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Patterning Si by using surface functionalization and microcontact printing with a polymeric ink

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Abstract

This paper describes a simple procedure for patterning Si substrate using a combination of surface functionalization and microcontact printing(ΜCP). The Si/SiO2 surfaces were chemically modified to present self-assembled monolayers (SAMs) of siloxanes terminating in reactive carboxylic anhydride groups and then patterned with poly(ethylene imine) (PEI) by, ΜCP We used the patterned thin films of PEI as etch resists on Si surfaces.

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References

  • Breen, T. L., Fryer, P. M., Nunes, R. W. and Rothwell, M. E., “Pattern-ing Indium Tin Oxide and Indium Zinc Oxide Using Microcontact Printing and Wet Etching”,Langmuir,18, 194 (2002).

    Article  CAS  Google Scholar 

  • Finnie, K. R, Haatsch, R. and Nuzzo, R. G., “Formation and Patterning of Self-Assembled Monolayers Derived from Long-Chain Organo-silicon Amphiphiles and Their Use as Templates in Materials Micro-fabrication”,Langmuir,16, 6968 (2000).

    Article  CAS  Google Scholar 

  • Geissler, M., Schmid, H., Bietsch, A., Michel, B. and Delamarche, E., “Defect-Tolerant and Directional Wet-Etch Systems for Using Mono-layers as Resists”,Langmuir,18, 2374 (2002).

    Article  CAS  Google Scholar 

  • Huck, W. T. S., Yan, L., Stroock, A., Haag, R. and Whitesides, G. M., “Patterned Polymer Multilayers as Etch Resists”,Langmuir,15 6862 (1999).

    Article  CAS  Google Scholar 

  • Lee, K.-B., Kim, Y. and Choi, I. S., “Pattern Generation of Cells on a Polymeric Surface Using Surface Functionalization and Microcon-tact Printing”,Bull. Korean Chem. Soc,24, 161 (2003).

    Article  CAS  Google Scholar 

  • Love, J. C., Wolfe, D. B., Chabinyc, M. L., Paul, K. E. and Whitesides, G. M., “Self-Assembled Monolayers of Alkanethiolates on Palla-dium are Good Etch Resists”,J. Am. Chem. Soc.,124, 1576 (2002).

    Article  CAS  Google Scholar 

  • St. John, P. M. and Craighead, H. G., “Microcontact Printing and Pat-tern Transfer Using Trichlorosilanes on Oxide Substrates”,Appl. Phys. Lett.,68, 1022 (1996).

    Article  CAS  Google Scholar 

  • Wasserman, S. R., Tao, Y.-T. and Whitesides, G. M., “Structure and Re-activity of Alkylsiloxane Monolayers Formed by Reaction of Al-kyltrichlorosilanes on Silicon Substrates”,Langmuir,5, 1074 (1989).

    Article  CAS  Google Scholar 

  • Xia, Y. and Whitesides, G. M., “Soft Lithography,”Angew. Chem. Int. Ed.,37, 550 (1998).

    Article  CAS  Google Scholar 

  • Xia, Y, Kim, E., Mrksich, M. and Whitesides, G. M., “Microcontact Printing of Akanethiols on Copper and Application in Microfabri-cation”,Chem. Mater.,8, 601 (1996).

    Article  CAS  Google Scholar 

  • Xia, Y., Zhao, X.-M., Kim, E. and Whitesides, G. M., “A Selective Etch-ing Solution for Use with Patterned Self-Assembled Monolayers of Alkanethiolates on Gold”,Chem. Mater.,7, 2332 (1995).

    Article  CAS  Google Scholar 

  • Yan, L., Huck, W T. S., Zhao, X.-M. and Whitesides, G. M., “Pattern-ing Thin Films of Poly(ethylene imine) on a Reactive SAM Using Microcontact Printing”,Langmuir,15, 1208 (1999).

    Article  CAS  Google Scholar 

  • Yan, L., Marzolin, C., Terfort, A. and Whitesides, G. M., “Formation and Reaction of Interchain Carboxylic Anhydride Groups on Self-Assembled Monolayers on Gold”,Langmuir,13, 6704 (1997).

    Article  CAS  Google Scholar 

  • Yan, L., Zhao, X.-M. and Whitesides, G. M., “Patterning a Preformed, Reactive SAM Using Microcontact Printing”,J. Am. Chem. Soc,120, 6179 (1998).

    Article  CAS  Google Scholar 

  • Zaho, X.-M., Wilbur, J. L. and Whitesides, G. M., “Using Two-Stage Chemical Amplification to Determine the Density of Defects in Self-Assembled Monolayers of Alkanethiolates on Gold”,Langmuir,12, 3257 (1996).

    Article  Google Scholar 

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Correspondence to Insung S. Choi.

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Lee, KB., Kim, D.J., Yoon, K.R. et al. Patterning Si by using surface functionalization and microcontact printing with a polymeric ink. Korean J. Chem. Eng. 20, 956–959 (2003). https://doi.org/10.1007/BF02697305

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  • DOI: https://doi.org/10.1007/BF02697305

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