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Hydrolysis of 2-alkoxyalk-2-enals

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Abstract

Hydrolysis of 2-alkoxyalk-2-enals with equimolar amount of water (in an organic solvent) and with an excess of water has been studied with the aim of synthesizing 2-oxopropanal (methylglyoxal). 2-Oxopropanal obtained in an excess of water exists in the hydrate from. In organic solvents, the cyclic trimer of 2-oxopropanal, 2,4,6-triacetyl-1,3,5-trioxane, predominates (NMR data).

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Authors and Affiliations

  1. Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    T. N. Mamashvili, N. A. Keiko, G. I. Sarapulova & M. G. Voronkov

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  1. T. N. Mamashvili
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  2. N. A. Keiko
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  3. G. I. Sarapulova
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  4. M. G. Voronkov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2547–2549, December, 1998.

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Mamashvili, T.N., Keiko, N.A., Sarapulova, G.I. et al. Hydrolysis of 2-alkoxyalk-2-enals. Russ Chem Bull 47, 2465–2467 (1998). https://doi.org/10.1007/BF02641556

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  • DOI: https://doi.org/10.1007/BF02641556

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