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Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India

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Environmental Geology

Abstract

A study of the hydrogeochemical processes in the national capital territory of India was carried out with the objective of identifying the geochemical processes and their relation with groundwater quality as well as to get an insight into the hydrochemical evalution of groundwater. Salinity and nitrate contamination are the two major problems in the area, which is alarming considering the use of this water for drinking. Various graphical plots and statistical analyses have been carried out using chemical data to deduce a hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies and factors controlling groundwater quality. The prevailing hydrochemical processes operating here are simple dissolution, mixing, weathering of carbonate minerals, locally known as ‘kankar’, and of silicate, ion exchange, and surface water interaction. Limited reverse ion exchange has been noticed in a few parts of the study area especially in post-monsoon periods. Periodic seasonal switch-over has been clearly noticed in these hydrogeochemical processes that control groundwater quality of the area. The number of factors that control the overall mineralization and water quality of Delhi vary from season to season. In pre-monsoon, there are four factors while in post-monsoon it increases to five. The study highlights the descriptive capabilities of conventional and multivariate techniques as effective tools in groundwater evaluation.

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References

  • APHA (1995) Standard methods for the examinations of water and waste water, 17th edn. American Public Health Association, Washington

    Google Scholar 

  • Ashley RP, Lloyd JW (1978) An example of the use of factor analysis and cluster analysis in groundwater chemistry interpretation. J Hydrol 39:355–364

    Article  Google Scholar 

  • Back W (1961) Techniques for mapping of hydrochemical facies. US Geol Surv Prof Pap 424-D:380–382

    Google Scholar 

  • Ballukraya PN, Ravi R (1999) Characterization of groundwater in the unconfined aquifer of Chennai City, India. J Geol Soc India 54:1–11

    Google Scholar 

  • Bartarya SK (1993) Hydrochemistry and rock weathering in a sub-tropical lesser Himalayan river basin in Kumaun, India. J Hydrol 146:149–174

    Article  Google Scholar 

  • Berner-Kay E, Berner RA (1987) The global water cycle, geochemistry and environment. Prentice-Hall, Englewood Cliffs, 396 p

  • Catroll D (1962) Rain water as a chemical agent for geological processes—a review. USGS Water Supply 1533:18–20

    Google Scholar 

  • Cattel RB (1965) Factor analysis: introduction to essentials. Biometrics 21:190–125

    Article  Google Scholar 

  • Cerling TE, Pederson BL, Damm KLV (1989) Sodium–calcium ion exchange in the weathering of shales: implications for global weathering budgets. Geology 17:552–554

    Article  Google Scholar 

  • CGWB (2003) Groundwater in Delhi—improving the sustainability through rain water harvesting. Report

  • CPCB (2001) Water quality status of lakes and reservoirs in Delhi. Report

  • Das Brijraj K, Kakar YP, Moser H, Stichler W (1988) Deuterium and oxygen-18 studies in groundwater of the Delhi area, India. J Hydrol 98:133–146

    Article  Google Scholar 

  • Datta PS, Tyagi SK (1996) Major ion chemistry of groundwater in Delhi area: chemical weathering processes and groundwater flow regime. J Geol Soc India 47:179–188

    Google Scholar 

  • Datta PS, Bhattacharya SK, Tyagi SK (1996) 18O studies on recharge of phreatic aquifers and groundwater flow-paths of mixing in the Delhi area. J Hydrol 176:25–36

    Article  Google Scholar 

  • Datta PS, Deb DL, Tyagi SK (1997) Assessment of groundwater contamination from fertilizers in the Delhi area based on 18O, NO −3 and K+ composition. J Contam Hydrol 27:249–262

    Article  Google Scholar 

  • Davis JC (1986) Statistics and data analysis in geology. Wiley, New York

    Google Scholar 

  • Davis SN, DeWiest RJM (1967) Hydrogeology. Wiley, New York

    Google Scholar 

  • Dawdy DR, Feth JH (1967) Application of factor analysis in the study of chemistry of groundwater quality, Mojave River Valley, California. Water Resour Res 3:505–510

    Article  Google Scholar 

  • Domenico PA (1972) Concepts and models in groundwater hydrology. McGraw-Hill, New York

    Google Scholar 

  • Durov SA (1948) Natural waters and graphical representation of their composition. Dokl Akad Nauk USSR 59:87–90

    Google Scholar 

  • Durum WH, Haffty J (1963) Implications of the minor element content of some major streams of the world. Geochim Cosmochim Acta 27:1

    Article  Google Scholar 

  • Edmond JM, Palwer MR, Measures CF, Grant B, Stallard RF (1995) The fluvial geochemistry and denudation rate of the Guayana Shield in Venezuela. Geochim Coscochim Acta 59:3301–3323

    Article  Google Scholar 

  • Fisher RS, Mulican WF III (1997) Hydrochemical evolution of sodium–sulphate and sodium–chloride groundwater beneath the Northern Chihuahuan desert, Trans-Pecos, Texas, USA. Hydrogeol J 10(4):455–474

    Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall, Englewood Cliffs, p 604

    Google Scholar 

  • Guler C, Thyne GD, McCray JE, Turner AK (2002) Evaluation of graphical and multivariate statistical method for classification of water chemistry data. Hydrogeol J 10(4):455–474

    Article  Google Scholar 

  • Gupta SK, Deshpande RD (2004) Water for India in 2050: first-order assessment of available options. Curr Sci 86:1216–1223

    Google Scholar 

  • Handa BK (1988) Content of potassium in groundwater in India. Fertil News 33(11):15–27

    Google Scholar 

  • Hem JD (1989) Study and interpretation of the chemical characteristics of natural water, 3rd edn. United States Geological Survey Water Supply Paper 2254

  • Huh Y, Tsoi MY, Zaitiser A, Edward JN (1998) The fluvial geochemistry of the river of Eastern Siberia. I. Tributaries of Lena River draining the sedimentation platform of the Siberia Craton. Geochim Cosmochim Acta 62:1657–1676

    Article  Google Scholar 

  • Jacks G (1973) Chemistry of groundwater in a district in Southern India. J Hydrol 18:185–200

    Article  Google Scholar 

  • Jankowski J, Acworth RI (1997) Impact of depris-flow deposits on hydrogeochemical processes and the development of dryland salinity in the Yass River catchment, New South Wales, Australia. Hydrogeol J 5(4):71–88

    Article  Google Scholar 

  • Klovan JE (1975) R-mode and Q-mode factor analysis. In: McCammon RB (ed) Concepts in geostatistics. Springer, Berlin Heidelberg New York, p 168

    Google Scholar 

  • Lloyd JW, Heathcode JA (1985) Natural inorganic hydrochemistry in relation to groundwater. Oxford University Press, New York

    Google Scholar 

  • Matthess G (1982) The properties of groundwater. Wiley, New York, p 498

    Google Scholar 

  • Maya AL, Loucks MD (1995) Solute and isotopic geochemistry and groundwater flow in the Central Wasatch Range, Utah. J Hydrol 172:31–59

    Article  Google Scholar 

  • Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287:401–428

    Article  Google Scholar 

  • Paliwal KV, Yadav BL (1976) Irrigation water quality and crop management in U.T. of Delhi. Water Technology Centre, IARI, New Delhi, Res Bull 9:1–45

  • Ramesam V (1982) Geochemistry of groundwater from a typical hard rock terrain. J Geol Soc India 23:201–204

    Google Scholar 

  • Sami K (1992) Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern Cape, South Africa. J Hydrol 139:27–48

    Article  Google Scholar 

  • Schoeller (1965) Hydrodynamique lans lekarst (ecoulemented emmagusinement). Actes Colloques Doubronik, I, AIHS et UNESCO, pp 3–20

  • Schuh WM, Klinekebiel DL, Gardner JC, Meyar RF (1997) Tracer and nitrate movements to groundwater in the Norruem Great Plains. J Environ Qual 26:1335–1347

    Article  Google Scholar 

  • Seth NN, Khanna SP (1969) A note on groundwater conditions in the Delhi area. Geological Survey of India Miscellaneous Publication No. 14, Part III, pp 101–110

  • Sett DN (1964) Groundwater geology of the Delhi region. Bull Geol Surv India Series B 16:l–35

    Google Scholar 

  • Sharma B, Kumar M, Ramanathan AL (2004) Impact of surface water on the groundwater quality in and around Nazafgarh Drain, Delhi. In: Ramesh R, Ramachandran S (eds) Freshwater management. Capital Publication Co., Delhi, pp 70–86

    Google Scholar 

  • Stallard RF, Edmond JM (1983) Geochemistry of Amazon, the influence of geology and weathering environment on the dissolved load. J Geophys Res 88:9671–9688

    Article  Google Scholar 

  • Subramanian V, Saxena K (1983) Hydrogeochemistry of groundwater in the Delhi region of India, relation of water quality and quantity. In: Proceedings of the Hamberg symposium IAHS publication no. 146, pp 307–316

  • Toth J (1984) The role of regional gravity flow in the chemical and thermal evolution of groundwater. In: Proceedings of the 1st Canadian/American conference on hydrogeology, Banff, Alberta, June 1984

  • Wadia DN (1981) Geology of India. Tata McGraw-Hill, New Delhi, p 508

    Google Scholar 

  • Wallick EI, Toth J (1976) Methods of regional groundwater flow analysis with suggestions for the use of environmental isotope and hydrochemical data in groundwater hydrology. IAEA, Vienna, pp 37–64

    Google Scholar 

  • WHO (1984) Guidelines for drinking water quality-II. Environmental Health Criteria, 5. World Health Organisation, Geneva, p 333

    Google Scholar 

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Acknowledgments

Author (MK) thanks Council of Scientific and Industrial Research (India) for financial grant through a junior research fellowship. The authors also thank the reviewer for his kind suggestions and the Director, National Institute of Hydrology, Roorkee for allowing to use the analysis facility in his department. We thank Department of Science and Technology (DST), India for partial funding in form of research projects. We would also like to thank Dr Roger Herbert Jr of Uppsala University, Sweden, for his useful directions.

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Authors and Affiliations

  1. School of Environmental Sciences, JNU, New Delhi, 110067, India

    Manish Kumar & AL. Ramanathan

  2. National Institute of Hydrology, Roorkee, Uttranchal, India

    M. S. Rao & Bhishm Kumar

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  1. Manish Kumar
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  2. AL. Ramanathan
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  3. M. S. Rao
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  4. Bhishm Kumar
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Correspondence to Manish Kumar.

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Kumar, M., Ramanathan, A., Rao, M.S. et al. Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. Environ Geol 50, 1025–1039 (2006). https://doi.org/10.1007/s00254-006-0275-4

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  • DOI: https://doi.org/10.1007/s00254-006-0275-4

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