Abstract
The present study includes synthesis of two γ-Al2O3 samples from waste aluminum cans using a simple precipitation method. Precipitation was carried out using two different precipitating agents (i.e. NaOH and NH4OH). The two prepared alumina samples were characterized by means of X-ray diffraction (XRD) and N2 adsorption–desorption techniques. Surface acidity of γ-Al2O3 samples was measured by adsorption of two different probe molecules (i.e. pyridine and dimethyl pyridine) followed by desorption measurements using thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. Catalytic activity of the two prepared alumina samples towards the dehydration of methanol (to dimethyl ether) was studied in a fixed bed reactor at 300 °C. For comparison reasons, commercial γ-Al2O3 sample was, also, tested for the same catalytic reaction under the same conditions. Results showed that the alumina sample prepared using NaOH as a precipitating agent exhibited a better catalytic activity and stability compared with that prepared using NH4OH and showed a similar activity as the commercial γ-Al2O3 sample.
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Harst E, Potting J, Kroeze C (2016) Comparison of different methods to include recycling in LCAs of aluminum cans and disposable polystyrene cups. Waste Manag 48:565–583
Umar UA, Shafiq N, Malakahmad A, Nuruddin MF, Khamidi MF (2016) A review on adoption of novel techniques in construction waste management and policy. J Mater Cycles Waste Manag. https://doi.org/10.1007/s10163-016-0534-8
Terazono A, Yoshida A, Yang J, Moriguchi Y, Sakai S (2004) Material cycles in Asia: especially the recycling loop between Japan and China. J Mater Cycles Waste Manag 6:82–96
Vujic G, Stanisavljevic N, Batinic B, Jurakic Z, Ubavin D (2017) Barriers for implementation of ‘‘waste to energy” in developing and transition countries: a case study of Serbia. J Mater Cycles Waste Manag 19:55–69
Yoo S-J, Yoon H-S, Jang H-D, Hong S-T, Park H-S, Park S-U, Kwak D-H, Lee S-I (2007) Synthesis of aluminum ethoxide from used aluminum cans. Korean J Chem Eng 24:872–876
Mohamed MA, Kassim ME, El-katatny EA (1998) Optimization of the extraction of aluminum sulfate and ammonium aluminum sulfate alums from aluminum dross tailings. J Mater Res 13:1075–1083
El-Katatny EA, Halawy SA, Mohamed MA, Zaki MI (1998) A novel synthesis of high-area alumina via H2O2-precipitated boehmite from sodium aluminate solutions. J Chem Technol Biotechnol 72:320–328
El-Katatny EA, Halawy SA, Mohamed MA, Zaki MI (2002) Surface and bulk properties of alumina recovered under various conditions from aluminum dross tailings chemical waste versus bauxite ore. J Mater Res 17:1721–1728
El-Katatny EA, Halawy SA, Mohamed MA, Zaki MI (2003) Surface composition, charge and texture of active alumina powders recovered from aluminum dross tailings chemical waste. Powder Technol 132:137–144
Ghamsari MS, Mahzar ZAS, Radiman S, Abdul Hamid AM, Khalilabad SR (2012) Facile route for preparation of highly crystalline γ-Al2O3 nanopowder. Mater Lett 72:32–35
Osman AI, Abu-Dahrieh JK, Rooney DW, Halawy SA, Mohamed MA, Abdelkader A (2012) Effect of precursor on the performance of alumina for the dehydration of methanol to dimethyl ether. Appl Catal B Environ 127:307–315
Gao-Feng FU, Wand J, Jian K (2008) Influence of AlF3 and hydrothermal conditions on morphologies of α-Al2O3. Trans Nonferr Met Soc China 18:743–748
Isfahani TD, Javadpour J, Khavandi A, Dinnebier R, Goodarzi M, Rezaie HR (2012) Mechanochemical synthesis of alumina nanoparticles: Formation mechanism and phase transformation. Powder Technol 229:17–23
Wang L, Hu J, Cheng Y, Fu Z, Shen Z, Xiong Y (2015) Defect formation by order coalescence in vermicular grains during alumina phase transformation. Scr Mater 107:59–62
Shi Z, Jiao W, Chen L, Wu P, Wang Y, He M (2016) Clean synthesis of hierarchically structured boehmite and g-alumina with a flower-like morphology. Microporous Mesoporous Mater 224:253–261
Saxen RC, Seal D, Kumar S, Goyal HB (2008) Thermo-chemical routes for hydrogen rich gas from biomass: A review. Renew Sustain Energy Rev 12:1909–1927
Ni M, Leung DYC, Leung MKH (2007) A review on reforming bio-ethanol for hydrogen production. Int J Hydrogen Energy 32:3238–3247
Deng C, Yang W, Zhou J, Wang Y, Wang Z, Cen K (2016) Kinetics of dimethyl ether oxidation over Pt/ZSM-5 catalyst. Catal Commun 84:48–51
Chen W-H, Hsu C-L, Wang X-D (2016) Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization. Energy 109:326–340
Luu MT, Milani D, Wake M, Abbas A (2016) Analysis of di-methyl ether production routes: process performance evaluations at various syngas compositions. Chem Eng Sci 149:143–155
Cai M, Palčić A, Subramanian V, Moldovan S, Ersen O, Valtchev V, Ordomsky VV, Khodakov AY (2016) Direct dimethyl ether synthesis from syngas on copper–zeolite hybrid catalysts with a wide range of zeolite particle sizes. J Catal 338:227–238
Akarmazyan SS, Panagiotopoulou P, Kambolis A, Papadopoulou C, Kondarides DI (2014) Methanol dehydration to dimethyl ether over Al2O3 catalysts. Appl Catal B: Environ 145:136–148
Dadgar F, Myrstad R, Pfeifer P, Holmen A, Venvik HJ (2016) Direct dimethyl ether synthesis from synthesis gas: the influence of methanol dehydration on methanol synthesis reaction. Catal Today 270:76–84
Fu Y, Hong T, Chen J, Auroux A, Shen J (2005) Surface acidity and the dehydration of methanol to dimethyl ether. Thermochim Acta 434:22–26
Mollavali M, Yaripour F, Mohammadi-Jam S, Atashi H (2009) Relationship between surface acidity and activity of solid-acid catalysts in vapour phase dehydration of methanol. Fuel Process Technol 90:1093–1098
Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A (2015) The effects of synthesis operation conditions on the properties of modified γ-alumina nanocatalysts in methanol dehydration to dimethyl ether using factorial experimental design. Fuel 139:40–50
Tavan Y, Nikou MRK, Shariati A (2014) Effect of the P/Al ratio on the performance of modified HZSM-5 for methanol dehydration reaction. J Ind Eng Chem 20:668–673
Zaherian AA, Kazemeini M, Aghaziarati M, Alamolhoda S (2013) Synthesis of highly porous nanocrystalline alumina as a robust catalyst for dehydration of methanol to dimethyl ether. J Porous Mater 20:151–157
Li H, He S, Ma K, Wu Q, Jiao Q, Sun K (2013) Micro-mesoporous composite molecular sieves H-ZSM-5/MCM-41 for methanol dehydration to dimethyl ether: effect of SiO2/Al2O3 ratio in H-ZSM-5. Appl Catal A Gen 450:152–159
Zeng D, Liu S, Gong W, Qiu J, Chen H, Wang G (2014) A Bronsted solid acid synthesized from fly ash for vapor phase dehydration of methanol. Fuel 119:202–206
Sang Y, Liu H, He S, Li H, Jiao Q, Wu Q, Sun K (2013) Catalytic performance of hierarchical H-ZSM-5/MCM-41 for methanol dehydration to dimethyl ether. J Eng Chem 22:769–777
Park HW, Ha JK, Lee ES (2014) Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant. Korean J Chem Eng 31:2130–2135
Dagwa IM, Adama KK (2016) Property evaluation of pumice particulate-reinforcement in recycled beverage cans for Al-MMCs manufacture. J King Saud Univ Eng Sci. https://doi.org/10.1016/j.jksues.2015.12.006
Adans YF, Martins AR,, Ballarini AD, Carvalho LS, Coelho RE, Virgens CF (2016) A simple way to produce γ-alumina from aluminum cans by precipitation reactions. Mater Res 19:977–982
Chotisuwan S, Sirirak A, Har-Wae P, Wittayakun J (2012) Mesoporous alumina prepared from waste aluminum cans and used as catalytic support for toluene oxidation. Mater Lett 70:125–127
El-Meligi AA (2011) Hydrogen production by aluminum corrosion in hydrochloric acid and using inhibitors to control hydrogen evolution. Intern J Hydrogen Energy 36:10600–10607
Ho C-Y, Huang C-H (2016) Enhancement of hydrogen generation using waste aluminum cans hydrolysis in low alkaline de-ionized water. Intern J Hydrogen Energy 41:3741–3747
Martίnez SS, Sánchez LA, Alberto A. Άlvarez Gallegos AAÁ, Sebastian PJ (2007) Coupling a PEM fuel cell and the hydrogen generation from aluminum waste cans. Intern J Hydrogen Energy 32:3159–3162
Halawy SA (2003) Unpromoted and K2O-promoted cobalt molybdate as catalysts for the decomposition of acetic acid. Chem Mon 134:371–380
Mekhemer GAH, Halawy SA, Mohamed MA, Zaki MI (2004) Qualitative and quantitative assessments of acid and base sites exposed on polycrystalline MgO surfaces: thermogravimetric, calorimetric, and in-situ FTIR spectroscopic study combination. J Phys Chem B 108:13379–13386
Conesa TD, Campelo JM, Luna D, Marinas JM, Romero AA (2007) Development of mesoporous Al,B-MCM-41 materials: effect of reaction temperature on the catalytic performance of Al,B-MCM-41 materials for the cyclohexanone oxime rearrangement. Appl Catal B Environ 70:567–576
Mohamed MA, Halawy SA (1994) Kinetic and mechanistic study of the non-isothermal decomposition of manganese (II) acetate tetrahydrate. Thermochim Acta 242:173–186
Leofanti G, Padovan M, Tozzola G, Venturelli B (1998) Surface area and pore texture of catalysts. Catal Today 41:207–219
Hellgardt K, Chadwick D (1998) Effect of pH of precipitation on the preparation of high surface area aluminas from nitrate solutions. Ind Eng Chem res 37:405–411
Said AA, Abd El-Wahab MM, Abd El-Aal M (2016) Effect of ZrO2 on the catalytic performance of nano γ-Al2O3 in dehydration of methanol to dimethyl ether at relatively low temperature. Res Chem Intermed 42:1537–1556
Dumitriu E, Hulea V (2003) Effects of channel structures and acid properties of large-pore zeolites in the liquid-phase tert-butylation of phenol. J Catal 218:249–257
Lee H, Jung JC, Kim H, Chung Y-M, Kim TJ, Lee SJ, Oh S-H, Kim YS, Song IK (2008) Preparation of ZnFe2O4 catalysts by a co-precipitation method using aqueous buffer solution and their catalytic activity for oxidative dehydrogenation of n-butene to 1,3-butadiene. Catal Lett 122:281–286
Trawczyński JT (1996) Effect of aluminum hydroxide precipitation conditions on the alumina surface acidity. Ind Eng Chem Res 35:241–244
López T, Gómez R (1998) Evidence for Lewis and Brønsted acid sites on MgO obtained by sol–gel. J Sol Gel Sci Technol 13:1043–1047
Kumar VS, Padmasri AH, Satyanarayana CVV, Reddy IAK, Raju BD, Rao KSR (2006) Nature and mode of addition of phosphate precursor in the synthesis of aluminum phosphate and its influence on methanol dehydration to dimethyl ether. Catal Commun 7:745–751
Sung DM, Kim YH, Park ED, Yie JE (2010) Correlation between acidity and catalytic activity for the methanol dehydration over various aluminum oxides. Res Chem Intermed 36:653–660
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Abdelkader, A., Osman, A.I., Halawy, S.A. et al. Preparation and characterization of mesoporous γ-Al2O3 recovered from aluminum cans waste and its use in the dehydration of methanol to dimethyl ether. J Mater Cycles Waste Manag 20, 1428–1436 (2018). https://doi.org/10.1007/s10163-018-0702-0
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DOI: https://doi.org/10.1007/s10163-018-0702-0