ti, or Zr as supports for highly active NiW catalysts for HDS

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Abstract

A series of SBA-15-type materials modified with Al, Ti, and Zr were prepared and used as supports for hydrodesulfurization (HDS) catalysts based on NiW. Prepared supports and catalysts were characterized by N2 physisorption, small- and wide-angle XRD, UV–Vis DRS, FT-IR, IEP, TPR, TPD, HRTEM, and SEM–EDX. Sulfided catalysts were evaluated in HDS of dibenzothiophene (DBT). Catalytic activity tests show that the creation of defined anchoring points for the W species by modifying the surface of SBA-15 with Al, Ti, and Zr results in a considerable improvement in catalysts’ performance compared to pure SBA-supported analog. The possible reasons for this behavior are discussed.

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Acknowledgements

Financial support by DGAPA-UNAM (grant IN-110609) is gratefully acknowledged. The authors thank M. Aguilar, I. Puente, and C. Salcedo for technical assistance.

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Authors and Affiliations

  1. Facultad de Química, Universidad Nacional Autónoma de México, Cd. Universitaria, Coyoacán, 04510, México, DF, México

    Lilia Y. Lizama & Tatiana E. Klimova

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  1. Lilia Y. Lizama
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  2. Tatiana E. Klimova
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Correspondence to Tatiana E. Klimova.

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Lizama, L.Y., Klimova, T.E. SBA-15 modified with Al, Ti, or Zr as supports for highly active NiW catalysts for HDS. J Mater Sci 44, 6617–6628 (2009). https://doi.org/10.1007/s10853-009-3613-6

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  • DOI: https://doi.org/10.1007/s10853-009-3613-6

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