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Electrochemical waste water treatment: Electrooxidation of acetaminophen

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Abstract

Oxidation of acetaminophen at boron-doped diamond (BDD) and at Ti/SnO2 anodes in a plug-flow divided electrochemical reactor led to electrochemical combustion, whereas at Ti/IrO2 benzoquinone was the exclusive product except at very long electrolysis times. The difference is explicable in terms of the different mechanisms of oxidation: direct oxidation at the anode for Ti/IrO2 vs. indirect oxidation involving electrogenerated hydroxyl radicals at BDD and Ti/SnO2. At BDD, at which the efficiency of degradation of acetaminophen was greatest, the rate of electrolysis at constant concentration was linearly dependent on the current, and at constant current linearly dependent on the concentration. Current efficiencies for mineralization up to 26% were achieved without optimization of the cell design.

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References

  1. Ternes T.A.(1998). Water Res. 32: 3245

    Article  CAS  Google Scholar 

  2. Stumpf M., Ternes T.A.,Wilken R-D., Rodrigues S.V. and Baumann W.(1999). Sci Total Environ 225: 135

    Article  PubMed  Google Scholar 

  3. Ternes T.A. and Hirsch R.(2000). Environ. Sci. Technol. 34: 2741

    Article  CAS  Google Scholar 

  4. Miao X-S, Bishay F., Chen M. and Metcalfe C.D.(2004). Environ. Sci. Technol. 38: 3533

    Article  PubMed  CAS  Google Scholar 

  5. Carballa M., Omil F., Lema J.M., Llompart M., Garcia-Jares C., Rodriguez I., Gomez M. and Ternes T.(2004). Water Res. 38: 2918

    Article  PubMed  CAS  Google Scholar 

  6. 6. Stan H.J. and Heberer T.(1997). Water Anal. 25: M20

    CAS  Google Scholar 

  7. Buser H-R., Müller M.D. and Theobald N.(1998). Environ. Sci. Technol. 32: 188

    Article  CAS  Google Scholar 

  8. Buser H-R., Poiger T. and Müller M.D.(1998). Environ. Sci. Technol. 32: 3449

    Article  CAS  Google Scholar 

  9. Halling-Sørensen R., Nielsen S.N., Lanzky P.F., Ingerslev F., Holten Lützhøft H.C. and Jørgensen S.E. (1998). Chemosphere 36: 357

    Article  PubMed  Google Scholar 

  10. Hirsch R., Ternes T., Haberer K. and Kratz K-L (1999). Sci. Total. Environ. 225:109

    Article  PubMed  CAS  Google Scholar 

  11. Buser H-R., Poiger T. and Müller M.D.(1999). Environ. Sci. Technol. 33: 2529

    Article  CAS  Google Scholar 

  12. Kolpin D.W., Furlong E.T., Meyer M.T., Thurman E.M., Zaugg S.D., Barber L.B. and Buxton H.T.(2002). Environ. Sci. Technol. 36: 1202

    Article  PubMed  CAS  Google Scholar 

  13. Anderson P.D., D’Aco V.J., Shanahan P., Chapra S.C., Buzby M.E., Cunningham V.L., Duplessie B.M., Hayes E.P., Mastrocco F.J., Parke N.J., Rader J.C., Samuelian J.H. and Schwab B.W.(2004). Environ. Sci. Technol. 38: 838

    Article  PubMed  CAS  Google Scholar 

  14. Heberer T.(2002). J Hydrology 266: 175

    Article  CAS  Google Scholar 

  15. Webb S., Ternes T., Gibert M. and Olejniczak K.(2003). Toxicol. Lett. 142: 157

    Article  PubMed  CAS  Google Scholar 

  16. Stackelberg P.E., Furlong E.T., Meyer M.T., Zaugg S.D., Henderson A.K. and Reissman D.B.(2004). Sci. Total Environ. 329: 99

    Article  PubMed  CAS  Google Scholar 

  17. Kümmerer K., Al-Ahmad A. and Mersch-Sundermann V.(2000). Chemosphere 40:701

    Article  PubMed  Google Scholar 

  18. Zuccato E., Calamari D., Natangelo M. and Fanelli R.(2000). Lancet 355: 1789

    Article  PubMed  CAS  Google Scholar 

  19. Kümmerer K.(2001). Chemosphere 45: 957

    Article  PubMed  Google Scholar 

  20. K. Kümmerer, in Proceedings of a Workshop Entitled “Pharmaceuticals in the Environment” held in Freiburg, Germany in July 1999 (Springer-Verlag, Berlin, 2001)

  21. Hansel S., Castegnaro M., Sportouch M.H., De Meo M., Milhavet J.C., Laget M. and Dumenil G.(1997). Internat. Arch. Environ. Health. 69: 109

    Article  CAS  Google Scholar 

  22. Castegnaro M., De Meo M., Laget M., Michelon J., Garren L., Sportouch M.H. and Hansel S.(1997). Internat. Arch. Environ. Health 70: 378

    Article  CAS  Google Scholar 

  23. Höfl C., Sigl G., Specht O., Wurdack I. and Wabner D.(1997). Water Sci. Technol. 35: 257

    Article  Google Scholar 

  24. Zweiner C. and Frimmel F.H.(2000). Water Res 34: 1881

    Article  Google Scholar 

  25. Balciolu I.A. and Ötker M.(2003). Chemosphere 50: 85

    Article  PubMed  Google Scholar 

  26. Ternes T.A., Stüber J., Herrmann N., McDowell D., Reid A., Kampmann M. and Teiser B.(2003). Water Res. 37: 1976

    Article  PubMed  CAS  Google Scholar 

  27. Andreozzi R., Caprio V., Marotta R. and Radnovnikovic A.(2003). J Hazrad Mat B103: 233

    Article  CAS  Google Scholar 

  28. Vogna D., Marotta R., Napolitano A., Anderozzi R., and Md’Ischia (2004). Water Res. 38: 414

    Article  PubMed  CAS  Google Scholar 

  29. Kabdaşli I., Gürel M. and Tünay O.(1999). Water Sci. Technol. 39: 265

    Article  Google Scholar 

  30. K. Burton, Endangered Species Bull. 25 (2000) 11, through http://www.findarticles.com/p/articles/mi_m0ASV/is_5_25, accessed November 5, 2004

  31. Andreozzi R., Caprio V., Marotta R. and Vogna D.(2003). Water Res. 37: 993

    Article  PubMed  CAS  Google Scholar 

  32. Vogna D., Marotta R., Napolitano A. and Md’Ischia (2002). J. Org. Chem. 67: 6143

    Article  PubMed  CAS  Google Scholar 

  33. Sires I., Arias C., Cabot P.Ll., Centellas F., Rodriguez R.M., Garrido J.A. and Brillas E.(2004). Environ. Chem. 1: 26

    Article  CAS  Google Scholar 

  34. Bock C. and MacDougall B.(1999). J. Electrochem. Soc. 146: 2925

    Article  CAS  Google Scholar 

  35. Comninellis C. and Pulgarin C.(1991). J. Appl. Electrochem. 21: 703

    Article  CAS  Google Scholar 

  36. Polcaro A.M., Mascia M., Palmas S. and Vacca A. (2002). Ind. Eng. Chem. Res., 2002 41: 2874

    Article  CAS  Google Scholar 

  37. Cañizares P., Martinez F., Diaz M., Garcia-Gomez J. and Rodrigo M.A.(2002). J. Electrochem. Soc. 149: D118

    Article  CAS  Google Scholar 

  38. Miner D.J., Rice J.R., Piggin R.M. and Kissinger P.T.(1981). Anal. Chem. 53: 2258

    Article  CAS  Google Scholar 

  39. Van Benschoten J.J., Lewis J.Y., Heineman W.R., Roston D.A. and Kissinger P.T.(1983). J. Chem. Educ. 60: 772

    Article  Google Scholar 

  40. Wangfuengkanagul N. and Chailapakul O.(2002). J. Pharmaceut. Biomed. Anal. 28: 841

    Article  CAS  Google Scholar 

  41. Gattrell M. and Kirk D.W.(1993). J. Electrochem. Soc. 140 : 1534

    Article  CAS  Google Scholar 

  42. Rodgers J.D., Jedral W. and Bunce N.J.(1999). Environ. Sci. Technol. 33: 1453

    Article  CAS  Google Scholar 

  43. Feng Y.J. and Li X.Y.(2003). Water Res 37: 2399

    Article  PubMed  CAS  Google Scholar 

  44. Tahar N.B. and Savall A.(1999). J. Appl. Electrochem. 29: 277

    Article  CAS  Google Scholar 

  45. Borras C., Laredo T. and Scharifker B.R.(2003). Electrochim. Acta 48: 2775

    Article  CAS  Google Scholar 

  46. Marselli B., Garcia-Gomez J., Michaud P-A., Rodrigo M.A. and Comninellis C.(2003). J. Electrochem. Soc. 150: D79

    Article  CAS  Google Scholar 

  47. Iniesta J., Michaud P.A., Panizza M., Cerisola G., Aldaz A. and Comininellis C.(2001). Electrochim. Acta 46: 3573

    Article  CAS  Google Scholar 

  48. Torres R.A.,Torres W.,Peringer P. and Pulgarin C.(2003). Chemosphere 50: 97

    Article  PubMed  CAS  Google Scholar 

  49. Salavagione H.J., Arias J., Garces P., Morallon E., Bebero C. and Vazquez J.L.(2004). J. Electroanal. Chem. 565: 375

    Article  CAS  Google Scholar 

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Acknowledgements

We thank the Natural Sciences and Engineering Research Council of Canada for financial support.

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Authors and Affiliations

  1. Department of Chemistry, University of Guelph, Guelph, Ontario, N1G 2W1, Canada

    Katie Waterston, Jenny Weijun Wang, Dorin Bejan & Nigel J. Bunce

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  1. Katie Waterston
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  2. Jenny Weijun Wang
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  3. Dorin Bejan
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  4. Nigel J. Bunce
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Correspondence to Nigel J. Bunce.

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Waterston, K., Wang, J.W., Bejan, D. et al. Electrochemical waste water treatment: Electrooxidation of acetaminophen. J Appl Electrochem 36, 227–232 (2006). https://doi.org/10.1007/s10800-005-9049-z

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  • DOI: https://doi.org/10.1007/s10800-005-9049-z

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