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Highly surfaced polypyrrole nano-networks and nano-fibers

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Abstract

Polypyrrole (PPy) nano-networks and nano-fibers were synthesized using interfacial and template polymerization techniques, respectively. The morphology of the PPy nano-networks showed that a homogeneous, three-dimensionally grown nano-fibers were produced. Dodecyl sulfonate was used as surfactant in the interfacial polymerization. Bulk conductivity of PPy nano-networks were in a range of 10−1–10−4 S/cm with a surface area of ca. 480 m2/g. Template synthesis produced one-directional alignment of conducting nano-arrays for the purpose of possible applications of these materials in charge storage devices (i.e., supercapacitors) as electrode materials. Electrochemical and spectroelectrochemical investigations showed that these materials are promising for device applications.

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References

  1. Sonmez G, Schottland P, Zong K, Reynolds JR (2001) J Mater Chem 11:289

    Article  CAS  Google Scholar 

  2. Orgzall I, Lorenz B, Ting ST, Hor PH, Menon VP, Martin CR, Hochheimer HD (1996) Phys Rev B 54:6654

    Article  Google Scholar 

  3. Oh KW, Park HJ, Kim SH (2004) J Appl Polym Sci 91:3659

    Article  CAS  Google Scholar 

  4. Skotheim TA, Elsenbaumer RL, Reynolds JR (eds) (1998) Handbook of conducting polymers, 2nd edn. Marcel Dekker, New York

  5. Shirakawa H, Lewis EJ, McDiarmid AG, Chiang CK, Heeger AJ (1977) Chem Commun 578

  6. Kros A, Nolte RJM, Sommerdijk NAJM (2002) Adv Mater 14:1779

    Article  CAS  Google Scholar 

  7. Ramanathan K, Bangar MA, Yun M, Chen W, Myung NV, Mulchandani A (2005) J Am Chem Soc 127:496

    Article  CAS  Google Scholar 

  8. An KH, Jeong SY, Hwang HR, Lee YH (2004) Adv Mater 16:1005

    Article  CAS  Google Scholar 

  9. Hosono K, Matsubara I, Murayama N, Woosuck S, Izu N (2005) Chem Mater 17:349

    Article  CAS  Google Scholar 

  10. Kros A, Linhardt JG, Bowman HK, Tirrell DA (2004) Adv Mater 16:723

    Article  CAS  Google Scholar 

  11. Johnson BJS, Wolf JH, Zalusky AS, Hillmyer MA (2004) Chem Mater 16:2909

    Article  CAS  Google Scholar 

  12. Jager EWH, Inganäs O, Lundström I (2001) Adv Mater 13:76

    Article  CAS  Google Scholar 

  13. Faverolle F, Attias AJ, Bloch B, Audebert P, Andrieux CP (1998) Chem Mater 10:740

    Article  CAS  Google Scholar 

  14. Gregory RV, Kimbrell WC, Kuhn HH (1989) Synth Met 28:C823

    Article  CAS  Google Scholar 

  15. White A, Slade R (2004) Macromol Symp 212:275

    Article  CAS  Google Scholar 

  16. Rowley NM, Mortimer RJ (2002) Sci Prog 85:243

    Article  CAS  Google Scholar 

  17. Sides CR, Martin CR (2005) Adv Mater 17:1

    Google Scholar 

  18. Leclerc M (1999) Adv Mater 11:1491

    Article  CAS  Google Scholar 

  19. Skotheim TA (ed) (1986) Handbook of conducting polymers, vols I and II. Marcel Dekker, New York

  20. Reece DA, Pringle JM, Ralph SF, Wallace GG (2005) Macromolecules 38:1616

    Article  CAS  Google Scholar 

  21. Pernaut JM, Reynolds JR (2000) J Phys Chem B 104:4080

    Article  CAS  Google Scholar 

  22. Stupnisek-Lisac E, Lencic D, Berkovic K (1992) Corrosion 48:924

    Article  CAS  Google Scholar 

  23. Iroh JO, Su W (2002) J Appl Polym Sci 85:2757

    Article  CAS  Google Scholar 

  24. Zhou XJ, Leung KT (2003) Macromolecules 36:2882

    Article  CAS  Google Scholar 

  25. Mecerreyes D, Alvaro V, Cantero I, Bengoetxea M, Calvo PA, Grande H, Rodriguez J, Pomposo JA (2002) Adv Mater 14:749

    Article  CAS  Google Scholar 

  26. Masalles C, Llop J, Viñas C, Teixidor F (2002) Adv Mater 14:826

    Article  CAS  Google Scholar 

  27. Ikegame M, Tajima K, Aida T (2003) Angew Chem Int Ed 42:2154

    Article  CAS  Google Scholar 

  28. He J, Chen W, Xu N, Li L, Li X, Xue G (2004) Appl Surf Sci 221:87

    Article  CAS  Google Scholar 

  29. Martin CR (1994) Science 266:1961

    Article  CAS  Google Scholar 

  30. Lu Y, Shi G, Li C, Liang Y (1998) J Appl Polym Sci 70:2169

    Article  CAS  Google Scholar 

  31. Zhang X, Manohar SK (2004) J Am Chem Soc 126:12714

    Article  CAS  Google Scholar 

  32. Yang Y, Liu J, Wan M (2002) Nanotechnology 13:771

    Article  CAS  Google Scholar 

  33. Huang J, Kaner RB (2004) J Am Chem Soc 126:851

    Article  CAS  Google Scholar 

  34. Huang J, Kaner RB (2004) Angew Chem 116:5941

    Article  Google Scholar 

  35. Huang J, Virgi S, Weiller BH, Kaner RB (2003) J Am Chem Soc 125:314

    Article  CAS  Google Scholar 

  36. Soudan P, Gaudet J, Guay D, Bélanger D, Schulz R (2002) Chem Mater 14:1210

    Article  CAS  Google Scholar 

  37. Menon VP, Lei J, Martin CR (1996) Chem Mater 8:2382

    Article  CAS  Google Scholar 

  38. Sonmez G, Sarac AS (2002) J Mater Sci 37:4609

    Article  Google Scholar 

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Acknowledgements

Authors gratefully acknowledge Prof. Ahmet Sirkecioglu for BET measurements. Instrumentation for this research was partially funded by TUBITAK grand TBAG-AY/104T251.

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Correspondence to Gursel Sonmez.

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Acik, M., Baristiran, C. & Sonmez, G. Highly surfaced polypyrrole nano-networks and nano-fibers. J Mater Sci 41, 4678–4683 (2006). https://doi.org/10.1007/s10853-006-0034-7

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