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The synthesis of jaceidin

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  • Chimica. Biochimica. Biophysica
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Zusammenfassung

Durch Kondensation nachAllan-Robinson wurde aus 2,4,6-Trihydroxy-3, ω-dimethoxy-acetophenon das 4′-Benzyloxy-5,7-dihydroxy-3,6,3′-trimethoxyflavon dargestellt. Entbenzylierung in C-4′-Stellung führte zum 5,7,4′-Trihydroxy-3,6,3′-trimethoxyflavon. Die Eigenschaften dieser Verbindung und ihre Derivate sind identisch mit dem ausCentaurea jacea L. isolierten Jaceidin bzw. seinen Derivaten.

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Literatur

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Fukui, K., Matsumoto, T., Nakamura, S. et al. The synthesis of jaceidin. Experientia 24, 108–109 (1968). https://doi.org/10.1007/BF02146923

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  • DOI: https://doi.org/10.1007/BF02146923

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