Skip to main content
Log in

Investigation of electric, dielectric, and magnetic properties of Li+1 and Mo+6 co-doped BiFeO3

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The bulk ceramics bearing chemical formula BiFeO3 and (BiLi)1/2(Fe2/3Mo1/3)O3 (abbreviated as BFO and BLFMO respectively) are synthesized using mixed oxide route. The physical properties (structural, dielectric, electric and magnetic) are tailored in Li and Mo co-doped BiFeO3. The phase evolution suggests that there is transformation from rhombohedral (pure BFO) to orthorhombic (BLFMO). Micro-structural suggests that due to co-doping the size of the grain is smaller than BFO. The dielectric properties of both BFO and BLFMO measure with an LCR meter varying the frequency (102–106 Hz) and temperature (30–375 °C). The leakage current decreases in BLFMO. The magnetic hysteresis loop owing weak ferromagnetism is depicted for Li and Mo co-doped BFO. The fabricated material will be base for various applications like filter and buffering.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. S. Dong, J.-M. Liu, S.-W. Cheong, Z. Ren, Adv. Phys. 64, 519–626 (2015)

    Article  ADS  Google Scholar 

  2. M. Fiebig, T. Lottermoser, D. Meier, M. Trassin, Nat. Rev. Mater. 1, 16046 (2016)

    Article  ADS  Google Scholar 

  3. S.V. Kalinin, Nat. Phys. 13, 115–116 (2017)

    Article  Google Scholar 

  4. W. Eerenstein, N.D. Mathur, J.F. Scott, Nature 442, 759–765 (2006)

    ADS  Google Scholar 

  5. C. Zhang, Y. Nie, S. Sanvito, A. Du, Nano Lett. 19, 1366–1370 (2019)

    Article  ADS  Google Scholar 

  6. P. Fischer, M. Polomska, I. Sosnowska, M. Szymanski, J. Phys. C 13, 1931–1940 (1980)

    Article  ADS  Google Scholar 

  7. V.S. Puli, A. Kumar, N. Panwar, I.C. Panwar, R.S. Katiyar, J. Alloys Compd. 509, 8223–8227 (2011)

    Article  Google Scholar 

  8. W. Mao, X. Li, Y. LI, X. Wang, Y. Wang, Y. Ma, X. Feng, T. Yang, J. Yang, Mater. Lett. 97 (2013) 56-58.

  9. H. Deng, M. Zhang, Z. Hu, Q. Xie, Q. Zhong, J. Wei, H. Yan, J. Alloys. Comp. 582, 273–276 (2014)

    Article  Google Scholar 

  10. F. Xue, Y. Tian, L. Tang, P. Guo, Z. Luo, W. Li, Ferroelectr. Lett. Sect. 45, 30–37 (2018)

    Article  Google Scholar 

  11. Xiao-Ya, LJ-Qing Dai, T-F Cao, Xiao-Wei Wang, Ceramics International, 45 (2019) 5015-5022

    Article  Google Scholar 

  12. Q. Xu, H. Zai, D. Wu, T. Qiu, M.X. Xu, Appl. Phys. Lett 95, 112510 (2009)

    Article  ADS  Google Scholar 

  13. Z. Wen, X. Shen, D. Wu, Q. Xu, J. Wang, A. Li, Solid State Comm. 150, 2081 (2010)

    Article  ADS  Google Scholar 

  14. N. Kumar, A. Shukla, R.N.P. Choudhary, J. Alloys Compounds 747, 895–904 (2018)

    Article  Google Scholar 

  15. S. Irfan, S. Rizwan, Y. Shen, L. Li, Asfandiyar. S Butt, Ce-Wen Nan, Sci. Rep. 7, 42493 (2017)

    Google Scholar 

  16. N. Kumar, A. Shukla, N. Kumar, R.N.P. Choudhary, A. Kumar, RSC Adv. 8, 36939–36950 (2018)

    Article  Google Scholar 

  17. N. Kumar, A. Shukla, R.N.P. Choudhary, Phys. Lett. A 381, 2721–2730 (2017)

    Article  ADS  Google Scholar 

  18. F. Zhang, X. Zeng, D. Bi, K. Guo, Y. Yao, S. Lu, Materials 11, 2208 (2018)

    Article  ADS  Google Scholar 

  19. D. Sando, Bin Xu, L. Bellaiche, V. Nagarajan, Applied Physics Reviews, 3 (2016)011106

    Article  ADS  Google Scholar 

  20. S. Pattanayak, R.N.P. Choudhary, P.R. Das, S.R. Shannigrahi, Ceram. Int. 40, 7983–7991 (2014)

    Article  Google Scholar 

  21. D.K. Nisha, S. Shukla, Kumar. AIP Conf. Proc. 2006, 030037 (2018)

    Article  Google Scholar 

  22. D. Barrionuevo, S.P. Singh, M.S. Tomar, Integrated Ferroelectr. 124, 41–47 (2011)

    Article  Google Scholar 

  23. POWDMULT: An interactive powder diffraction data interpretations and indexing Program Version 2.1, E. WU School of Physical Sciences, Flinder University of South Australia Bradford Park, SA 5042, Australia.

  24. H.P. Klug, L.E. Alexander, X-ray diffraction procedures (Wiley, New York, 1974)

    MATH  Google Scholar 

  25. A.M. Glazer, Simple ways of determining perovskite structures. Acta CrystA 31, 756–762 (1975)

    Article  Google Scholar 

  26. L. Vegard, Zeitschriftfür Physik 5, 17 (1921)

    Article  ADS  Google Scholar 

  27. A.R. Denton, N.W. Ashcroft, Vegard’s law. Phys. Rev. A 43, 3161–3164 (1991)

    Article  ADS  Google Scholar 

  28. A.R. Makhdoom, M.J. Akhtar, M.A. Rafiq, M.M. Hassan, Ceram. Int. 38, 3829–3834 (2012)

    Article  Google Scholar 

  29. X. Huang, W. Li, J. Zeng, L. Zheng, Z. Man, G. Li, Physica B 560, 16–22 (2019)

    Article  ADS  Google Scholar 

  30. C.M. Raghavan, E.S. Kim, J.W. Kim, S.S. Kim, Ceram. Int. 39, 6057–6062 (2013)

    Article  Google Scholar 

  31. H.O. Rodrigues, G.F.M. Pires Jr., J.S. Almeida, E.O. Sancho, A.C. Ferreira, M.A.S. Silva, A.S.B. Sombra, J. Phys. Chem. Solids 71, 1329 (2010)

    Article  ADS  Google Scholar 

  32. S.K. Barik, S. Ahemed, S. Hajra, Appl. Phys. A 125, 200 (2019)

    Article  ADS  Google Scholar 

  33. M. Sahu, S.K. Pradhan, S. Hajra, B. Panigrahi, R.N.P. Choudhary, Appl. Phys. A 125, 183 (2019)

    Article  ADS  Google Scholar 

  34. A.M. Glazer, Acta Cryst. A 31, 756 (1975)

    Article  Google Scholar 

  35. Ren Chen Da, Yi Guo Yan. Electron. Elem. Mater. 1, 25 (1982)

    Google Scholar 

  36. N.F. Mott, R.W. Gurney, Electronic Processes in Ionic Crystals (Clarendon, Oxford, 1940)

    MATH  Google Scholar 

  37. M.A. Lampert, P. Mark, Current Injection in Solids (Academic, New York, 1970)

    Google Scholar 

  38. S. Ahmed, S.K. Barik, Mater. Chem. Phys. 164, 6–14 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

The work is supported by AICTE, Govt. of India [No.: 8023/RID/RPS-32/(POLICY- III)(NER)/2011–12] and Ministry of Minority Affairs, Government of India and University Grant Commission (UGC), New Delhi (F1-17.1/2013–14/MANF-2013–14-MUS-ASS- 202128/SA-III/Website).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Subrat Kumar Barik.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ahmed, S., Barik, S.K. & Hajra, S. Investigation of electric, dielectric, and magnetic properties of Li+1 and Mo+6 co-doped BiFeO3. Appl. Phys. A 125, 303 (2019). https://doi.org/10.1007/s00339-019-2617-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-019-2617-6

Navigation