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Effect of Regime of Addition of Initiator on TEMPO-Mediated Polymerization of Styrene

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Summary

Investigation of the TEMPO-mediated polymerization of styrene at different regimes of addition of AIBN initiator showed that the course of the polymerization could be changed dramatically by a mode of the initiator addition without using any other additives. A very significant acceleration of the polymerization was reached at a specific regime without broadening the polydispersity of the resulting polymer.

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Authors and Affiliations

  1. Instituto de Investigaciones en Materiales, Mexico

    F. Díaz-Camacho, S. López-Morales, R. Vera-Graziano & L. Alexandrova

  2. Facultad de Química, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán, México D.F., 04510, Mexico

    E. Vivaldo-Lima

  3. Centro de Investigación en Química Aplicada, Blvd. Enrique Reyna 140, Saltillo, Coahuila, 25100, Mexico

    E. Saldívar-Guerra

Authors
  1. F. Díaz-Camacho
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  2. S. López-Morales
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  3. E. Vivaldo-Lima
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  4. E. Saldívar-Guerra
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  5. R. Vera-Graziano
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  6. L. Alexandrova
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Corresponding author

Correspondence to L. Alexandrova.

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Díaz-Camacho, F., López-Morales, S., Vivaldo-Lima, E. et al. Effect of Regime of Addition of Initiator on TEMPO-Mediated Polymerization of Styrene. Polym. Bull. 52, 339–347 (2004). https://doi.org/10.1007/s00289-004-0295-8

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  • DOI: https://doi.org/10.1007/s00289-004-0295-8

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