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The effect of central metal atom on the electrical properties of phthalocyanine macromolecule

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Abstract

In order to investigate the effect of the central metal atom variation on the electrical properties of phthalocyanine macromolecule, iron, cobalt, nickel and copper as the di-valent metals were incorporated into the macrocycle. The electrical properties of these metallophthalocyanines were then studied to establish a structure-property relation-ship. The experimental data show that electrical parameters are greatly influenced by the choice of metal atom. It remains to be investigated whether results are dominantly interpretable in terms of the size of the metal, intermolecular π-electron delocalization of the macrocycle, or other molecular orbital property.

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  1. Hari S. Nalwa

    Present address: Department of Chemistry, State University of New York at Buffalo, 14214, Buffalo, New York

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  1. Department of Chemistry, University of Southern California, 90089-0482, Los Angeles, CA

    Hari S. Nalwa

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Nalwa, H.S. The effect of central metal atom on the electrical properties of phthalocyanine macromolecule. J. Electron. Mater. 17, 291–295 (1988). https://doi.org/10.1007/BF02652108

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  • DOI: https://doi.org/10.1007/BF02652108

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