Skip to main content
SpringerLink
Log in

Hexadecyltrimethylammonium bromide/ethanol/water systems as mobie phase in reverse phase high performance liquid chromatography. Study of metal-diethyldithiocarbamate complexes retention

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

This paper presents the, chromatographic retention of Co(II), Ni(II) and Cu(II) as diethyldithiocarbamate complexes in the presence of hexadecyltrimethylammonium bromide/ethanol/water systems, as mobile phase, by reversed phase high performance liquid chromatography. The presence of an organic modifier reduces the retention times and improves the efficiency. In order to evaluate the interaction between the metal complexes and the mixed micellar system the values of solute binding constants are calculated in, two ways: a) Arunyanart and Cline-Love's treatment and b) multiple regression analysis taking account of the ethanol percentages.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. W. Armstrong, S. J. Henry, J. Liq. Chromatogr.3, 657 (1980).

    CAS  Google Scholar 

  2. D. W. Armstrong, F. Nome, Anal. Chem.53, 1662 (1981).

    Article  CAS  Google Scholar 

  3. D. W. Armstrong Sep. Purif. Methods,14, 213 (1985).

    Article  CAS  Google Scholar 

  4. J. G. Dorsey, Adv. Chromatogr.27, 167 (1987).

    CAS  Google Scholar 

  5. “Ordered Media in Chemical Separations,” W. L. Hinze, D. W. Armstrong, Eds., (ACS Symposium Series, No. 342), American Chemical Society, Washington DC, 1987.

    Google Scholar 

  6. M. G. Khaledi, Trends Anal. Chem.7, 293 (1988).

    Article  CAS  Google Scholar 

  7. A. Berthod, J. G. Dorsey, Analysis16, 75 (1988).

    CAS  Google Scholar 

  8. J. G. Dosey, M. T. De Echegaray, J. S. Landy, Anal. Chem.5, 924 (1983).

    Google Scholar 

  9. A. Berthod, I. Girard, C. Gonnet, Anal. Chem.58, 1359 (1986).

    Article  CAS  Google Scholar 

  10. A. Berthod, M. F. Borgerding, W. L. Hinze, J. Chromatogr.556, 263 (1991).

    Article  CAS  Google Scholar 

  11. M. L. Marina, O. Jiménez M. A. García, S. Vera, Microchem. J.53, 215 (1996).

    Article  CAS  Google Scholar 

  12. M. Arunyanart, L. J. Cline Love, Anal. Chem.56, 1557 (1984).

    Article  CAS  Google Scholar 

  13. J. P. Foley, Anal. Chim. Acta231, 237 (1990).

    Article  CAS  Google Scholar 

  14. P. Yarmchuck, R. Weinberger, R. F. Hirsch, L. L. Cline-Love, Anal. Chem.57, 2183 (1985).

    Article  Google Scholar 

  15. A. Berthod, A. Roussel, J. Chromatogr.449, 349 (1988).

    Article  CAS  Google Scholar 

  16. R. Bailey, R. M. Cassidy, Anal. Chem.64, 2277 (1992).

    Article  CAS  Google Scholar 

  17. J. H. Fendler, “Membrane Mimetic, Chemistry,” Wiley-Interscience, New York 1982.

    Google Scholar 

  18. P. C. Hiemenz, “Principles of Colloid and Surface Chemistry”, Marcel Dekker, New York 1986.

    Google Scholar 

  19. D. Myers, “Surfactant Science and Technology”, VCH Publishers, New York 1992.

    Google Scholar 

  20. M. L. Marina, S. Vera, A. R. Rodríguez, Chromatographia28, 379 (1989).

    Article  CAS  Google Scholar 

  21. M. A. García, S. Vera, M. L. Marina, Chromatographia,32, 148 (1991).

    Article  Google Scholar 

  22. V. González, M. A. Rodríguez Delgado, M. J. Sánchez, F. García Montelongo, Chromatographia32, 627 (1992).

    Article  Google Scholar 

  23. M. A. Rodríguez Delgado, M. J. Sánchez, V. González, F. García Montelongo, Fresenius J. Anal. Chem.345, 748 (1993).

    Article  Google Scholar 

  24. M. A. Rodríguez Delgado, M. J. Sánchez, V. González, F. García Montelongo, Chromatographia38, 342 (1994).

    Article  Google Scholar 

  25. D. López-López, S. Rubio-Barroso, L. M. Polo-Díez, J. Liq. Chrom. & Rel. Technol.18, 2397 (1995).

    Google Scholar 

  26. M. R. Hadjmohammadi, M. H. Fatemi, J. Liq. Chrom. & Rel. Technol.18, 2569 (1995).

    CAS  Google Scholar 

  27. M. A. García, M. L. Marina, J. Liq. Chrom. & Rel. Technol.19, 1757 (1996).

    Google Scholar 

  28. P. Jandera, J. Fischer, J. Chromatogr. A.788, 279 (1996).

    Article  Google Scholar 

  29. X. Li, J. S. Fritz, J. Chromatogr. A728, 235 (1996).

    Article  CAS  Google Scholar 

  30. M. L. Marina, M. A. García, J. Chromatogr A780, 103 (1997).

    Article  CAS  Google Scholar 

  31. E. Ruckenstein, R. Nagarajan, J. Phys. Chem.84, 1349 (1980).

    Article  CAS  Google Scholar 

  32. H. N. Singh, S. M. Sateem, R. P. Singh, K. S. Birdi J. Phys. Chem.84, 1349 (1980).

    Article  Google Scholar 

  33. P. L. Luisi, B. E. Straub, “Reverse Micelles. Biological and Technological Relevance of Amphiphilic Structures in Apolar Media”, Plenum Press, New York, 1984.

    Google Scholar 

  34. K. Fontell, A. Khan, B. Lindström, D. Maciejewska, S. Puang-Ngern, Colloid Polym. Sci.269, 727 (1991).

    Article  CAS  Google Scholar 

  35. M. P. San Andrés, S. Vera, M. L. Marina, J. Chromatogr685, 271 (1994).

    Article  Google Scholar 

  36. M. P. San Andrés, S. Vera, J. Liq. Chrom. & Rel. Technol.19, 799 (1996).

    Google Scholar 

  37. “Surfactants in Solution” K. L. Mittal, B. Lindman, Eds., Plenum Press, New York, 1984.

    Google Scholar 

  38. D. A. Piasecki, M. J. Wirth, Anal. Chim. Acta271, 183 (1993).

    Article  Google Scholar 

  39. D. J. Jobe, R. E. Verral, B. Skalski, E. Aircart, J. Phys. Chem.96, 6811 (1992).

    Article  CAS  Google Scholar 

  40. E. Aicart, D. J. Jobe, B. Skalski, R. E. Verral, J. Phys. Chem.96, 2348 (1992).

    Article  CAS  Google Scholar 

  41. A. Berthod, J. Chromatogr. A780, 191 (1997).

    Article  CAS  Google Scholar 

  42. R. Zana, S. Yiv C. Strazielle, P. Lianos, J Colloid Interface Sci.80, 208 (1981).

    Article  CAS  Google Scholar 

  43. F. M. Menger, C. E. Portnoy, J. Am. Chem. Soc.89, 4698 (1967).

    Article  CAS  Google Scholar 

  44. C. A. Bunton, Pure Appl. Chem.49, 969, (1977).

    CAS  Google Scholar 

  45. J. Gettins, D. Hall, P. L. Jobling, J. E. Rassing, E. Wyn-Jones, J. Chem. Soc. FaradayTrans 274, 1957 (1978).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department de Química Analítica, Facultad de Ciencias, Universidad de Alcalá, 28871 Alcalá de Henares, (Madrid), Spain

    M. P. San Andrés, M. J. Barroso & S. Vera

Authors
  1. M. P. San Andrés
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. J. Barroso
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Vera
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

San Andrés, M.P., Barroso, M.J. & Vera, S. Hexadecyltrimethylammonium bromide/ethanol/water systems as mobie phase in reverse phase high performance liquid chromatography. Study of metal-diethyldithiocarbamate complexes retention. Chromatographia 48, 517–522 (1998). https://doi.org/10.1007/BF02466643

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02466643

Key Words

Search

Navigation