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Effect of Cyclodextrins on Coupling of o-Ethoxybenzenediazonium Salt with Pyrrole, Imidazole and 2-Methylimidazole

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Abstract

The effect of β-cyclodextrin on o-ethoxybenzenediazonium salt coupling with pyrrole, imidazole and 2-methylimidazole has been studied. The differences in the reaction course, the overall yield and products distribution have been analyzed. Experiments without cyclodextrins and selected reactions with α- and γ-cyclodextrins have been performed for comparison. The results are discussed in terms of co-conformation of azole molecules embedded in cyclodextrin cavity.

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Acknowledgements

Financial support of this study from the State Committee for Scientific Research, Grant No. 3 T09A 128 27 is kindly acknowledged.

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  1. Gdańsk University of Technology, 80-952, Gdańsk, Poland

    Marzena Jamrógiewicz, Kamila Sadowska & Jan F. Biernat

Authors
  1. Marzena Jamrógiewicz
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  2. Kamila Sadowska
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  3. Jan F. Biernat
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Correspondence to Jan F. Biernat.

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Jamrógiewicz, M., Sadowska, K. & Biernat, J.F. Effect of Cyclodextrins on Coupling of o-Ethoxybenzenediazonium Salt with Pyrrole, Imidazole and 2-Methylimidazole. J Incl Phenom Macrocycl Chem 56, 355–362 (2006). https://doi.org/10.1007/s10847-006-9115-0

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  • DOI: https://doi.org/10.1007/s10847-006-9115-0

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