Abstract
Some indispensable fundamental aspects of the kinetics of polymer crystallization are summed up. Those aspects are of particular interest in the development of crystalline structures during polymer processing. In this connection also a monograph (Janeschitz-Kriegl 2009) must be mentioned, which has been written last year by the first author of this article. The present paper contains a selection of particularly interesting subjects. It turns out that many of these subjects have eluded a mathematical treatment. The pertinent list is given in the introduction. And those people, who feel pressed to produce computer programs, are exhorted to mind the content of the present article and also of the mentioned monograph in avoiding arbitrary assumptions.
Similar content being viewed by others
References
Janeschitz-Kriegl H (2009) Crystallization modalities in polymer melt processing. Springer, New York
Van Krevelen DW (1978) Crystallinity of polymers and the means to influence the crystallization process. Chimia 32:279–294
Janeschitz-Kriegl H, Ratajski E, Stadlbauer M (2003) Flow as an effective promotor of nucleation in polymer melts: a quantitative evaluation. Rheol Acta 42:355–364
Marand H, Xu J, Srinivas S (1998) Determination of the equilibrium melting temperature of polymer crystals: linear and non-linear Hoffman-Weeks extrapolation. Macromolecules 31:8219–8229
Lijima M, Strobl G (2000) Isothermal crystallization and remelting of isotactic polypropylene analized by time- and temperature-dependent small angle X-ray scattering experiments. Macromolecules 33:5204–5214
Tribaut C, Monasse B, Haudin JM (1996) Experimental study of shear induced crystallization of an impact polypropylene copolymer. Colloid & Polymer Sci 274:197–208
Janeschitz-Kriegl H, Eder G, Stadlbauer M, Ratajski E (2005) A thermodynamic frame for the kinetics of polymer crystallization under process conditions. Monatshefte für Chemie (in English) 136:1119–1137
Olsen AP, Flagan RC, Kornfield JA (2006) Manipulation of athermal nuclei in aqueous solutions of poly(ethylene oxide) by scanning activity gravimetric analysis. Macromolecules 39:8419–8427
Becker R, Döring W (1935) Kinetic treatment of nucleation in supersaturated vapor. Ann Phys 5(24):719–752
Larson MA, Garside J (1986) Solute clustering in supersaturated solutions. Chem Engng Sci 41:1285–1289
Tolman RC (1949) The effect of droplet size on the surface tension. J Chem Phys 17:331–337
Janeschitz-Kriegl H (2003) How to understand nucleation in crystallizing polymer melts under real processing conditions. Colloid Polym Sci 281:1157–1171
Keller A (1957) Single crystals in polymers: evidence of folded chain configuration. Phil Mag 2:1171–1175
Blundell DJ, Keller A, Kovacs AJ (1966) A new self-nucleation phenomenon and its application to the growing of polymer crystals from solution. Polym Lett 4:481–486
Eder G, Janeschitz-Kriegl H, Liedauer S (1990) Crystallization processes in quiescent and moving polymer melts under heat transfer conditions. Progr Polym Sci 15:629–714
Janeschitz-Kriegl H, Eder G (2007) Shear induced crystallization, a relaxation process in polymer melts: a recollection. J Macromol Sci B Phys 46:1–11
Alfonso GC (1999) Formation of cylindric morphology in melt-sheared it-polybutene-1. Polym Mat Sci Engng 81:330–331
Schultz JM, Petermann J (1984) Transmission electron microscope observations of fibrillar-lamellar transformation in melt-drawn polymers-I. Isotactic polypropylene Colloid & Polymer Sci 262:294–305
Braun J, Wippel H, Eder G, Janeschitz-kriegl H (2003) Industrial solidification processes in polybutene-1. Part II. Influence of shear flow. Polym Engng Sci 43:188–203
Janeschitz-Kriegl H (1983) Polymer melt rheology and flow birefringence. Springer, New York, pp. 93 and 108
Eder G, Janeschitz-Kriegl H, Ratajski E (2006) Towards the prediction of structure development in injection molded semicrystalline polymers. In: Greener J, Wimberger-Friedl R (eds) Precision injection molding. Carl Hanser, Munich, pp 137–152
Stadlbauer M, Janeschitz-Kriegl H, Eder G, Ratajski E (2004) New extensional rheometer for creep flow at high tensile stress. Part II Flow induced nucleation for the crystallization of iPP J Rheol 48:631–639
Kimata S, Sakurai T, Nozue Y, Kasahara T, Yamaguchi N, Karino T, Shibayama M, Kornfield JA (2007) Molecular basis of the Shish-Kebab morphology in polymer crystallization. Science 316:1014–1017
Liedauer S, Eder G, Janeschitz-Kriegl H, Jerschow P, Geymayer W, Ingolic E (1993) On the kinetics of shear induced crystallization in polypropylene. Intern Polym Proc 8:236–244
Janeschitz-Kriegl H, Ratajski E (2005) Kinetics of polymer crystallization under processing conditions: transformation of dormant nuclei by the action of flow. Polymer 46:3856–3870
Scelsi L, Mackley MR, Klein H, Olmsted PD, Graham RS, Harlen OG, McLeish TCB (2009) Experimental observations and matching viscoelastic specific work predictions of flow induced crystallization for molten polyethylene within two flow geometries. J Rheol 53:859–876
Mykhaylyk OO, Chambon P, Graham RS, Patric J, Fairclough A, Olmsted PD, Ryan J (2008) Specific work of flow as a criterion for orientation in polymer crystallization. Macromolecules 41:1901–1904
Doi M, Edwards SF (1986) The Theory of Polymer Dynamics, Oxford.
Hadinata C, Gabriel C, Ruellmann M, Laun HM (2005) Comparison of shear-induced crystallization behavior of PB-1 samples with different molecular weight distributions. J Rheol 49:327–349
Hadinata C, Gabriel C, Ruellmann M, Kao N, Laun HM (2006) Shear-induced crystallization of PB-1 up to processing relevant shear rates. Rheol Acta 45:539–546
Gortemaker FH, Hanssen MG, De Cindio B, Laun HM, Janeschitz-Kriegl H (1976) Flow birefringence of polymer melts: application to the investigation of time dependent rheological properties. Rheol Acta 15:256–267
Lodge AS (1964) Elastic liquids. Academic, London
Wales JLS (1976) The application of flow birefringence to rheological studies of polymer melts. Doctoral Thesis, Delft University Press
Acknowledgment
The preparation of this report was carried out in the course of activities sponsored by the Austrian Science Foundation FWF under the contract nb. P 21228-N14.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Janeschitz-Kriegl, H., Ratajski, E. Some fundamental aspects of the kinetics of flow-induced crystallization of polymers. Colloid Polym Sci 288, 1525–1537 (2010). https://doi.org/10.1007/s00396-010-2266-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-010-2266-y